全文获取类型
收费全文 | 6447篇 |
免费 | 205篇 |
国内免费 | 25篇 |
专业分类
化学 | 5013篇 |
晶体学 | 77篇 |
力学 | 114篇 |
数学 | 499篇 |
物理学 | 974篇 |
出版年
2022年 | 45篇 |
2021年 | 56篇 |
2020年 | 75篇 |
2019年 | 95篇 |
2018年 | 57篇 |
2017年 | 43篇 |
2016年 | 112篇 |
2015年 | 107篇 |
2014年 | 147篇 |
2013年 | 308篇 |
2012年 | 352篇 |
2011年 | 382篇 |
2010年 | 211篇 |
2009年 | 205篇 |
2008年 | 399篇 |
2007年 | 416篇 |
2006年 | 436篇 |
2005年 | 362篇 |
2004年 | 334篇 |
2003年 | 301篇 |
2002年 | 271篇 |
2001年 | 90篇 |
2000年 | 81篇 |
1999年 | 75篇 |
1998年 | 55篇 |
1997年 | 89篇 |
1996年 | 86篇 |
1995年 | 46篇 |
1994年 | 62篇 |
1993年 | 55篇 |
1992年 | 49篇 |
1991年 | 52篇 |
1990年 | 35篇 |
1989年 | 32篇 |
1988年 | 43篇 |
1987年 | 42篇 |
1986年 | 38篇 |
1985年 | 84篇 |
1984年 | 91篇 |
1983年 | 41篇 |
1982年 | 85篇 |
1981年 | 80篇 |
1980年 | 76篇 |
1979年 | 74篇 |
1978年 | 71篇 |
1977年 | 55篇 |
1976年 | 63篇 |
1975年 | 42篇 |
1974年 | 44篇 |
1973年 | 64篇 |
排序方式: 共有6677条查询结果,搜索用时 31 毫秒
951.
Yumiko Sano Keishi Kato Masaaki Yokoyama Yasuhiko Shirota Hiroshi Mikawa 《Molecular Crystals and Liquid Crystals》2013,570(1-2):137-141
Glass-forming properties of 2-pyrazoline derivatives were examined and discussed in terms of the molecular structure. The results show that the molecular shape of 1,3,5-triaryl-2-pyrazolines is responsible for the glass-forming properties of these compounds. Glass transition points of several 1,3,5-triaryl-2-pyrazoline derivatives were measured. 相似文献
952.
Kenichi Imaeda Hiroo Inokuchi Kenji Ichimura Shinichi Inoue Satoshi Nakakita Hiroshi Okamoto 《Molecular Crystals and Liquid Crystals》2013,570(1):667-670
Abstract Solid state 1H NMR of (KH)3C60 was measured in the temperature range between ?80 and 60 °C. A doublet spectrum composed of main peak at ?7.0 ppm and shoulder peak at ~0 ppm was observed at room temperature. The negative chemical shift of the main peak indicates that hydrogen in (KH)3C60 exists as a hydride-like ion. The 60 °C spectrum became singlet at ?5.8 ppm due to motional narrowing. 相似文献
953.
Hiroshi Negishi Saiko Negishi Minoru Sasaki Masasi Inoue Shigeo Ohara 《Molecular Crystals and Liquid Crystals》2013,570(2):63-68
Abstract EXAFS and XANES spectra of Ti K-edge have been measured for 3d transition metal intercalation compounds M x TiS2 (M = Mn, Fe, Co and Ni; x ≤ 0.33). We have found that the interatomic distance between Ti and the first nearest neighbor S atoms, R(Ti-S), increases with the guest concentration x. The variation in XANES spectra with x reveals the reduction of the valence state of Ti atoms upon intercalation of M. From these results as well as the M K-edge EXAFS data studied previously, we have proposed a simple model on the local structure of M x TiS2 to reproduce the observed values of R(Ti-S) by averaging local shift of S atoms caused by intercalation. 相似文献
954.
Effects of pressure and temperature on the solubility of monosodium L-glutamate monohydrate in water
Yoshihisa Suzuki Hiroshi Matsuo Yoshikata Koga Katsuya Mukae Tetsuya Kawakita Seiji Sawamura 《高压研究》2013,33(2):93-104
Abstract The solubility of monosodium L-glutamate monohydrate (MSG.H2O) in water was measured at pressures in the range of 0.10-300MPa and 298.15K. The density of MSG solution at high concentrations and heat of solution at saturated concentration were also measured at atmospheric pressure. The solubility, ms, increased with increasing pressure and the pressure coefficient, Θp, [?(? In ms,? p)T] at 0.10 MPa was (2.0 ± 0.1) × 10-10Pa-1. It agrees well with (2.1 ±0.2)× 10-10 Pa-1 thermodynamically estimated using the partial molar volume, the activity coefficient of the solute in solution, and the molar volume of the crystal. The excellent agreement at 0.10MPa gives us confidence in the solubility data at higher pressures. The heat of solution data and other pertinent values were used to calculate the temperature coefficient of solubility, ΘT [? (? In ms/?(1/T))p], by a thermodynamic equality. The resulting ΘT compares well with the data directly measured by Ogawa. 相似文献
955.
956.
Abstract Energy loss spectra of 1000 keV electrons transmitted by [111]-: riented thin silicon crystals were observed by an energy analyzer attached to the HVEM. The crystals were set to the systematic 220 Bragg reflection. Measurements were made for crystal thickness ranging from 1000 to 10,000 Å, which were determined by observations of pendellösung fringes. Results were analyzed with Landau's transport equation, giving the : onclusion that the loss probability, which is the reciprocal of the mean free path, is 0.52 ± 0.02 × 10?3 A?1 for plasmon excitation and 1.50 ± 0.02 × 10?3 A?1 for L-electron excitation. 相似文献
957.
We study a curvature-dependent motion of plane curves in a two-dimensional infinite cylinder with spatially undulating boundary. The law of motion is given by V=κ+A, where V is the normal velocity of the curve, κ is the curvature, and A is a positive constant. The boundary undulation is assumed to be almost periodic, or, more generally, recurrent in a certain sense. We first introduce the definition of recurrent traveling waves and establish a necessary and sufficient condition for the existence of such traveling waves. We then show that the traveling wave is asymptotically stable if it exists. Next we show that a regular traveling wave has a well-defined average speed if the boundary shape is strictly ergodic. Finally we study what we call “virtual pinning”, which means that the traveling wave propagates over the entire cylinder with zero average speed. Such a peculiar situation can occur only in non-periodic environments and never occurs if the boundary undulation is periodic. 相似文献
958.
Hiroshi Nagase 《代数通讯》2013,41(10):4561-4577
We count the number of isomorphism classes of hom-orthogonal partial tilting modules over path algebras of Dynkin quiver of type 𝔸 n , 𝔻 n , 𝔼 n . This number is independent on the choice of an orientation of the arrows, and the number for 𝔸 n or 𝔻 n -type can be expressed as a special value of a hypergeometric function. As a consequence of our theorem, we obtain a minimum value of the number of basic relative invariants of corresponding regular prehomogeneous vector spaces. 相似文献
959.
960.
This paper discusses an alternative criterion for estimating the baseband transfer function of multimode optical fibers. The optical fibers having little mode conversions show that the baseband frequency characteristics are affected strongly by the launching condition of an input optical pulse. In the criterion presented here, the baseband transfer function in such fibers is estimated by considering the launching condition that excites all fiber modes uniformly in amplitudes. In order to obtain such a transfer function, the actual responses affected by the launching conditions are measured together with the modal power distributions for different kinds of launching conditions. A numerical procedure is then presented that enables us to derive the baseband transfer function independently of modal power distributions. Experimental results at λ x= 633 nm and 856 nm are presented for step index fibers (0.1 and 0.2 km long) having a core radius of 30 pm (its refractive index is 1.452) and a refractive index difference of 0.7%. 相似文献