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91.
92.
Takashi Tokoroyama Masamitsu Tsukamoto Toshihiro Asada Hideo Iio 《Tetrahedron letters》1987,28(52):6645-6648
Doubly stereocontrolled cyclization of the allylsilane derivative 1 followed by trapping of the enolate with ClCH2SMe gives in one-pot manner the decalone derivatve 5 in which all of the four contiguous diastereomeric centers of
-clerodane skeleton have been secured. The total synthesis of linaridial 4 have been accomplished from 5. 相似文献
93.
A bienzyme reactor sensor system with amperometric detection was developed for the determination of ornithine. The system based on the immobilized enzymes (ornithine carbamyl transferase and pyruvate oxidase) consisted of a buffer tank, a peristaltic pump, an enzyme reactor, an oxygen electrode and a recorder. Then, 0.1 M MOPS buffer, containing pyruvic acid (0.5 mM) and carbamyl phosphate (0.5 mM), was continuously transferred into the system at 35 °C. Phosphate ion was formed enzymatically by transformation of ornithine in the presence of carbamyl phosphate. Pyruvate oxidase is activated by the presence of phosphate. Therefore, ornithine was determined from the oxygen consumed upon oxidation of pyruvic acid catalyzed by pyruvate oxidase in the presence of phosphate ion. The limit of detection was 0.05 mM and the response was linear to 3 mM (R2=0.9905). The variation coefficients were 4.9 (n=15) and 3.9% (n=15) for 1.1 and 3.0 mM standard ornithine, respectively. Good comparative results (R2=0.9238) were observed between ornithine contents in prawn muscle determined by the proposed system and by the HPLC. One assay was completed within 4 min. The immobilized enzymes were stable for 2 months at 4 °C and more than 150 samples could be continually determined using this enzyme reactor. 相似文献
94.
Ekenechukwu C. Okafor Masaaki Tsukamoto Akihiro Hayakawa K.D. Kunkuma A. Somarathne Taku Kudo Taku Tsujimura Hideaki Kobayashi 《Proceedings of the Combustion Institute》2021,38(4):5139-5146
The influence of wall heat loss on the emission characteristics of ammonia-air swirling flames has been investigated employing Planar Laser-Induced Fluorescence imaging of OH radicals and Fourier Transform Infrared spectrometry of the exhaust gases in combustors with insulated and uninsulated walls over a range of equivalence ratios, ?, and pressures up to 0.5 MPa. Strong influence of wall heat loss on the flames led to quenching of the flame front near the combustor wall at 0.1 MPa, resulting in large unburned NH3 emissions, and inhibited the stabilization of flames in the outer recirculating zone (ORZ). A decrease in heat loss effects with an increase in pressure promoted extension of the fuel-rich stabilization limit owing to increased recirculation of H2 from NH3 decomposition in the ORZ. The influence of wall heat loss resulted in emission trends that contradict already reported trends in literature. NO emissions were found to be substantially low while unburned NH3 and N2O emissions were high at fuel-lean conditions during single-stage combustion, with values such as 55 ppmv of NO, 580 ppmv of N2O and 4457 ppmv of NH3 at ? = 0.8. In addition, the response of the flame to wall heat loss as pressure increased was more important than the effects of pressure on fuel-NO emission, thereby leading to an increase in NO emission with pressure. It was found that a reduction in wall heat loss or a sufficiently long fluid residence time in the primary combustion zone is necessary for efficient control of NH3 and N2O emissions in two-stage rich-lean ammonia combustors, the latter being more effective for N2O in addition to NO control. This study demonstrates that the influence of wall heat loss should not be ignored in emissions measurements in NH3-air combustion, and also advances the understanding of previous studies on ammonia micro gas turbines. 相似文献
95.
Keigo Kobayashi Prof. Hirokazu Kobayashi Prof. Mitsuhiko Maesato Dr. Mikihiro Hayashi Tomokazu Yamamoto Dr. Satoru Yoshioka Prof. Syo Matsumura Prof. Takeharu Sugiyama Dr. Shogo Kawaguchi Prof. Yoshiki Kubota Prof. Hiroshi Nakanishi Prof. Hiroshi Kitagawa 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(23):6678-6682
We report on hexagonal close-packed (hcp) palladium (Pd)–boron (B) nanocrystals (NCs) by heavy B doping into face-centered cubic (fcc) Pd NCs. Scanning transmission electron microscopy–electron energy loss spectroscopy and synchrotron powder X-ray diffraction measurements demonstrated that the B atoms are homogeneously distributed inside the hcp Pd lattice. The large paramagnetic susceptibility of Pd is significantly suppressed in Pd–B NCs in good agreement with the reduction of density of states at Fermi energy suggested by X-ray absorption near-edge structure and theoretical calculations. 相似文献
96.
Some important classes of optimization problems originating from the optimal design of semiconductor memories such as SRAM,
aiming at boosting the yield rate, are studied. New optimization methods for the classes based on a symbolic algorithm called
quantifier elimination, combined with numerical computation, are proposed. The total efficiency of the design process is improved
by reducing the number of numerical yield-rate evaluations. In addition, useful information such as the explicit relations
among design variables, objective functions, and the yield rate, is provided. 相似文献
97.
Miyake H Siviloglou GA Puentes G Pritchard DE Ketterle W Weld DM 《Physical review letters》2011,107(17):175302
We have observed Bragg scattering of photons from quantum degenerate ^{87}Rb atoms in a three-dimensional optical lattice. Bragg scattered light directly probes the microscopic crystal structure and atomic wave function whose position and momentum width is Heisenberg limited. The spatial coherence of the wave function leads to revivals in the Bragg scattered light due to the atomic Talbot effect. The decay of revivals across the superfluid to Mott insulator transition indicates the loss of superfluid coherence. 相似文献
98.
Masai H Fujiwara T Matsumoto S Takahashi Y Iwasaki K Tokuda Y Yoko T 《Optics letters》2011,36(15):2868-2870
The authors have demonstrated white light emission of rare earth (RE)-free Mn-doped SnO-ZnO-P(2)O(5) glass. The RE-free glass shows white light emission with a high value of quantum efficiency (QE) comparable to conventional crystalline phosphor. It is notable that the high QE value is attained for RE-free transparent glass, and the broad emission can be continuously tuned by both the amount of activator and the composition of the glass. Since this glass possesses low-melting property, we emphasize that the glass phosphor will lead to the development of a novel inorganic white-light-emitting device in combination with a solid state UV light-emitting source. 相似文献
99.
Hirokazu KitauraAkitoshi Hayashi Kiyoharu TadanagaMasahiro Tatsumisago 《Solid State Ionics》2011,192(1):304-307
To improve the electrochemical performance of an all-solid-state In/80Li2S⋅20P2S5 (electrolyte)/LiMn2O4 cell, a lithium-titanate thin film was used to coat LiMn2O4. The interfacial resistance between LiMn2O4 and the electrolyte (measured after initial charging) decreased when the LiMn2O4 particles were coated with lithium-titanate. A cell with lithium-titanate-coated LiMn2O4 had a higher capacity than a cell with noncoated LiMn2O4 for current densities in the range 0.064 to 2.6 mA cm− 2. Additionally, a cell with coated LiMn2O4 retained 96% of the 10th-cycle reversible capacity at a current density of 0.064 mA cm− 2 after 50 cycles. 相似文献
100.
K Imai A Nishitani Y Tsukamoto W H Wang S Kanda K Hayakawa M Miyazaki 《Biomedical chromatography : BMC》1990,4(3):100-104
The catalytic effect of bases (imidazole, pyridine, Tris and triethylamine) on the peroxyoxalate chemiluminescence (PO-CL) reaction for high performance liquid chromatography (HPLC) was investigated. Imidazole increased PO-CL intensity extraordinarily, whereas the other bases (pyridine, Tris and triethylamine) did not. The peak heights of dipyridamole (coronary vasodilator) obtained using the eluents containing buffers were largest at pH 7.0, a few times less at pH 6.0 and pH 5.0, 100 times less at pH 4.0 and a few hundred times less at pH 3.0. The eluents containing buffers at pH 3, 4, 5, 6 or 7 each with imidazole increased the peak heights by a few to ten times as compared with those without imidazole, and those peak heights were within one order of magnitude. On the other hand, the eluent containing buffer at pH 2 did not affect the peak heights with or without imidazole. Bis(4-nitro-2-(3,6,9-trioxadecyloxycarbonyl)phenyl) oxalate (TDPO) alone and bis(2,4-dinitrophenyl)oxalate (DNPO) plus TDPO were recommended to be used against eluents containing buffers of pH 5-7 and pH 3-4, respectively. Dipyridamole and benzydamine hydrochloride (anti-inflammatory drug) were separated on the ODS column and detected by the present system. The detection limits of dipyridamole and benzydamine hydrochloride were 40 amol and 270 fmol, respectively. 相似文献