全文获取类型
收费全文 | 533篇 |
免费 | 10篇 |
国内免费 | 5篇 |
专业分类
化学 | 383篇 |
晶体学 | 5篇 |
力学 | 3篇 |
数学 | 15篇 |
物理学 | 142篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2020年 | 7篇 |
2019年 | 8篇 |
2018年 | 5篇 |
2017年 | 2篇 |
2016年 | 9篇 |
2015年 | 8篇 |
2014年 | 7篇 |
2013年 | 19篇 |
2012年 | 26篇 |
2011年 | 14篇 |
2010年 | 19篇 |
2009年 | 8篇 |
2008年 | 38篇 |
2007年 | 26篇 |
2006年 | 41篇 |
2005年 | 48篇 |
2004年 | 26篇 |
2003年 | 28篇 |
2002年 | 29篇 |
2001年 | 8篇 |
2000年 | 13篇 |
1999年 | 8篇 |
1998年 | 3篇 |
1997年 | 11篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 12篇 |
1992年 | 12篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1988年 | 5篇 |
1987年 | 7篇 |
1986年 | 14篇 |
1985年 | 7篇 |
1984年 | 9篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 1篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1969年 | 1篇 |
排序方式: 共有548条查询结果,搜索用时 15 毫秒
21.
Y. Muramatsu K. Tagami S. Uchida 《Journal of Radioanalytical and Nuclear Chemistry》1994,188(4):305-311
Measurements of some selected radionuclides were carried out in rain waters collected from Ibaraki Prefecture, Japan, following the nuclear accident at Tomsk-7, Russian Federation, in April 1993. The concentrations obtained for artificial radionuclides were90Sr1.8 mBq l–1,137Cs0.1 Bq l–1,131I0.1 Bq l–1 and129I4 Bq l–1. Uranium (238U) concentrations in rainfalls in April 1993 were 6.3–39 ng l–1. These data were compared to control values obtained previously and there was no appreciable influence on the radioactivity levels in Japan after the Tomsk-7 accident. Since only limited data on the concentrations of129I and uranium in rain water are available, these new analytical results contribute to understanding the background levels for these nuclides. 相似文献
22.
M. Ishikawa G. Izawa T. Omori Y. Muramatsu K. Yoshihara 《Journal of Radioanalytical and Nuclear Chemistry》1985,91(1):163-171
Particle-induced X-ray emission (PIXE) was applied to evaluate the loss of volatile elements such as iodine in biological samples. The analytical quality of the method is comparable or better than spectrophotometry, which is currently believed to be the most reliable for iodine determination. The temperature dependence of volatility loss of trace iodine was characteristic, and the feature was divided into three temperature regions. The first one, ranging from room temperature to 200 °C, showed only a slight loss below 20% on drying; the second stage, between 200 °C and 350 °C, where carbonizing processes became prominent, showed a remarkable loss up to 50%; the last one, beyond 350 °C, was accompanied by a considerable loss of iodine (more than 80%) with ashing. Even in the analysis using low temperature ashing with oxygen plasma, the loss of iodine observed was considerable (nearly 80%). The significance of these findings by PIXE in trace analysis is noted to improve analytical quality of volatile elements, such as iodine in biological, medical and also environmental fields. 相似文献
23.
Wang CR Kai T Tomiyama T Yoshida T Kobayashi Y Nishibori E Takata M Sakata M Shinohara H 《Angewandte Chemie (International ed. in English)》2001,40(2):265
The cover picture shows a section of the electron charge density of the first metal carbide endohedral metallofullerene (Sc(2)C(2))@C(84) obtained from a synchrotron X-ray powder diffraction study by the maximum entropy method (MEM). The several density maxima, which correspond to scandium and carbon atoms, are clearly seen inside the C(84) carbon cage. The MEM charge density distribution also reveals that the C(84) cage has D(2d) symmetry (no. 23) and that the C(2) axis is parallel to the <100> face-centered cubic (fcc) direction of the unit cell. As a consequence of the site symmetry being 4mm, the C(2) axis of (Sc(2)C(2))@C(84) is oriented to six equivalent <100> directions and shows a merohedral disorder. The resultant Sc small middle dot small middle dot small middle dotSc distances and C-C bond lengths of the Sc(2)C(2) cluster are 0.429(2) and 0.142(6) nm, respectively. The observed C-C bond length is between that of a typical single and a double bond, and is very close to that of the C-C bond (0.143 nm) combining two pentagons in a C(60) molecule. More about this fascinating structure can be found in the contribution by Shinohara and co-workers on p. 397 ff. 相似文献
24.
25.
Copper-catalyzed oxonium ylide formation-[2,3] shift of (5S,7R)-5-allyloxy-1-diazo-8-(p-methoxybenzyloxy)-7-methyl-2-octanone (3) proceeded in tetrahydrofuran-dichloromethane (4 : 1) under reflux with an excellent stereoselectivity (97 : 3) to give (2R,6S)-2-allyl-6-[(2R)-3-(p-methoxybenzyloxy)-2-methylpropyl]-3-dihydropyranone (2) as a major isomer in 82% yield. The resultant pyranone (2) was converted to the key intermediate (1) of the Mulzer's laulimalide synthesis and its derivatives (14, 15). 相似文献
26.
27.
28.
29.
Dr. Jinying Zhang Zhen Zhu Prof. Dr. Yanquan Feng Hitoshi Ishiwata Dr. Yasumitsu Miyata Dr. Ryo Kitaura Dr. Jeremy E. P. Dahl Prof. Dr. Robert M. K. Carlson Dr. Natalie A. Fokina Prof. Dr. Peter R. Schreiner Prof. Dr. David Tománek Prof. Dr. Hisanori Shinohara 《Angewandte Chemie (International ed. in English)》2013,52(13):3536-3536
30.