全文获取类型
收费全文 | 579篇 |
免费 | 26篇 |
国内免费 | 3篇 |
专业分类
化学 | 434篇 |
晶体学 | 4篇 |
力学 | 8篇 |
数学 | 52篇 |
物理学 | 110篇 |
出版年
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 2篇 |
2019年 | 6篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 22篇 |
2015年 | 16篇 |
2014年 | 18篇 |
2013年 | 36篇 |
2012年 | 42篇 |
2011年 | 48篇 |
2010年 | 24篇 |
2009年 | 20篇 |
2008年 | 33篇 |
2007年 | 19篇 |
2006年 | 38篇 |
2005年 | 24篇 |
2004年 | 24篇 |
2003年 | 26篇 |
2002年 | 20篇 |
2001年 | 10篇 |
2000年 | 5篇 |
1999年 | 4篇 |
1998年 | 10篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1992年 | 6篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 9篇 |
1988年 | 4篇 |
1986年 | 4篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 6篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1970年 | 2篇 |
排序方式: 共有608条查询结果,搜索用时 609 毫秒
71.
Yoshinori Kamiya Yasutoshi Naito Takuji Hirose Keishin Mizoguchi 《Journal of Polymer Science.Polymer Physics》1990,28(8):1297-1308
Sorption of N2, O2, Ar, CH4, CO2, C2H4, and C2H6 in poly (dimethyl siloxane) liquid and rubber and the dilation of the polymers due to sorption of the gases are studied at 25°C under pressures up to 50 atm. In the liquid, the sorption isotherms for low-solubility and high-solubility gases are described by Henry's law and the Flory–Huggins equation, respectively. Gas sorption in the rubber, which contains a 29 wt % silica filler, follows the dual-mode sorption model, though marked hysteresis is observed in the sorption of O2 and CH4. The dilation isotherms increase linearly or exponentially in both polymers with increasing pressure. Considering that gas molecules adsorbed into micropores of the filler particles do not participate in the dilation, partial molar volumes of the dissolved gases in the rubber are determined from data of sorption and dilation. The values are nearly equal to the partial molar volumes in the liquid (48–60 cm3/mol). 相似文献
72.
Toshihiko Sakurai Maki Horikawa Makoto Takafuji Atsushi Kubo Hirotaka Ihara 《Applied Surface Science》2006,253(2):869-873
An l-glutamic acid-derived lipid with a terminal thiol has been synthesized and its corresponding self-assembled structure on Au(1 1 1) surfaces described. The surface morphology of the lipid self-assembled monolayer (SAM) exhibits nano-order patterning, where the height of the monolayer (approximately 1.5 nm) could be interpreted as due to the monolayer structure estimated from molecular models. The molecular orientation in the monolayer is almost perpendicular to the Au(1 1 1) surface depending on the three-point hydrogen-bonding sites in the molecule. 相似文献
73.
74.
Brownian dynamics simulations of shear flows are carried out for various suspensions of ellipsoids interacting via the Gay-Berne
potential. In this simulation all the systems of the suspension are in a liquid crystalline phase at rest. In a shear flow
they exhibit various motions of the director depending on the shear rate: the continuous rotation, the intermittent rotation,
the wagging-like oscillation, and the aligning. The director is almost always out of the vorticity plane when it rotates,
that is the kayaking. The number density of the system and the inter-particle potential intensity significantly affect the
shear rate dependence of orientation. In particular, the continuous rotation of director is maintained to higher shear rates
for the system with a stronger potential. Furthermore, the rheological properties are examined. The shear-thinning in viscosity
is observed, but the negative first normal difference is not obtained. 相似文献
75.
Prof. Dr. K. Mizoguchi Dr. K. Shirakawa 《Archive of Applied Mechanics (Ingenieur Archiv)》1980,49(2):107-117
Summary The analytical method is presented for a cylindrical shell with spiral groove. The governing equations of cylindrical shell
derived by one of the authors are introduced and Kirchhoff's boundary conditions along any smooth path are deduced from the
principle of energy. The analysis is carried out for a cylindrical shell under a uniform bending moment by considering the
equilibrium conditions of a shell element. Numerical results are given for various geometrical parameters of cylindrical shell
and the angle of the spiral groove, some of which are confirmed by an experiment.
übersicht Die analytische Methode wird für eine Kreiszylinderschale mit spiraler Fuge entwickelt. Die von einem der Verfasser eingeführten Differentialgleichungen der Kreiszylinderschale und die Kirchhoffschen Randbedingungen l?ngs des beliebig geneigten Randes, die vom Prinzip der Energie hergeleitet wurden, werden angegeben. Das Problem der Kreiszylinderschale mit spiraler Fuge unter einem uniformen Biegemoment wird unter Berücksichtigung der komplizierten Gleichgewichtsbedingungen der Schalenelemente analysiert. Die numerischen Ergebnisse zeigen gute übereinstimmung mit experimentellen Ergebnissen.相似文献
76.
Mingliang Zhang Abul K. Mallik Makoto Takafuji Hirotaka Ihara Hongdeng Qiu 《Analytica chimica acta》2015
Ionic liquids (ILs), a class of unique substances composed purely by cation and anions, are renowned for their fascinating physical and chemical properties, such as negligible volatility, high dissolution power, high thermal stability, tunable structure and miscibility. They are enjoying ever-growing applications in a great diversity of disciplines. 相似文献
77.
Hiroshi Mizoguchi SangWon Park Haruhiro Hiraka Kazutaka Ikeda Toshiya Otomo Hideo Hosono 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2015,127(10):2975-2978
Using a high pressure technique and the strong donating nature of H−, a new series of tetragonal La2Fe2Se2O3‐type layered mixed‐anion arsenides, Ln2M2As2Hx, was synthesized (Ln=La or Sm, M=Ti, V, Cr, or Mn; x≈3). In these compounds, an unusual M2H square net, which has anti CuO2 square net structures accompanying two As3− ions, is sandwiched by (LaH)2 fluorite layers. Notably, strong metal–metal bonding with a distance of 2.80 Å was confirmed in La2Ti2As2H2.3, which has metallic properties. In fact, these compounds are situated near the boundary between salt‐like ionic hydrides and transition‐metal hydrides with metallic characters. 相似文献
78.
Hirotaka Fujita Qingrong Qian Takao Fujii Kazuhiro Mochizuki Akiyoshi Sakoda 《Adsorption》2011,17(5):869-879
A novel bioethanol separation process was proposed in this study employing molecular sieving carbon (MSC) as an adsorbent,
whose pore diameter is close to molecular size of ethanol. In the proposed process, fermentation broth is first introduced
to the adsorption bed packed with MSC. In this step, ethanol is selectively adsorbed onto MSC, with highly enriching ethanol
in the micropore of MSC. Subsequently, the concentrated ethanol is desorbed from MSC to gaseous phase, resulting in further
purification of ethanol owing to a considerable difference in desorption rate between water and ethanol; Because of molecular
sieving effect of MSC, the desorption rate of ethanol is much smaller than that of water. To establish this process, adsorption
equilibrium and kinetics of ethanol on various MSCs were investigated in aqueous phase as the first step. Also, desorption
kinetics of ethanol and water in gaseous phase were investigated. As a result, it was suggested that highly concentrated ethanol
could be obtained with high recovery ratio through these simple operations, meaning the proposed process is quite promising. 相似文献
79.
Noriko Mizoguchi 《Journal of Differential Equations》2011,250(1):26-32
A solution u of a Cauchy problem for a semilinear heat equation
80.
This paper is concerned with blowup of positive solutions to a Cauchy problem for a parabolic-elliptic system