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461.
Kitahara K Yoshihama I Hanada T Kokuba H Arai S 《Journal of chromatography. A》2010,1217(46):7249-7254
Monodispersed molecularly imprinted polymer particles selective for cholesterol were prepared by the copolymerization of styrene and divinylbenzene in the presence of template silica gel particles (particle size: 5 μm; pore size: 10 nm) functionalized with cholesterol on the surface, followed by dissolution of the cholesterol-bonded silica gel with a NaOH aqueous solution. Transmission and scanning electron micrographs of the molecularly imprinted polymer (MIP) particles revealed good monodispersity and porous structure. The MIP particles were packed into a high performance liquid chromatographic column, and its recognition ability of cholesterol was evaluated using cholesterol, cholesterol esters and fatty acid methyl esters by comparison with the non-imprinted polymer (NIP) particles prepared from styrene and divinylbenzene without cholesterol. The MIP particles showed a high affinity for cholesterol and cholesterol esters (K(MIP)'/K(NIP)' > 5.7). 相似文献
462.
Yamada H Kushibe K Okujuma T Uno H Ono N 《Chemical communications (Cambridge, England)》2006,(4):383-385
5-Alkenyl-15-alkynylporphyrins have been obtained unexpectedly by [2 + 2] acid-catalyzed condensation of dipyrrylmethane and TMS propynal in addition to 5,15-dialkynylporphyrin, and the unsymmetrical porphyrin can be converted to a butadiyne-linked dimer by selective desilylation of the alkynyl TMS. 相似文献
463.
The following degenerate parabolic system modelling chemotaxis is considered:
(KS) 相似文献
464.
Masataka Mori Tatsuji Chuman Masahiro Kohno Kunio Kato Masao Noguchi Hiroko Nomi Kenji Mori 《Tetrahedron letters》1982,23(6):667-670
The absolute stereochemistry of serricornin was determined to be (4S,6S,7S) by the synthesis of its (4S,6R,7R)-isomer using a carbohydrate synthon. 相似文献
465.
A new phenoxyl-nitroxide hetero biradical was prepared, and the nitrogen hyperfine splitting and giso-value of the biradical in toluene have been determined from its solution ESR spectrum. 相似文献
466.
Hiroko Shimomura Yutaka Sashida Kazunori Ogawa Yoichi Iitaka 《Tetrahedron letters》1981,22(14):1367-1368
The structure of a new bitter neo-clerodane, ajugamarin, isolated from Makino, has been elucidated by spectroscopic studies and confirmed by X-ray crystallographic analysis. 相似文献
467.
Hiroko Seki Yoshihisa Sei Kazuaki Shikii Sakurako Shimotakahara Hiroaki Utsumi Kentaro Yamaguchi Mitsuru Tashiro 《Analytical sciences》2004,20(10):1467-1470
A difference diffusion-based NMR technique and cold-spray ionization mass spectrometry were employed as a solution-based approach for identifying a ligand binding with a protein receptor. The difference diffusion-based NMR technique, called difference NOE-pumping, can directly detect the ligand interacting with a protein receptor. This technique uses a simple pulse sequence and the diffusion filter can easily be optimized. The cold-spray ionization mass spectrometry (CSI-MS), a variant of electrospray ionization mass spectrometry (ESI-MS) operating at low temperature, has been applied to detect the ligand-receptor complex. The efficiency of these techniques for identifying binding ligands is demonstrated with the human serum albumin (HSA)-drug system. 相似文献
468.
Masayuki Kirihara Hiroko Kakuda Yuta Ochiai Asuka Mokuya Akihiko Hatano 《Tetrahedron》2005,61(20):4831-4839
Tertiary cyclopropanol compounds react with a catalytic amount of vanadyl acetylacetonate in the presence of oxygen affording β-hydroxyketones and β-diketones. For 3-substituted-bicyclo[4.1.0]alkanols, peroxides are obtained, as are the β-hydroxyketones. Conversely, 2-ethoxycarbonylcyclopropyl silyl ethers produce ethyl γ-oxocarboxylate derivatives given the same reaction conditions. 相似文献
469.
Hiroko Kyotani Hisaaki Kanetsuna Masanao ya 《Journal of Polymer Science.Polymer Physics》1977,15(6):1029-1036
Conditions that affect the conformation of poly(β-benzyl L-aspartate) in films have been studied. A slow transition from the left-handed to the right-handed α-helical form is observed under certain conditions in half-dried film cast from chloroform solutions and after exposure of amorphous films of the left-handed β-helical form to chloroform vapor. This transition is caused by adsorption of moisture. Thermal transitions of these films were examined by differential scanning calorimetry and infrared spectroscopy. The right-handed α-helices change to left-handed ω-helices around 140°C, and sharp exothermic peak is observed in this region for some films. 相似文献
470.
Hiroko Kuritani Seiichi Imajo Keiji Shingu Masazumi Nakagawa 《Tetrahedron letters》1979,20(19):1697-1700
(+)-endo-cis-Bicyclo[3.3.0]oct-7-en-2-ol gave good optical yields in the kinetic resolution of aryl-t-butylacetic anhydrice, establishing the absolute configuration of t-butyl-α-naphthylacetic acid as (S) - (+). 相似文献