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81.
Hisayoshi Matsushima Daisuke Kiuchi Yasuhiro Fukunaka Kazuhiko Kuribayashi 《Electrochemistry communications》2009,11(8):1721-1723
Single bubble evolution on a micro-electrode (Pt, φ = 0.2 mm) was observed in 0.36 M KOH solution under terrestrial (1-G) and microgravity (μ-G) environments. The bubble size during galvanostatic electrolysis (j = −2.6 × 103 A m−2) was measured by CCD images, which allowed us to calculate the gas evolution efficiency, fG, by comparison with the consumed charge. The efficiency under μ-G increased until 1 s after starting electrolysis and then reached constant value (fG = 0.85), while, under 1-G, it showed a lower value and remarkably decreased 2 s after the beginning of the measurement. Such differences between μ-G and 1-G were explained by the mass transfer rate of the dissolved gas. Bubble-induced microconvection dominated the mass transfer under μ-G without any buoyancy force, on the other hand, the single-phase free convection (microscopic natural convection) influenced the bubble growth under 1-G. 相似文献
82.
Density functional theory calculations found that spin density distributions of platinum clusters adsorbed on nanometer-size defective graphene patches with zigzag edges deviate strongly from those in the corresponding bare clusters, due to strong Pt-C interactions. In contrast, platinum clusters on the pristine patch have spin density distributions similar to the bare cases. The different spin density distributions come from whether underlying carbon atoms have radical characters or not. In the pristine patch, center carbon atoms do not have spin densities, and they cannot influence radical characters of the absorbed cluster. In contrast, radical characters appear on the defective sites, and thus spin density distributions of the adsorbed clusters are modulated by the Pt-C interactions. Consequently, characters of platinum clusters adsorbed on the sp2 surface can be changed by introducing vacancy-type defects. 相似文献
83.
With the aim of understanding the nature of the interactions between organic molecules and metal surfaces, the adsorption of NH3 onto model Fe(110) and Fe(111) surfaces has been studied with use of the molecular orbital and density functional theories. B3LYP calculations have revealed that the on-top site is most suitable for adsorption of NH3 both on Fe(110) and on Fe(111). Mulliken population analysis in terms of the MO's of the two fragment systems suggested that electron delocalization from NH3 to the Fe surface should play a key role in the adsorption. Then, our transformation scheme of fragment orbitals has demonstrated that the electron delocalization is represented well only by a pair of interaction orbitals. The NH3 molecule provides the occupied interaction orbital bearing a close resemblance to the highest occupied (HO) MO, whereas the Fe surface prepares the paired unoccupied orbital that is localized at the adsorption site and overlaps in-phase with the orbital of NH3. Not only the lowest unoccupied (LU) MO but also other unoccupied MO's have been shown to participate significantly in the interaction. The reason the on-top site is the most preferable position for NH3 attack has been elucidated by investigating the interaction orbitals. 相似文献
84.
Shingo Ebata Morio Ishihara Kousuke Kumondai Ryo Mibuka Kiichiro Uchino Hisayoshi Yurimoto 《Journal of the American Society for Mass Spectrometry》2013,24(2):222-229
A new system incorporating a multi-turn time-of-flight secondary ion/sputtered neutral mass spectrometer (TOF-SIMS/SNMS) with laser post-ionization was designed and constructed. This system consists of a gallium focused ion beam, femtosecond (fs) laser for post-ionization, and multi-turn TOF mass spectrometer. When laser post-ionization was used, the secondary ion signal strengths for several metals increased by up to 650 times, and were greater than the values obtained in conventional TOF-SIMS experiments. Use of the multi-turn mass spectrometer resulted in an increase in mass resolving power with increase in the total TOF. The mass resolving power reached to 23,000 after 800 multi-turn cycles, corresponding to a flight path length of 1040 m. These results indicated that this system is very effective for the analysis of valuable materials such as space samples with high sensitivity, high mass resolving power, and high lateral resolution. 相似文献
85.
Hiroaki Otaka Shigeru Ogawa Ichiro Minato Hisayoshi Utsugi Takashi Amagai 《International journal of environmental analytical chemistry》2013,93(8):583-599
The extractability of dioxins from suspended substances (SS) in distributed water was evaluated. Dioxins adsorbed on the collected SS were extracted by pressurized liquid extraction with various solvents. High-polarity solvents (acetone, alcohols) extracted considerably higher amounts of some lower-chlorinated dibenzo-p-dioxins (LoCDDs) than did low-polarity solvents (dichloromethane, toluene), whereas the extracted amounts of higher-chlorinated dibenzo-p-dioxins (HiCDDs) were roughly the same, regardless of the solvent. The extractability of the LoCDDs depended on the isomer. Daily variations in quantities for PCDDs, organic matter (OM), and iron in the SS were examined, and the results suggested that in the SS, LoCDDs and HiCDDs were associated, respectively, with raw water-derived organic matter and microparticles sequestered in iron oxy(hydr)oxide floc. It was also suggested that the low extractability of certain congeners was not attributable to the enormously coexisting ferric compounds but was probably attributable to OM with which they strongly associate. 相似文献
86.
Compositional design of high modulus glasses for disk substrates 总被引:1,自引:0,他引:1
Modified equations have been derived on the basis of Makishima–Machenzie (M–M) theory for direct determination of the elastic modulus of glasses from composition. This modified calculation model gives an excellent agreement between the measured and estimated values of elastic modulus for over 50 different glasses. Using this model we developed a glass in the Li2O–MgO–Al2O3–Y2O3–TiO2–SiO2 system with elastic modulus value greater than 130 GPa and bending strength higher than 50 kg f/mm2. This high modulus glass substrate is expected to provide a solution to the vibration problem of rapid rotation magnetic disk and allow higher track density per inch to be achieved for high performance hard-disk drives (HDDs). 相似文献
87.
Ohta R Shimazu T Siry M Gunjishima I Nishikawa K Oshima H Okamoto A 《Chemical communications (Cambridge, England)》2011,47(13):3873-3875
Cylindrical carbon nanotubes (CNTs) pretreated by UV irradiation were able to react with NH(3) to give nitrogen-containing CNTs without destroying their vertically aligned morphology. This process provided incorporation of nitrogen mostly at pyridinic and pyrrolic sites and promoted disordering, which was correlated with decreased electrical conductivity of CNT yarns. 相似文献
88.
Nagasawa Y Ueoka R Yamanokuchi R Horiuchi N Ikeda T Rotinsulu H Mangindaan RE Ukai K Kobayashi H Namikoshi M Hirota H Yokosawa H Tsukamoto S 《Chemical & pharmaceutical bulletin》2011,59(2):287-290
Salsolinol (1), a tetrahydroisoquinoline alkaloid, was isolated from the marine sponge Xestospongia cf. vansoesti collected in Indonesia as a proteasome inhibitor, along with three salsolinol derivatives, norsalsolinol (2), cis-4-hydroxysalsolinol (3), and trans-4-hydroxysalsolinol (4). Compounds 1 and 2 inhibited the chymotrypsin-like activity of the proteasome with IC(50) values of 50 and 32 μg/ml, respectively, but 3 and 4 showed no inhibitory effect even at 100 μg/ml. 相似文献
89.
Chang HC Komasaka K Kishida K Shiozaki T Ohmori T Matsumoto T Kobayashi A Kato M Kitagawa S 《Inorganic chemistry》2011,50(10):4279-4288
Liquid crystalline (LC) platinum(II) complexes with 1,2-thiophenolato and 1,2-benzendithiolato have been newly synthesized and investigated by spectroscopy together with the catecholato analogue. The variations in coordinating atoms (O or S or O/S mixed) lead to significant modulation in electrochemical properties in solution and absorption and emission properties of the complexes both in solution media and in the condensed phases. The asymmetric, polar mesogens/chromophores consisting of Pt(II), redox-active ligands, and alkyl-substituted bipyridine commonly play important roles not only in stabilizing the columnar LC phases, but also in fluctuations of the ground state energies. A key finding of the present work is the chromic properties of LC complexes induced by the interplay of self-association of the mesogens/chromophores and their fluctuating properties. 相似文献