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51.
Catalytic synthesis of 2-substituted benzothiazoles from thiobenzanilides was achieved in the presence of a palladium catalyst through C-H functionalization/C-S bond formation. This method features the use of a novel catalytic system consisting of 10 mol % of Pd(II), 50 mol % of Cu(I), and 2 equiv of Bu4NBr that produced variously substituted benzothiazoles in high yields with good functional group tolerance. 相似文献
52.
Roman V. Shpanchenko Alexander A. Tsirlin Evgeny V. Antipov Joke Hadermann Hiroya Sakurai 《Journal of solid state chemistry》2008,181(9):2433-2441
The new complex germanates RCrGeO5 (R=Nd-Er, Y) have been synthesized and investigated by means of X-ray powder diffraction, electron microscopy, magnetic susceptibility and specific heat measurements. All the compounds are isostructural and crystallize in the orthorhombic symmetry, space group Pbam, and Z=4. The crystal structure of RCrGeO5, as refined using X-ray powder diffraction data, includes infinite chains built by edge-sharing Cr+3O6 octahedra with two alternating Cr−Cr distances. The chains are combined into a three-dimensional framework by Ge2O8 groups consisting of two edge-linked square pyramids oriented in opposite directions. The resulting framework contains pentagonal channels where rare-earth elements are located. Thus, RCrGeO5 germanates present new examples of RMn2O5-type compounds and show ordering of Cr+3 and Ge+4 cations. Electron diffraction as well as high-resolution electron microscopy confirm the structure solution. Magnetic susceptibility data for R=Nd, Sm, and Eu are qualitatively consistent with the presence of isolated 3d (antiferromagnetically coupled Cr+3 cations) and 4f (R+3) spin subsystems in the RCrGeO5 compounds. NdCrGeO5 undergoes long-range magnetic ordering at 2.6 K, while SmCrGeO5 and EuCrGeO5 do not show any phase transitions down to 2 K. 相似文献
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A new method for analyzing and visualizing the molecular excited states, named "excited state paired interacting orbital (EPIO)," is proposed. The method is based both on the paired interacting orbital (PIO) proposed by Fujimoto and Fukui [J. Chem. Phys. 60, 572 (1974)] and the natural transition orbital (NTO) by Martin [J. Chem. Phys. 118, 4775 (2003)]. Within the PIO method, orbital interactions between the two fragmented molecules are represented practically only by a few pairs of fragment orbitals. The NTO method is a means of finding a compact orbital representation for the electronic transitions in the excited states. With the method, electronic transitions are expressed by a few particle-hole orbital pairs and a clear picture on the electronic transitions is obtained. EPIO method is designed to have both properties of the preceding two methods: electronic transitions in composite molecular systems can be expressed with a few pairs of EPIOs which are constructed with fragmented molecular orbitals (MOs). Excited state characters, such as charge transfer and local excitations, are analyzed by using EPIOs with their generation probabilities. Thus, the present method gives us clear information on the composition of MOs which play an important role in the molecular excitation processes, e.g., optical processes. 相似文献
57.
H Nakata DG Fedorov T Nagata S Yokojima K Ogata K Kitaura S Nakamura 《The Journal of chemical physics》2012,137(4):044110
A consideration of the surrounding environment is necessary for a meaningful analysis of the reaction activity in large molecular systems. We propose an approach to perform unrestricted Hartree-Fock (UHF) calculations within the framework of the fragment molecular orbital (FMO) method (FMO-UHF) to study large systems with unpaired electrons. Prior to an energy analysis one has to optimize geometry, which requires an accurate analytic energy gradient. We derive the FMO-UHF energy and its analytic gradient and implement them into GAMESS. The performance of FMO-UHF is evaluated for a solvated organic molecule and a solvated metal complex, as well as for the active part of a protein, in terms of energy, gradient, and geometry optimization. 相似文献
58.
Hiroya Nakao 《The European physical journal. Special topics》2014,223(12):2411-2421
Dynamics of the complex Ginzburg-Landau equation describing networks of diffusively coupled limit-cycle oscillators near the Hopf bifurcation is reviewed. It is shown that the Benjamin-Feir instability destabilizes the uniformly synchronized state and leads to non-uniform pattern dynamics on general networks. Nonlinear dynamics on several network topologies, i.e., local, nonlocal, global, and random networks, are briefly illustrated by numerical simulations. 相似文献
59.
Time course experiment revealed that cultured plant cells of Eucalyptus perriniana regioselectively glucosylated silybin to silybin-23-beta-D-glucoside in up to 70% yield. 相似文献
60.
Hatakeyama M Nakata H Wakabayashi M Yokojima S Nakamura S 《The journal of physical chemistry. A》2012,116(26):7089-7097
A new mechanism of the oxygen evolving reaction catalyzed by [H(2)O(terpy)Mn(μ-O)(2)Mn(terpy)OH(2)](3+) is proposed by using density functional theory. This proton coupled electron transfer (PCET) model shows reasonable barriers. Because in experiments excess oxidants (OCl(-) or HSO(5)(-)) are required to evolve oxygen from water, we considered the Mn(2) complex neutralized by three counterions. Structure optimization made the coordinated OCl(-) withdraw a H(+) from the water ligand and produces the reaction space for H(2)O(2) formation with the deprotonated OH(-) ligand. The reaction barrier for the H(2)O(2) formation from OH(-) and protonated OCl(-) depends significantly on the system charge and is 14.0 kcal/mol when the system is neutralized. The H(2)O(2) decomposes to O(2) during two PCET processes to the Mn(2) complex, both with barriers lower than 12.0 kcal/mol. In both PCET processes the spin moment of transferred electrons prefers to be parallel to that of Mn 3d electrons because of the exchange interaction. This model thus explains how the triplet O(2) molecule is produced. 相似文献