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91.
[reaction: see text] New Lewis acid-assisted Br?nsted acids (LBAs), tin(IV) chloride-2,6-dialkoxyphenols, serve as artificial cyclases for biomimetic polyene cyclization. For example, the enantioselective cyclization of 4-(homogeranyl)toluene using tin(IV) chloride-2,6-di[(1'R,2'R)-trans-2'-(3' ',5' '-xylyl)cyclohexanoxy]phenol gave a trans-fused tricyclic compound with 85% ee. 相似文献
92.
Haraguchi K Shiina N Yoshimura Y Shimada H Hashimoto K Tanaka H 《Organic letters》2004,6(16):2645-2648
2'-Beta-methyl- and 2'-beta-hydroxymethyl-2'-deoxy-4'-thionucleosides have been synthesized through PhSeCl-mediated electrophilic glycosidation using 4-thiofuranoid glycals having carbon substituents at the C2-position as a glycosyl donor. Preparation of these glycals were carried out by means of the C2 lithiation of 1-chloro-4-thiofuranoid glycal with LTMP followed by the Birch reduction of the chlorine atom. [reaction: see text] 相似文献
93.
Hisashi Kojima 《Journal of Number Theory》2004,107(1):25-62
The purpose of this paper is to derive a generalization of Shimura's results concerning Fourier coefficients of Hilbert modular forms of half integral weight over total real number fields in the case of Hilbert-Maass wave forms over algebraic number fields by following the Shimura's method. Employing theta functions, we shall construct the Shimura correspondence Ψτ from Hilbert-Maass wave forms f of half integral weight over algebraic number fields to Hilbert-Maass wave forms of integral weight over algebraic number fields. We shall determine explicitly the Fourier coefficients of in terms of these f. Moreover, under some assumptions about f concerning the multiplicity one theorem with respect to Hecke operators, we shall establish an explicit connection between the square of Fourier coefficients of f and the central value of quadratic twisted L-series associated with the image of f. 相似文献
94.
We investigate coherent time evolution of charge states (pseudospin qubit) in a semiconductor double quantum dot. This fully tunable qubit is manipulated with a high-speed voltage pulse that controls the energy and decoherence of the system. Coherent oscillations of the qubit are observed for several combinations of many-body ground and excited states of the quantum dots. Possible decoherence mechanisms in the present device are also discussed. 相似文献
95.
Hori A Kataoka H Okano T Sakamoto S Yamaguchi K Fujita M 《Chemical communications (Cambridge, England)》2003,(2):182-183
The reversible cross-catenation of two different coordination rings (Pd(II)- and Pt(II)-linked rings) has been achieved by using the labile nature of the Pd-N interaction and efficient hydrophobic contact between the rings. 相似文献
96.
97.
Four new aromatic constituents, rhododendroketoside, (-)-sakuraresinoside, acernikol, and nikoenoside, were isolated from a Japanese folk medicine, the stem bark of Acer nikoense MAXIM. The structures of the new constituents were determined on the basis of chemical and physicochemical evidence. The principle cyclic diarylheptanoids were found to show inhibitory effects on the release of beta-hexosaminidase in RBL-2H3 cells. 相似文献
98.
Two new friedelane-type triterpenes, salasones D and E, a new norfriedelane-type triterpene, salaquinone B, and a new polyacylated eudesmane-type sesquiterpene, salasol B, were isolated from the stems of Salacia chinensis LINN. (S. prinoides DC., Hippocrateaceae) collected in Thailand. Their stereostructures were elucidated on the basis of chemical and physicochemical evidence. Some norfriedelane-type triterpene, lignan, and catechin constituents were found to show radical scavenging activity. 相似文献
99.
100.