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71.
[reaction: see text] Treatment of 1,6-enynes with tetramethallylchromate induces a cyclization reaction with concurrent introduction of a methallyl group. A catalytic amount of CrCl(3) combined with methallylmagnesium chloride also achieves this cyclization process. The resultant cyclic organometallic species undergo further functionalization upon reaction with electrophiles. 相似文献
72.
Kubo K Akemoto M Anderson S Aoki T Araki S Bane KL Blum P Corlett J Dobashi K Emma P Frisch J Fukuda M Guo Z Hasegawa K Hayano H Higo T Higurashi A Honda Y Iimura T Imai T Jobe K Kamada S Karataev P Kashiwagi S Kim E Kobuki T Kotseroglou T Kurihara Y Kuriki M Kuroda R Kuroda S Lee T Luo X McCormick DJ McKee B Mimashi T Minty M Muto T Naito T Naumenko G Nelson J Nguyen MN Oide K Okugi T Omori T Oshima T Pei G Potylitsyn A Qin Q Raubenheimer T Ross M Sakai H Sakai I Schmidt F Slaton T Smith H 《Physical review letters》2002,88(19):194801
Electron beams with the lowest, normalized transverse emittance recorded so far were produced and confirmed in single-bunch-mode operation of the Accelerator Test Facility at KEK. We established a tuning method of the damping ring which achieves a small vertical dispersion and small x-y orbit coupling. The vertical emittance was less than 1% of the horizontal emittance. At the zero-intensity limit, the vertical normalized emittance was less than 2.8 x 10(-8) rad m at beam energy 1.3 GeV. At high intensity, strong effects of intrabeam scattering were observed, which had been expected in view of the extremely high particle density due to the small transverse emittance. 相似文献
73.
Kitagawa K Inoue A Shinokubo H Oshima K 《Angewandte Chemie (International ed. in English)》2000,39(14):2481-2483
74.
The history of high-performance computing in turbulent flows is reviewed and their recent topics in industrial use are addressed. Special attention is paid to the validity of the method in flow visualization, and three-dimensional unsteady simulation is focused. Seemingly fundamental CFD technique for 3-D turbulence simulation has been well developed recently, but its practical use as an industrial tool has not yet become popular. An effort to close a wide gap between fundamental and practical use of scientific computer simulation is introduced through the national project promoting computational science and its development in industries of the next generation. 相似文献
75.
Nakao H 《Chaos (Woodbury, N.Y.)》1999,9(4):902-909
A two-dimensional system of nonlocally coupled complex Ginzburg-Landau oscillators is investigated numerically for the first time. As previously shown for the one-dimensional case, this two-dimensional system exhibits anomalous spatio-temporal chaos characterized by power-law spatial correlations. In this chaotic regime, the amplitude difference between neighboring elements displays temporal noisy on-off intermittency. The system is also spatially intermittent in this regime, as revealed by multiscaling analysis: The amplitude field is multiaffine and the difference field is multifractal. Correspondingly, the probability distribution function of the measure defined for each field is strongly non-Gaussian, exhibiting scale-dependent deviations in the tail due to intermittency. (c) 1999 American Institute of Physics. 相似文献
76.
77.
Toishiyuki Uryu Haruki Ohkawa Ryuichi Oshima 《Journal of Polymer Science.Polymer Physics》1988,26(6):1227-1236
(N-Ethylcarbazol-3-yl)methyl acrylate and methacrylate were polymerized anionically and radically. Anionically-polymerized polyacrylate using ethylmagnesium chloride-benzalacetophenone as catalyst is an isotactic rich polymer with 85% isotactic dyad. All polymers except anionically polymerized polymethacrylate showed good film forming property. Hole drift mobilities measured by the time-of-flight method at room temperature and at 5 × 105 V/cm are in the following order: isotactic polyacrylate (1.0 × 10-5 cm2/V s) > atactic polyacrylate (1.8 × 10-6 cm2/V s) > atactic polymethacrylate (1.2 × 10-6 cm2/V s) at 5 × 105 V/cm. These results are discussed in terms of the hopping model between localized sites. 相似文献
78.
An imaging method for partially coherent objects is proposed by the aid of the propagation law of mutual intensity, and it can be reduced to principles used in holography and radio astronomy if the coherence reaches the both extremes, i.e., perfect coherence and complete incoherence, respectively. 相似文献
79.
Transverse magnetoconductivity tensor components have been measured in dilute Bi:Sn and Bi:Te alloys up to magnetic field/temperature = 13T / 0.5 K and compared with those of high purity sample. As was expected, perfect phase inversion and enhancement of the quantum oscillation of the magnetoresistivity component were observed. It was also found that peaks of Hall resistivity tensor component due to the hole Fermi surface in the highest magnetic field region revealed dispersion-type line shape in Bi:Sn alloy in contrast to those in Bi:Te alloy or in pure Bi, which may be ascribed to the difference between the screening of anions and that of cations by electrons and holes in these semimetals. 相似文献
80.
Albone DP Challenger S Derrick AM Fillery SM Irwin JL Parsons CM Takada H Taylor PC Wilson DJ 《Organic & biomolecular chemistry》2005,3(1):107-111
Amination of C-H bonds activated by ether oxygen atoms is facile with chloramine-T as nitrene source and copper(I) chloride in acetonitrile as catalyst. For cyclic ethers the hemiaminal products are generally stable and can be isolated pure. For acyclic ethers, the hemiaminal products, as expected, fragment with elimination of alcohol to yield imines. When activation of benzylic positions is remote through a conjugated system, stable benzylamine derivatives are isolated. Mechanistic studies are consistent with concerted insertion of an electrophilic nitrenoid into the C-H bond in the rate-determining step, though in an asynchronous manner with a more activated substrate. 相似文献