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911.
A TiO2(1 1 0)-(1 × 1) surface was prepared in an ultra-high vacuum, transported in laboratory air, and observed with a scanning tunneling microscope (STM) operated in a vacuum of 10−4 Pa. Empty state images showed atomically flat terraces separated by single-height steps, on which 5-fold-coordinated surface Ti atoms were observed as spots arranged in a rectangular lattice. The Ru(4,4′-dicarboxy-2,2′-bipyridine)2(NCS)2 (N3) dye was adsorbed on the TiO2 surface by immersing the TiO2 wafer into an acetonitrile solution of the dye. In the empty state images, individual N3 molecules were observed as oval particles protruding by 0.6 nm from the TiO2 surface. The oval shape elongated to the [1 0] directions was attributed to electron tunneling from tip to unoccupied states localized at the two carboxyl groups bound to the TiO2 surface. 相似文献
912.
Tokiyoshi Matsuda Mamoru Furuta Takahiro Hiramatsu Hiroshi Furuta Chaoyang Li Takashi Hirao 《Applied Surface Science》2010,256(21):6350-2485
Thermal stability of sputter deposited ZnO thin films was evaluated by thermal desorption spectroscopy (TDS). Desorption of Zn was mainly observed from the films deposited at low O2/Ar gas ratio and low RF power. In contrast, O2 desorption was mainly observed from the films deposited at high O2/Ar gas ratio and high RF power. The amount of desorbed O2 from the film increased with increasing the O2/Ar gas flow ratio and the RF power. Furthermore, the desorption temperature of O2 increased with increasing the RF power during the deposition. Thermal stability of the ZnO films was controlled not only by the O2/Ar gas flow ratio, but also applied RF power to the target. 相似文献
913.
914.
Michiya Kobayashi Hiroshi Yabe 《Journal of Computational and Applied Mathematics》2010,234(2):375-397
In this paper, we deal with conjugate gradient methods for solving nonlinear least squares problems. Several Newton-like methods have been studied for solving nonlinear least squares problems, which include the Gauss-Newton method, the Levenberg-Marquardt method and the structured quasi-Newton methods. On the other hand, conjugate gradient methods are appealing for general large-scale nonlinear optimization problems. By combining the structured secant condition and the idea of Dai and Liao (2001) [20], the present paper proposes conjugate gradient methods that make use of the structure of the Hessian of the objective function of nonlinear least squares problems. The proposed methods are shown to be globally convergent under some assumptions. Finally, some numerical results are given. 相似文献
915.
Ikeda T Fujiyoshi S Kato H Kudo A Onishi H 《The journal of physical chemistry. B》2006,110(15):7883-7886
Electrons photoexcited in K(3)Ta(3)B(2)O(12), an efficient photocatalyst for the water-splitting reaction driven by ultraviolet light, were observed using time-resolved IR absorption spectroscopy with microsecond resolution. When the catalyst was irradiated with 266 nm light pulses, a structureless absorption appeared at 3000-1500 cm(-1). The absorption was assigned to the optical transition of electrons that were band gap-excited and then trapped in mid-gap states. The absorbance decayed with a time delay because of the electron-hole recombination. The rate of recombination in an argon atmosphere was sensitive to the composition of the starting material used in the catalyst preparation. The electron decay was accelerated by exposing the catalyst to water vapor. The degree of acceleration was qualitatively correlated with the H(2) production rate observed during steady-state light irradiation. 相似文献
916.
Shimada T Kondoh H Iwasaki M Nakai I Nagasaka M Amemiya K Orita H Ohta T 《The journal of physical chemistry. B》2006,110(41):20507-20512
The adsorption structure of NO on the reconstructed Pt(110)-(1 x 2) surface was studied with X-ray photoelectron spectroscopy (XPS), X-ray photoelectron diffraction (XPD), low-energy scanned-angle photoelectron diffraction (LESA-PD), and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. The experiments were performed at 180 K, where no surface lifting from (1 x 2) to (1 x 1) takes place after NO adsorption. XPS indicates that the (1 x 2) unit cell of the Pt(110) surface contains 1.5 NO molecules at the saturated coverage. XPD and LESA-PD analyses allow us to propose a structural model for the NO adlayer, where two-thirds of the NO molecules in the (1 x 2) unit cell are adsorbed on the atop site of the close-packed Pt rows (ridges) along the [10] direction with an inclined geometry and one-third of the NO molecules adsorb on the bridge site between the Pt ridges with an upright configuration. This model is supported by the N K-edge NEXAFS experiments and is consistent with the recently reported model based on the density functional theory (Orita, H.; Nakamura, I.; Fujitani, T. J. Phys. Chem. B 2005, 109, 10312). 相似文献
917.
Sahoo AK Nakamura Y Aratani N Kim KS Noh SB Shinokubo H Kim D Osuka A 《Organic letters》2006,8(18):4141-4144
Highly efficient synthesis of meso,meso-dibromo doubly and triply fused diporphyrins has been achieved through a powerful oxidative coupling mediated by AuCl3-AgOTf combination. In addition, palladium-catalyzed debromination of meso-bromoporphyrins has been developed. This debromination protocol enables employment of bromine as a protecting group for the reactive meso-position of porphyrins. 相似文献
918.
A facile approach for synthesis of bipolar oligofluorenes, TAZ-OF(n)-NPh, n = 2 or 3 end-capped with hole-transporting diphenylamino and electron-transporting triazole moieties by Suzuki cross-coupling as the key reaction has been developed. This novel bipolar oligofluorenes exhibited blue-emission, high thermal and morphological stabilities. The single-layer OLED based on TAZ-OF(2)-NPh exhibited superior device performance with a maximum luminance of 1128 cd m(-2) and luminance efficiency of up to 0.83 cd A(-1). 相似文献
919.
Stereoisomeric bicyclic tert-alcohols afforded identical ring-expansion products via cationic anti-Markovnikov rearrangement from perpendicular tert-cations into identical six-membered ring secondary cations by the treatment with TiCl4. These results provide evidence that the reaction takes place by the cationic stepwise mechanism. [reaction: see text] 相似文献
920.
A magnetic vortex core in a ferromagnetic circular nanodot has a resonance frequency originating from the confinement of the vortex core. By the micromagnetic simulation including the spin-transfer torque, we show that the vortex core can be resonantly excited by an ac (spin-polarized) current through the dot and that the resonance frequency can be tuned by the dot shape. The resistance measurement under the ac current successfully detects the resonance at the frequency consistent with the simulation. 相似文献