全文获取类型
收费全文 | 10040篇 |
免费 | 233篇 |
国内免费 | 45篇 |
专业分类
化学 | 7292篇 |
晶体学 | 124篇 |
力学 | 173篇 |
数学 | 733篇 |
物理学 | 1996篇 |
出版年
2022年 | 78篇 |
2021年 | 79篇 |
2020年 | 116篇 |
2019年 | 140篇 |
2018年 | 88篇 |
2017年 | 69篇 |
2016年 | 158篇 |
2015年 | 167篇 |
2014年 | 205篇 |
2013年 | 505篇 |
2012年 | 508篇 |
2011年 | 572篇 |
2010年 | 315篇 |
2009年 | 328篇 |
2008年 | 580篇 |
2007年 | 615篇 |
2006年 | 621篇 |
2005年 | 522篇 |
2004年 | 437篇 |
2003年 | 417篇 |
2002年 | 409篇 |
2001年 | 183篇 |
2000年 | 187篇 |
1999年 | 144篇 |
1998年 | 94篇 |
1997年 | 126篇 |
1996年 | 147篇 |
1995年 | 91篇 |
1994年 | 96篇 |
1993年 | 98篇 |
1992年 | 114篇 |
1991年 | 93篇 |
1990年 | 77篇 |
1989年 | 73篇 |
1988年 | 98篇 |
1987年 | 86篇 |
1986年 | 88篇 |
1985年 | 146篇 |
1984年 | 150篇 |
1983年 | 69篇 |
1982年 | 126篇 |
1981年 | 115篇 |
1980年 | 113篇 |
1979年 | 115篇 |
1978年 | 103篇 |
1977年 | 97篇 |
1976年 | 85篇 |
1975年 | 72篇 |
1974年 | 74篇 |
1973年 | 88篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
31.
32.
Hiroshi Sugimoto Hiromitsu Ohshima Shohei Inoue 《Journal of polymer science. Part A, Polymer chemistry》2003,41(22):3549-3555
The first successful example of the formation of polycarbonate from 1-atm carbon dioxide and epoxide was demonstrated by the alternating copolymerization of carbon dioxide and epoxide with manganese porphyrin as a catalyst. The copolymerization of carbon dioxide and cyclohexene oxide with (porphinato)manganese acetate proceeded under the 1-atm pressure of carbon dioxide to give a copolymer with an alternating sequence. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3549–3555, 2003 相似文献
33.
Hiroshi Sakurai Fumitake Itoh Katsuyoshi Takano Hiromi Oike 《Journal of Physics and Chemistry of Solids》2004,65(12):2083-2088
A novel technique of measuring a magnetic Compton profile using the grazing angle geometry against a sample surface (Grazing Incidence Magnetic Compton Profile) has been successively developed. Measurements of a magnetic moment and a magnetic Compton profile are possible for a Fe 200 nm film on a thick glass substrate. The estimated thinnest limit for measurements is 100 nm for a Fe film. 相似文献
34.
H. Kobayashi T. Sakurai Y. Yamashita T. Kubota O. Maida M. Takahashi 《Applied Surface Science》2006,252(21):7700-7712
X-ray photoelectron spectroscopy (XPS) measurements under bias can observe low density interface states for metal-oxide-semiconductor (MOS) diodes with low densities. This method can give energy distribution of interface states for ultrathin insulating layers for which electrical measurements cannot be performed due to a high density leakage current. During the XPS measurements, a bias voltage is applied to the rear semiconductor surface with respect to the ∼3 nm-thick front platinum layer connected to the ground, and the bias voltage changes the occupation of interface states. Charges accumulated in the interface states shift semiconductor core levels at the interface, and thus the analysis of the bias-induced shifts of the semiconductor core levels measured as a function of the bias voltage gives energy distribution of interface states. In the case of Si-based MOS diodes, the energy distribution and density of interface states strongly depend on the atomic density of silicon dioxide (SiO2) layers and the interfacial roughness, respectively. All the observed interface state spectra possess peaked-structures, indicating that they are due to defect states. An interface state peak near the Si midgap is attributable to isolated Si dangling bonds at the interface, while those above and below the midgap to Si dangling bonds interacting weakly with Si or oxygen atoms in the SiO2 layers. A method of the elimination of interface states and defect states in Si using cyanide solutions has been developed. The cyanide method simply involves the immersion of Si in KCN solutions. Due to the high Si-CN bond energy of ∼4.5 eV, the bonds are not ruptured at 800 °C and upon irradiation. The cyanide treatment results in the improvement of the electrical characteristics of MOS diodes and solar cells. 相似文献
35.
Hiroshi Sato 《Journal of Theoretical Probability》1992,5(2):349-353
The aim of this paper is to characterize the nuclearity of an integral operator, defined by a continuous non-negative definite square integrable kernel on a separable metric space, in terms of the integrability of the trace of the kernel function. Nuclearity here plays a role forU-statistics. 相似文献
36.
K. Takamiya T. Fukunishi R. Tsujito S. Fukutani T. Takahashi S. Shibata S. Uchida 《Journal of Radioanalytical and Nuclear Chemistry》2007,273(1):195-198
The adsorption behavior of fission products to various soils was studied using a multitracer. The multitracer was prepared
by neutron irradiation of 235U. Distribution coefficients of fission products were obtained for seventeen kinds of Japanese soils. It was found that zirconium,
niobium, and rare earth elements show high distribution coefficients for all soil samples, however, elements like alkali metals
show varied values. 相似文献
37.
Fumie Takei Daisuke Kodama Sugiko Nakamura Kiyotaka Onitsuka Shigetoshi Takahashi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):585-595
Aryl isocyanides bearing free‐base and metallo‐porphyrins were prepared and polymerized with a Pd–Pt μ‐ethynediyl complex as the initiator to give polymers with narrow polydispersity indices. The molecular weights of the resulting polymers were precisely controlled by the initial feed ratio of the porphyrin monomer to the initiator. The UV–VIS spectra suggested that the porphyrin pendants are regularly arranged to form stacked columns. Metallo‐porphyrin polymers were also prepared by reacting free‐base porphyrin polymers with metal salts. The successive reactions of free‐base and zinc‐porphyrin monomers resulted in the formation of diblock polymers. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 585–595, 2006 相似文献
38.
39.
Hiroshi Aoki Ken Hosoya Tomohisa Norisuye Nobuo Tanaka Daisuke Tokuda Norio Ishizuka Kazuki Nakanishi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(2):949-958
An investigation was made of the gelation of dimethacrylate‐type crosslinking agents in view of an application for separation media. The study mainly centered on a crosslinking agent, glycerol dimethacrylate (GDMA), which is relatively hydrophilic because of a hydroxyl group in the middle of its structure. The gelation of GDMA was compared with that of other hydrophobic crosslinking agents such as ethylene glycol dimethacrylate and 1,6‐hexanediol dimethacrylate. The diluents used in the study were toluene, toluene with methanol, and cyclohexanol. The gelation was observed in real time with a charge coupled device camera and dynamic light scattering (DLS). Also, the separated dry gels were extensively characterized with scanning electron microscopy, BET (N2 absorption and desorption isotherm), and Fourier transform infrared. DLS analysis showed a stronger molecular interaction of GDMA gelation in toluene, whereas this interaction was much weaker in an alcoholic solvent such as toluene with methanol or cyclohexanol. This indicated that GDMA gelation might proceed through hydrogen bonding as well as a crosslinking reaction of vinyl groups. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 949–958, 2006 相似文献
40.
Kazuhiko Hashimoto Hiroshi Saito Ryo Ohsawa 《Journal of polymer science. Part A, Polymer chemistry》2006,44(16):4895-4903
Two kinds of new glycopolymers, (P(VB‐1‐GlcaH‐co‐AAm), 9 ) and (P(VB‐1‐Glco‐co‐AAm), 10 ), were synthesized through the radical copolymerization of styrene derivatives bearing pendant D ‐glucaric and D ‐gluconic moieties, N‐(p‐vinylbenzyl)‐1‐D ‐glucaramide (VB‐1‐GlcaH, 7 ), and N‐(p‐vinylbenzyl)‐D ‐gluconamide (VB‐1‐Glco, 8 ), with acrylamide (AAm). Glycopolymer 9 bearing the pendant glucaric moiety at the first position inhibited the hydrolysis of a model compound for xenobiotics‐β‐glucuronide conjugates, p‐nitrophenyl β‐D ‐glucuronide, uncompetitively, in contrast to the competitive inhibition in the presence of the corresponding isomeric glycopolymer bearing the pendant D ‐glucaric unit at the sixth position (P(VB‐6‐GlcaH‐co‐AAm), 3 ) reported in our previous article. On the other hand, another copolymer 10 bearing the gluconic moiety was found not to inhibit the hydrolysis as well as the corresponding copolymer bearing pendant gulonic unit (P(VB‐6‐Glco‐co‐AAm), 4 ). These results indicate that the hydrolysis is influenced not only by existence of pendant carboxyl units but also by the direction on the linkage of the glyco‐units to the polymer frame. Therefore the configurational position of hydroxy groups in pendant glyco‐units in macromolecular inhibitors may be essential for the interaction with β‐glucuronidase. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4895–4903, 2006 相似文献