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881.
Masayoshi Nakano Hitoshi Fukui Takuya Minami Kyohei Yoneda Yasuteru Shigeta Ryohei Kishi Beno?t Champagne Edith Botek Takashi Kubo Koji Ohta Kenji Kamada 《Theoretical chemistry accounts》2011,130(4-6):711-724
We have developed a method for analyzing the (hyper)polarizabilities of open-shell molecular systems. This method employs the (hyper)polarizability densities based on the natural orbitals and occupation numbers, which enables us to analyze the contributions of odd electrons having various open-shell (diradical) characters. Within broken-symmetry, i.e., spin-unrestricted, single-determinant molecular orbital and density functional theory approaches, we can also remove the spin contamination effects on these quantities through spin projection. To do that, an approximate spin projected method has been elaborated and applied to the analysis of the (hyper)polarizability of multi-radical systems. As examples, typical open-shell singlet systems, 1,3-dipoles and rectangular graphene nanoflakes, are examined. 相似文献
882.
Dr. Mari Toyama Takako Takizawa Itaru Morita Prof. Noriharu Nagao Dr. Yusuke Kuramochi Prof. Hitoshi Ishida 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(72):16582-16590
Two isomers of heteroleptic bis(bidentate) ruthenium(II) complexes with dimethyl sulfoxide (dmso) and chloride ligands, trans(Cl,Nbpy)- and trans(Cl,NHdpa)-[Ru(bpy)Cl(dmso-S)(Hdpa)]+ (bpy: 2,2′-bipyridine; Hdpa: di-2-pyridylamine), are synthesized. This is the first report on the selective synthesis of a pair of isomers of cis-[Ru(L)(L′)XY]n+ (L≠L′: bidentate ligands; X≠Y: monodentate ligands). The structures of the ruthenium(II) complexes are clarified by means of X-ray crystallography, and the signals in the 1H NMR spectra are assigned based on 1H–1H COSY spectra. The colors of the two isomers are clearly different in both the solid state and solution: the trans(Cl,Nbpy) isomer has a deep red color, whereas the trans(Cl,NHdpa) isomer is yellow. Although both complexes have intense absorption bands at λ≈440–450 nm, only the trans(Cl,Nbpy) isomer has a shoulder band at λ≈550 nm. DFT calculations indicate that the LUMOs of both isomers are the π* orbitals in the bpy ligand, and that the LUMO level of the trans(Cl,Nbpy) isomer is lower than that of the trans(Cl,NHdpa) isomer due to the trans effect of the Cl ligand; thus resulting in the appearance of the shoulder band. The HOMO levels are almost the same in both isomers. The energy levels are experimentally supported by cyclic voltammograms, in which these isomers have different reduction potentials and similar oxidation potentials. 相似文献
883.
Hitoshi Miyasaka Prof. Karin Takayama Ayumi Saitoh Sachie Furukawa Masahiro Yamashita Prof. Rodolphe Clérac Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(12):3656-3662
Two one‐dimensional compounds composed of a 1:1 ratio of MnIII salen‐type complex and NiII oximato moiety with different counter anions, PF6? and BPh4?, were synthesized: [Mn(3,5‐Cl2saltmen)Ni(pao)2(phen)]PF6 ( 1 ) and [Mn(5‐Clsaltmen)Ni(pao)2(phen)]BPh4 ( 2 ), where 3,5‐Cl2saltmen2?=N,N′‐(1,1,2,2‐tetramethylethylene)bis(3,5‐dichlorosalicylideneiminate); 5‐Clsaltmen2?=N,N′‐(1,1,2,2‐tetramethylethylene)bis(5‐chlorosalicylideneiminate); pao?=pyridine‐2‐aldoximate; and phen=1,10‐phenanthroline. Single‐crystal X‐ray diffraction study was carried out for both compounds. In 1 and 2 , the chain topology is very similar forming an alternating linear chain with a [‐MnIII‐ON‐NiII‐NO‐] repeating motif (where ‐ON‐ is the oximate bridge). The use of a bulky counteranion, such as BPh4?, located between the chains in 2 rather than PF6? in 1 , successfully led to the magnetic isolation of the chains in 2 . This minimization of the interchain interactions allows the study of the intrinsic magnetic properties of the chains present in 1 and 2 . While 1 and 2 possess, as expected, very similar paramagnetic properties above 15 K, their ground state is antiferromagnetic below 9.4 K and paramagnetic down to 1.8 K, respectively. Nevertheless, both compounds exhibit a magnet‐type behavior at temperatures below 6 K. While for 2 , the observed magnetism is well explained by a Single‐Chain Magnet (SCM) behavior, the magnet properties for 1 are induced by the presence in the material of SCM building units that order antiferromagnetically. By controlling both intra‐ and interchain magnetic interactions in this new [MnIIINiII] SCM system, a remarkable AF phase with a magnet‐type behavior has been stabilized in relation with the intrinsic SCM properties of the chains present in 1 . This result suggests that the simultaneous enhancement of both intrachain (J) and interchain (J′) magnetic interactions (with keeping J ? J′), independently of the presence of AF phase might be an efficient route to design high temperature SCM‐based magnets. 相似文献
884.
Chlorophyll molecules are well organized for efficient energy or electron transfer in a light-harvesting antenna or a reaction center of photosynthetic organisms. In order to make effective photosynthetic mimics, self-aggregates of natural chlorophylls and their synthetic analogues have been prepared with the specific intermolecular interactions. Many studies have been carried out to prepare aqueous chlorophyll aggregates by use of surfactants or chemical modifications of the natural pigments, because chlorophylls basically are poorly soluble in water. This review article focuses on the preparation and function of aqueous chlorophyll aggregates used in making artificial photosynthetic systems. 相似文献
885.
886.
Hitoshi Ohta S. Okubo N. Souda M. Tomoo T. Sakurai T. Yoshida E. Ohmichi M. Fujisawa H. Tanaka R. Kato 《Applied magnetic resonance》2009,35(3):399-410
A multiextreme (high-field, low-temperature, high-pressure and nanoscale) electron spin resonance (ESR) measurement system
is under development in Kobe. In this connection, our recent development is introduced and two applications of our high-frequency
high-field ESR are described. High-frequency high-field ESR measurements of dioptase (Cu6Si6O18·6H2O), which has an interesting antiferromagnetic Cu2+ network, have been performed using a pulsed magnetic field of up to 55 T. Antiferromagnetic resonances (AFMR) are clearly
observed at 4.2 K with the light sources of up to 1017 GHz. However, a deviation from the conventional two-sublattice AFMR
theory is observed in the high field. Temperature dependence of the X-band and high-frequency ESR has been also observed in
the triangular lattice antiferromagnet EtMe3P[Pd(dmit)2]2 which shows the spin-Peierls-like transition below T
c = 25 K. The preliminary field dependence of the spin gap estimated from the analyses of our ESR results has been shown in
connection with the previous magnetic susceptibility results. 相似文献
887.
Hiroshi Nomura Yusuke Suganuma Akinori Setani Masashi Takahashi Masato Mikami Hitoshi Hara 《Proceedings of the Combustion Institute》2009,32(2):2163-2169
Flame spreading along a fuel droplet array at microgravity has been studied as a simple model of spray combustion. A three droplet array with a pendulum suspender was employed to investigate interactions between flame spreading and droplet motion in the array direction. Initial droplet diameter was 0.8 mm and fuel was n-heptane. A silicon carbide pendulum suspender of 15 μm in diameter and 30 mm in length was used for the third droplet. The first fixed droplet was ignited by electric spark. Behavior of the flame and the third droplet was observed using a high-speed video camera. Dimensionless span, which is the averaged droplet span divided by the averaged initial diameter of the three droplets, was varied from 2.7 to 10. Large displacement of the movable droplet was observed after group flame grew around the movable droplet. As the initial dimensionless span increased, the averaged droplet speed after the occurrence of flame spreading to the movable droplet increased steeply, taking the maximum value around 5 in initial dimensionless span, and then decreased gradually. The movable droplet advanced toward the second droplet in small spans and moved away from the second droplet in large spans. The direction of the motion changed around 4.6 in initial dimensionless span. Flame spread induction time from the second to the third droplet increased exponentially as the initial dimensionless span was increased. The induction time of flame spreading to a movable droplet was longer than that of flame spreading to a fixed droplet. From calculations of flame spreading along a 20-droplet array, it was predicted that the droplet speed nearly converged after flame spread to the sixteenth droplet. The maximum speed of the nineteenth droplet appeared around 7.5 in the initial dimensionless span. 相似文献
888.
Miyasaka H Izawa T Takahashi N Yamashita M Dunbar KR 《Journal of the American Chemical Society》2006,128(35):11358-11359
Two isostructural 2D assemblies composed of [Ru2(O2CCF3)4] and TCNQ or TCNQF4 in a 2:1 ratio were synthesized: [{Ru2(O2CCF3)4}2TCNQ].3(p-xylene) (1b) and [{Ru2(O2CCF3)4}2TCNQF4].3(p-xylene) (2). In 1b, the TCNQ moiety is assigned to be neutral because of no significant electron transfer from the Ru24+ units. Therefore, the magnetic property of 1b can be understood to be a paramagnetic nature of the isolated Ru24+ unit, while, a fully charge-transfer from the Ru2 units to the TCNQF4 molecules in 2 leads to charge delocalization spreading over the 2D network and allows a long-range magnetic order to occur. On the basis of an idea of the resonance scheme in charge-transfer D2A network systems, the first successful example of a charge-transferred magnet in the Ru2-TCNQ system was rationally designed by tuning redox between [Ru2]4+ and the TCNQ molecule changing from TCNQ to TCNQF4. 相似文献
889.
Nakao K Nishimura M Tamachi T Kuwatani Y Miyasaka H Nishinaga T Iyoda M 《Journal of the American Chemical Society》2006,128(51):16740-16747
Fully conjugated giant macrocyclic oligothiophenes with 60pi, 90pi,120pi, 150pi, and 180pi frames (1, 2, 3, 4 and 5) have been designed, and their butyl-substituted derivatives (1a, 2a, 3a, 4a, and 5a) have been synthesized using modified Sonogashira and McMurry coupling reactions as key steps. The 60-180pi systems 1-5 are circular with 1.8-6 nm inner cavities and 3.3-7.5 nm outside molecular diameters. Compound 1a containing ten 3,4-dibutyl-2,5-thienylene, eight ethynylene, and two vinylene units has been converted into macrocyclic oligo(3,4-dibutyl-2,5-thienylene-ethynylene) 6a using bromination/dehydrobromination procedure. Giant macrocycles 1a-6a exhibit a red shift of their absorption spectra and a fairly strong fluorescence with a large Stokes shift as compared to a linear conjugated counterpart having five thiophene rings. Compounds 1a-6a exhibit multistep reversible redox behaviors with fairly low first oxidation potentials, reflecting their cyclic conjugation. Furthermore, chemical oxidation of 1a-6a with FeCl3 shows drastic changes of spectroscopic properties due to intramolecular and intermolecular pi-pi interactions. Doping of 1a-3a with iodine forms semiconductor due to its pi-donor properties and pi-pi stacking ability. X-ray analysis of 1a confirmed a round, planar structure with nanoscale inner cavity, and revealed host ability for alkanes and unique packing structure. Interestingly, 2a and 3a self-aggregate in the solid state to form "molecular wires," which are about 200 nm thick and more than 1 mm long. The internal structures of fibrous aggregates have been investigated by optical microscope, scanning electron microscopy, atomic force microscopy, and X-ray diffraction analyses. 相似文献
890.
Saito T Wu CC Shiku H Yasukawa T Yokoo M Ito-Sasaki T Abe H Hoshi H Matsue T 《The Analyst》2006,131(9):1006-1011
A quantitative analysis of the oxygen concentration profile near a poly(dimethylsiloxane) (PDMS) microfluidic device was performed using scanning electrochemical microscopy (SECM). A microchannel filled with sodium sulfite (Na(2)SO(3)) aqueous solution was imaged by SECM, showing that the oxygen diffusion layer of the PDMS microchannel was observed to be hemicylindrical. Based on a theoretical analysis of the hemicylindrical diffusion layer of the microchannel, the total oxygen mass transfer rates of oxygen to the PDMS microchannel filled with the Na(2)SO(3) solution was calculated to be (4.01 +/- 0.30) x 10(-12) mol s(-1). This is the maximum value of the oxygen transfer rate for this PDMS microchannel device. The oxygen consumption rate increased almost linearly with the logarithm of the concentration of E. coli cells (10(6) approximately 10(8) cells). The respiratory activity for a single E. coli cell was estimated to be approximately 4.31 x 10(-20) mol s(-1) cell(-1). 相似文献