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91.
Shundo A Nakashima R Fukui M Takafuji M Nagaoka S Ihara H 《Journal of chromatography. A》2006,1119(1-2):115-119
Poly(octadecylacrylate) having plural trimethoxysilyl groups in the side chain (co-ODA(n)) was newly synthesized and immobilized onto silica through these groups. The liquid chromatographic behavior of silica-supported co-ODA(n) (Sil-co-ODA(n)) was investigated and compared with that of Sil-ODA(n), in which poly(octadecylacrylate) was immobilized through a terminal trimethoxy group at one side of the polymer main chain. Sil-co-ODA(n) showed higher selectivity for molecular shape, especially molecular planarity of PAHs than Sil-ODA(n). 相似文献
92.
93.
Hirotaka Kudo Marvin L. Tedjamulia Raymond N. Castle Milton L. Lee 《Journal of heterocyclic chemistry》1984,21(1):185-192
We describe the synthesis of thieno[2,3-c]dibenzothiophene ( 6 ), thieno[3,2-c]dibenzothiophene ( 10 ), thieno-[3,2-a]dibenzothiophene ( 14 ), thieno[2,3-a]dibenzothiophene ( 16 ), benzo[1,2-b:4,3-b]bisbenzo[b]thiophene ( 18 ), benzo[1,2--6:3,4-b]bisbenzo[b]thiophene ( 20 ), benzo[2,1--6:3,4-b]bisbenzo[b]thiophene ( 22 ), benzo[1,2-b:3,4-g]bisbenzo[b]thiophene ( 27 ), benzo[1,2-b:4,3-e]bisbenzo[b]thiophene ( 29 ), benzo[2,1--6:3,4-g]bisbenzo[b]thiophene ( 36 ), benzo[2,1--6:4,3-e]bisbenzo[b]thiophene ( 38 ), benzo[1,2--6:4,3-g]bisbenzo[b]thiophene ( 41 ), benzo[1,2-b:4,5-g]bisbenzo[b]thiophene ( 42 ), benzo[1,2-b:3,4-e]bisbenzo[b]thiophene ( 44 ) and benzo-[1,2-b:5,4-e]bisbenzo[b]thiophene ( 45 ). 相似文献
94.
Marvin L. Tedjamulia Hirotaka Kudo Raymond N. Castle Milton L. Lee 《Journal of heterocyclic chemistry》1984,21(2):321-325
The syntheses of naphtho[1,2–6:7,6-b′]bisbenzo[b]thiophene ( 4 ), naphtho[1,2–6:7,8-b′]bisbenzo[b]thiophene ( 5 ), naphtho[2,1-b:7,6-b′]bisbenzo[b]thiophene ( 8 ), naphtho[2,1-b:7,8-b′]bisbenzo[b]thiophene ( 9 ), naphtho-[1,2–6:5,6-b′]bisbenzo[b]thiophene ( 14 ), naphtho[1,2–6:6,5-b]bisbenzo[b]thiophene ( 17 ) and naphtho[2,1–6:-6,5-b′]bisbenzo[b]thiophene ( 23 ) are reported. 相似文献
95.
Hirotaka Kudo Marvin L. Tedjamulia Raymond N. Castle Milton L. Lee 《Journal of heterocyclic chemistry》1984,21(6):1833-1839
The synthesis of phenanthro[1,2-c]dibenzothiophene (6) , phenanthro[4,3-c]dibenzothiophene (10) , phenanthro[2,1-a]dibenzothiophene (14) , phenanthro[3,4-a]dibenzothiophene (16) , phenanthro[1,2-a]dibenzothiophene (19) , phenanthro[2,1-b]dibenzothiophene (20) , 8-methylphenanthro[3,2-a]dibenzothiophene (24) , 7-methylphenanthro[1,2-a]dibenzothiophene (25) , phenanthro[3,4-a]dibenzothiophene (27) , phenanthro[4,3-a]-dibenzothiophene (28) , 6-methylphenanthro[2,3-a]dibenzothiophene (31) , and 5-methylphenanthro[4,3-a]dibenzothiophene (32) is described. 相似文献
96.
Derivatization of tributyltin for tandem mass spectrometry is described. Tributyltin (TBT) and triphenyltin (TPT) were derivatized with sodium tetrakis(4-fluorophenyl)borate. After optimization of their MS/MS conditions, derivatization conditions were examined. Under the optimum conditions using in-situ derivatization, the calibration curves for the TBT and TPT were linear in the ranges of 0.4 - 200 and 1.2 - 200 pg of Sn, respectively. The detection limits for TBT and TPT were 0.07 and 0.43 pg of Sn, respectively. In the case of TBT, the detection limit with 4-fluorophenylation was improved about five times compared with that with pentylation (0.35 pg). This improvement is ascribed to the bond-dissociation energy of Sn-aryl being stronger than that of Sn-alkyl. Namely, the selective fragmentation of 4-fluorophenyl TBT resulted in high sensitivity. The relative recoveries of TBT and TPT from seawater were 99 and 109%, respectively. The method was successfully applied to the seawater samples. 相似文献
97.
H. Imajo K. Hayasaka R. Ohmukai M. Watanabe S. Urabe 《Applied physics. B, Lasers and optics》1995,61(3):285-289
Be+ ions trapped in a Penning trap are laser-cooled to about 10 mK. The excitation spectra of ion clouds containing about 500 ions are obtained by scanning the frequency of the cooling laser and discontinuities in these spectra are observed because of phase transitions. When the cooled ions are heated electrically by applying an rf voltage, no phase transition occurs and the spectra become continuous. Two-dimensional measurement of the ion clouds is carried out and the abrupt change in the shape of the ion cloud due to the phase transition is observed. When many ions are trapped and cooled, the phase transition occurs partially and a transient state where two states are mixed can be observed. The static properties of the ions are also measured by using an additional probe laser and the results of experimental measurements are compared with theoretical predictions. 相似文献
98.
The decay of one monolayer gold atoms at the nickel surface by bombardment with 5 keV Ar+ ions at room temperature has been studied by means of the RBS technique. It is found that the gold concentration decreases bi-exponentially with increasing ion fluence. It is shown that the fast decay component gives the removal cross-section which is the summation of the desorption and the recoil-implantation cross-sections. The recoil-implantation cross-section is evaluated from the difference between the removal cross-section and the desorption cross-section obtained at a previous high-temperature experiment. 相似文献
99.
M. J. Musmar Gary E. Martin Robert T. Gampe Milton L. Lee Ralph E. Hurd Marvin L. Tedjamulia Hirotaka Kudo Raymond N. Castle 《Journal of heterocyclic chemistry》1985,22(1):219-223
Total assignment of the 13C-nmr spectrum of the helical molecule phenanthro[4,3-a]dibenzothiophene at 125.762 MHz is reported. Assignments were made by the combined application of 13C-13C autocorrelated double quantum coherence and heteronuclear relayed coherence transfer (RELAY) experiments. 相似文献
100.
Two diastereomers of 3,3′-di-t-butyl-1,1′-spirobi[benz[g]indan] have been prepared; c.d. spectral evidence is presented for the difference between their conformations. 相似文献