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排序方式: 共有149条查询结果,搜索用时 31 毫秒
11.
Jun Yano Akihiko Muta Yutaka Harima Akira Kitani 《Journal of Solid State Electrochemistry》2011,15(3):601-605
A poly(2,5-dimethoxyaniline) (PDMA) film was coated on the iron surface by the electropolymerization of 2,5-dimethoxyaniline in neutral buffer solution (pH?6.86). The PDMA film strongly adhered to the surface because of the polar methoxy groups of the PDMA molecules. The fact that no electrochemical response of the PDMA film-coated iron electrode to dissolved Fe2+ exhibited that the PDMA film was less permeable to dissolved species, acting as a diffusion barrier against agents causing corrosion such as H2O and O2. The PDMA film coating greatly lowered the anodic current peak ascribed to the anodic dissolution of iron and the corrosion current in strongly acidic medium, 0.5?M H2SO4 aqueous solution (1?M?????mol?dm??) as well as neutral medium (pH?6.86). The high anti-corrosion ability was due to a hybrid effect of the PDMA film not only as the diffusion barrier, but also as an in situ oxidant in spite of the slight redox activity of PDMA. In addition, the PDMA film is much more durable and adhesive than polyaniline film against over-oxidation. 相似文献
12.
Anek Charoenphakdee Ken Kurosaki Hiroaki Muta Masayoshi Uno Shinsuke Yamanaka 《固体物理学:研究快报》2008,2(2):65-67
High‐density polycrystalline samples (above 98% of the theoretical density) of Ag8GeTe6 were prepared by solid‐state reactions of Ag2Te, GeTe, and Te, followed by hot‐pressing. The thermoelectric properties were measured at temperatures ranging from room temperature to around 700 K. The thermal conductivity values were extremely low (0.25 Wm–1 K–1 at room temperature), and consequently Ag8GeTe6 exhibited a relatively high thermoelectric figure of merit, ZT = 0.48 at 703 K. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
13.
Nakao H 《Chaos (Woodbury, N.Y.)》1999,9(4):902-909
A two-dimensional system of nonlocally coupled complex Ginzburg-Landau oscillators is investigated numerically for the first time. As previously shown for the one-dimensional case, this two-dimensional system exhibits anomalous spatio-temporal chaos characterized by power-law spatial correlations. In this chaotic regime, the amplitude difference between neighboring elements displays temporal noisy on-off intermittency. The system is also spatially intermittent in this regime, as revealed by multiscaling analysis: The amplitude field is multiaffine and the difference field is multifractal. Correspondingly, the probability distribution function of the measure defined for each field is strongly non-Gaussian, exhibiting scale-dependent deviations in the tail due to intermittency. (c) 1999 American Institute of Physics. 相似文献
14.
A pitch-synchronous analysis of hoarseness in running speech 总被引:3,自引:0,他引:3
H Muta T Baer K Wagatsuma T Muraoka H Fukuda 《The Journal of the Acoustical Society of America》1988,84(4):1292-1301
A method of pitch-synchronous acoustic analysis of hoarseness requiring a voice sample of only four fundamental periods is presented. This method calculates a noise-to-signal (N/S) ratio, which indicates the depth of valleys between harmonic peaks in the power spectrum. The spectrum is calculated pitch synchronously from a Fourier transform of the signal, windowed through a continuously variable Hanning window spanning exactly four fundamental periods. A two-stage procedure is used to determine the exact duration of the four fundamental periods. An initial estimate is obtained using autocorrelation in the time domain. A more precise estimate is obtained in the frequency domain by minimizing the errors between the preliminary calculated power spectrum and the predicted spectrum spread of a windowed harmonic signal. Analysis of synthesized voices showed that the N/S ratio is sensitive to additive noise, jitter, and shimmer, and is insensitive to slow (8 Hz) modulation in fundamental frequency and amplitude. An analysis of pre- and postoperative voices of six patients with benign laryngeal disease showed that the N/S ratio for vowel /u/ in running speech consistently improved after surgery for all subjects, in agreement with their successful therapeutic results. 相似文献
15.
Albone DP Challenger S Derrick AM Fillery SM Irwin JL Parsons CM Takada H Taylor PC Wilson DJ 《Organic & biomolecular chemistry》2005,3(1):107-111
Amination of C-H bonds activated by ether oxygen atoms is facile with chloramine-T as nitrene source and copper(I) chloride in acetonitrile as catalyst. For cyclic ethers the hemiaminal products are generally stable and can be isolated pure. For acyclic ethers, the hemiaminal products, as expected, fragment with elimination of alcohol to yield imines. When activation of benzylic positions is remote through a conjugated system, stable benzylamine derivatives are isolated. Mechanistic studies are consistent with concerted insertion of an electrophilic nitrenoid into the C-H bond in the rate-determining step, though in an asynchronous manner with a more activated substrate. 相似文献
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18.
Hiroya Kitahata Kiyoharu Tadanaga Tsutomu Minami Norifumi Fujimura Taichiro Ito 《Journal of Sol-Gel Science and Technology》2000,19(1-3):589-593
Hexagonal YMnO3 has a ferroelectric property with an optimal remanent polarization along the c-axis. The c-axis oriented YMnO3 thin films with a small leakage current were prepared by the sol-gel dipping method. The c-axis orientation of the films was promoted by the addition of diethanolamine to the Mn precursor solution. A heat treatment with multiple steps led to a dense film structure with fine grains. The dense structure resulted in the decrease of the leakage current. Furthermore, when the films were heat-treated in a vacuum, the leakage current became considerably small and the ferroelectricity of the YMnO3 thin films was observed even at room temperature. 相似文献
19.
We successfully synthesized two enantiomers of bicyclic enones, (7R,7aR)- and (7S,7aS)-9, from the hemiacetal 2a, which we first synthesized from the symmetrical diketone 1a via diastereoselective carbon-oxygen bond formation between one of the carbonyl groups and the chiral alcohol on the C2 side chain in a 2,2-disubstituted 1,3-cycloalkanedione derivative. We also report the total synthesis of natural (+)-lycopladine A [(+)-6] from (7R,7aR)-9 and the formal synthesis of unnatural (-)-lycopladine A [(-)-6] from (7S,7aS)-9. 相似文献
20.
We have employed IR-UV double resonance spectroscopy to identify the tautomeric and isomeric structures of uric acid and its monohydrated clusters which are produced by the techniques of laser-desorption and supersonic-jet cooling. The IR spectrum obtained for bare uric acid exhibits four distinct NH stretching transitions assignable to those of the most stable triketo form. We have also observed the two most stable monohydrated clusters, each with uric acid in the triketo form and water bonded to either the N3H or N9H site. It is demonstrated that the R2PI spectra of these monohydrates can be separated by using the IR-purified spectroscopic method. 相似文献