全文获取类型
收费全文 | 784篇 |
免费 | 40篇 |
国内免费 | 1篇 |
专业分类
化学 | 725篇 |
晶体学 | 4篇 |
力学 | 3篇 |
数学 | 1篇 |
物理学 | 92篇 |
出版年
2023年 | 5篇 |
2022年 | 11篇 |
2021年 | 5篇 |
2020年 | 9篇 |
2019年 | 20篇 |
2018年 | 10篇 |
2017年 | 5篇 |
2016年 | 14篇 |
2015年 | 19篇 |
2014年 | 13篇 |
2013年 | 57篇 |
2012年 | 49篇 |
2011年 | 49篇 |
2010年 | 27篇 |
2009年 | 25篇 |
2008年 | 64篇 |
2007年 | 46篇 |
2006年 | 49篇 |
2005年 | 42篇 |
2004年 | 62篇 |
2003年 | 30篇 |
2002年 | 32篇 |
2001年 | 14篇 |
2000年 | 8篇 |
1999年 | 12篇 |
1998年 | 8篇 |
1997年 | 12篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 13篇 |
1992年 | 10篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 7篇 |
1983年 | 6篇 |
1982年 | 9篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 10篇 |
1978年 | 8篇 |
1977年 | 2篇 |
1976年 | 6篇 |
1974年 | 3篇 |
1972年 | 3篇 |
1970年 | 1篇 |
1967年 | 2篇 |
1964年 | 1篇 |
排序方式: 共有825条查询结果,搜索用时 15 毫秒
101.
Kitano H Suzuki H Kondo T Sasaki K Iwanaga S Nakamura M Ohno K Saruwatari Y 《Macromolecular bioscience》2011,11(4):557-564
A CMB monomer was polymerized on a glass plate with a surface-confined ATRP initiator containing a 2-bromoisobutyryl group. The glass plate modified with a PCMB brush was highly hydrophilic and showed a strong resistance against non-specific adsorption of proteins and cell adhesion. Upon ion beam irradiation, furthermore, the PCMB brush was ablated and a hollow space with a designed shape could be made to which HEK293 cells (from human embryonic kidney) and Hep G2 (from human hepatoma) cells non-specifically adhered, while no adhesion of these cells to the non-treated area on the brush was observed. The present results clearly indicate the usefulness of ion beam-printed patterns of anti-biofouling zwitterionic polymer brushes in the biomedical field. 相似文献
102.
Kuwahara Y Nishizawa K Nakajima T Kamegawa T Mori K Yamashita H 《Journal of the American Chemical Society》2011,133(32):12462-12465
A new class of heterogeneous catalytic systems utilizing cation-guest interactions was designed based on microporous titanosilicate molecular sieves. Introducing heavier alkali metal cations on ion-exchange sites of the framework resulted in a significant enhancement of the catalytic activity for oxidation of cyclohexene and styrene, whereas such an enhancement was not observed in oxidation of cyclohexane without π systems. Distinct relationships between the catalytic activities and intermolecular interaction energies which were determined by IR spectroscopic and computational approaches clearly evidenced the predominance of the cation-π interaction in this catalytic system. 相似文献
103.
Suzuki IH Kono Y Ikeda A Ouchi T Ueda K Takahashi O Higuchi I Tamenori Y Nagaoka S 《The Journal of chemical physics》2011,134(8):084312
Spectator resonant KL(23)L(23) Auger electron spectra have been measured in the Si 1s photoexcitation region of Si(CH(3))(4) using monochromatized undulator radiation combined with a hemispherical electron spectrometer. The broad peak with high intensity in a total ion yield spectrum, coming mainly from excitation of a 1s electron into the 6t(2) vacant orbital, induces a spectator Auger decay in which the excited electron remains in its excited orbital. The component on the higher energy side of this peak through 1s excitation into a Rydberg orbital produces resonant Auger decays in which the excited Rydberg electron moves into a slightly higher Rydberg orbital, or is partly shaken up to a significantly higher Rydberg orbital. These findings of Si(CH(3))(4) indicate a clear contrast to those for SiF(4), in which the 1s excitation into a Rydberg orbital induces a shake-down phenomenon as well as a shake-up one. The results of these molecules exhibit a clear splitting effect among excited orbitals which are smeared out by overlapping due to lifetime widths and due to densely populated levels in the 1s electron excitation spectrum. This is consistent with the calculation on photoexcitation within the framework of density functional theory. 相似文献
104.
Miyazaki M Ando N Sugai K Seito Y Fukuoka H Kanemitsu T Nagata K Odanaka Y Nakamura KT Itoh T 《The Journal of organic chemistry》2011,76(2):534-542
A catalytic asymmetric allylation of 3,4-dihydroisoquinoline was carried out with allyltrimethoxylsilane-Cu as the nucleophile in the presence of DTBM-SEGPHOS as the chiral ligand to afford corresponding chiral 1-allyltetrahydroisoquinoline derivatives in good yield and stereoselectivity. The allyl adduct thus obtained was applied to the synthesis of several isoquinoline alkaloids such as crispine A and homolaudanosine. The reaction was further used for the synthesis of the isoquinoline moiety of schulzeine A. 相似文献
105.
Monitoring the aggregation processes of amyloid-β using a spin-labeled, fluorescent nitroxyl radical
Mito F Yamasaki T Ito Y Yamato M Mino H Sadasue H Shirahama C Sakai K Utsumi H Yamada K 《Chemical communications (Cambridge, England)》2011,47(17):5070-5072
Amyloid nitroxyl radical (nitroxide) ligands were used to detect amyloid-β fibrils, the main constituents of senile plaques in Alzheimer's disease, using anisotropic ESR spectra, and were found to affect the aggregation process due to the radical functionality. These compounds have great potential as novel and multifunctional probes, combining spin labels, spin probes, and fluorescence probes. 相似文献
106.
This paper describes a promising method to synthesize supported metal catalysts based on a photochromic reaction. Highly dispersed Ag nanoparticles (NPs) with a mean diameter of ca. 10 nm stabilized by 3-mercaptopropionic acid (3-MPA) were prepared as a colloidal precursor solution. The zeta electric potential was found to be negatively charged in the region of pH higher than 5 due to the presence of dissociated carboxylate ions (-COO(-)), which led to electric repulsion between Ag NPs and kept the solution in a highly dispersed colloidal state. In the presence of photochromic molecules, trans-2-hydroxychalcone, the photo-irradiation gradually decreased the electric charge on the nanoparticles owing to the formation of flavylium cations, which induced the assembly of Ag NPs. Such photo-induced assembly-dispersion control of Ag NPs enables size selective deposition on a catalyst support, which is controlled by varying the photo-irradiation time. 相似文献
107.
Hiromi Takiguchi Tamao Odake Tomonari Umemura Hiroki Hotta Kin-ichi Tsunoda 《Analytical sciences》2005,21(11):1269-1274
The formation conditions and characteristics of a liquid/liquid optical waveguide (LLW) were studied using a two-phase sheath flow, where the inner organic phase flow acted as the core and the outer aqueous flow acted as the clad. In immiscible solvent systems, i.e., toluene/water and diethyl ether/water systems, the LLWs were formed in the range of higher than ca. 600 of the Reynolds number (Re), where the linear velocity of the organic solvent was much higher than that of the aqueous solution. On the other hand, in a miscible solvent system, i.e., a tetrahydrofuran/water system, a stable LLW was formed in the range of a much lower Re than in immiscible systems. Moreover, the molecules at the toluene/water interface of the LLW were observed with both fluorescence and absorbance measurement systems. In particular, the change in the fluorescence spectrum of 1-anilino-8-naphthalenesulfonate (ANS) at the interface within 1 ms was observed by this method, indicating the usefulness of the LLW for a fast kinetic study of a liquid/liquid interface. 相似文献
108.
Masaru Matsuoka Akihiro Iwamoto Takeshi Ouchi Hiroshi Yoshioka Kazumi Nakatsu 《Journal of heterocyclic chemistry》1993,30(1):173-176
The structure of 1,4-dithiines obtained from orthodihalogeno heterocycles with thiocarbonyl compounds was determined by X-ray structure analysis of the intermolecular charge-transfer complex between 5,7,12,14-tetramethoxydibenzo[b,i]thianthrene and TCNQ. The formation of the thiazole ring has already been reported but the products were confirmed to be 1,4-dithiines by X-ray structure analysis and the previously reported results. 相似文献
109.
Bang JK Naka H Teruya K Aimoto S Konno H Nosaka K Tatsumi T Akaji K 《The Journal of organic chemistry》2005,70(25):10596-10599
[reaction: see text] The solid-phase Horner-Emmons reaction was successfully applied for the convenient syntheses of olefin-containing protease inhibitors. The isomerization during the solid-phase Horner-Emmons reaction can be minimized simply by the use of an appropriate amount of the base. The synthesized olefin peptides, which have an olefin gamma-amino acid at the scissile site, were found to act as effective inhibitors for the HTLV-1 protease for the first time. 相似文献
110.