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81.
Hirokazu Sato Shusaku Hamada Roberto M. Sertkawa Tatsuya Nishimura Takashi Usui Hideo Sekino 《高压研究》2013,33(1-6):403-413
Abstract Continuous flames have been observed in Supercritical water oxidation (scWO) of isopropyl alcohol (IPA), using a vertical continuous reactor with sapphire windows and a mixing nozzle. Two types of continuous flame were confirmed: the one was long pale blue colored and the other was red short cone shaped, changing blue to red at around air ratio 2.0. The flame was strongly influenced by IPA concentration, air ratio and design of the mixing nozzle. Results for decomposition of PA are presented for IPA concentrations ranging from 600 up to 28260 ppm as TOC and initial reactor temperatures, were mostly around 490°C, at 25 MPa. Decomposition rate at steady state was over 99.9%. Experimentally measured CO2 and O2 concentrations at the flue gas were in good agreement with theoretically calculated values. Even for low air ratio as 1.1, high decomposition rate without CO, NO, NO2 was achieved. 相似文献
82.
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85.
M. Tsukamoto T. Shinonaga M. Takahashi M. Fujita N. Abe 《Applied Physics A: Materials Science & Processing》2013,110(3):679-682
Titanium dioxide (TiO2) films were irradiated with a femtosecond laser to alter their photoconductive properties. The laser wavelength and pulse duration were 775 nm and 150 fs, respectively. The TiO2 films irradiated with the femtosecond laser were darkened without changing the topography of the TiO2 film surface. The electrical resistances of the films as a function of time were measured under visible-light illumination. The transient electrical resistances decreased as time was increased after turning on the light. There were two stages in the reduction process of the electrical resistance. 相似文献
86.
87.
Hirokazu Nishimura 《International Journal of Theoretical Physics》1999,38(2):653-663
We present a basic theory of differential formsin synthetic differential supergeometry. Exteriordifferential calculus is developed, and Cartan's threemagic formulas as well as a variant of de Rham's theorem are established. 相似文献
88.
Yasutaka Shimada Kazumasa Usuda Hirokazu Okabe Tsuguru Suzuki Kazutsugu Matsumoto 《Tetrahedron: Asymmetry》2009,20(24):2802-2808
The deracemization of 1,2-diol monotosylate derivatives is achieved by the sequential combination of enzymatic hydrolysis and Mitsunobu inversion using a polymer-bound triphenylphosphine. After the lipase-catalysed hydrolysis of the racemic 2-acetoxyhexyl tosylate, the subsequent Mitsunobu reaction without separation causes an inversion of the resulting (R)-alcohol to give the (S)-enantiomer of the acetate as a single product. In particular, the reaction using the polymer-bound triphenylphosphine also proceeds smoothly, and the product is easily separated by filtration from the polymer-bound reagent and its by-products. This deracemization process is applicable to the preparation of several optically active 1,2-diol monotosylates. 相似文献
89.
A novel gas-sensing system based on a dynamic nonlinear response is reported to enhance the selectivity toward sample gases using a single detector. A periodic temperature change was applied to a semiconductor gas sensor and the resulting conductance of the sensor was evaluated by fast Fourier transformation (FFT). The dynamic nonlinear response to the sample gases was further characterized depending on the frequency of the temperature change. The characteristic sensor response under the application of a temperature change was theoretically simulated by considering the kinetics of gas molecules on the semiconductor surface. 相似文献
90.
Kenzo Inoue Hisanori Kaku Hirokazu Hayashi Teiichi Tanigaki 《Journal of polymer science. Part A, Polymer chemistry》1989,27(13):4231-4239
The copolymerization of 4-hydroxy-4′-vinylbiphenyl (HVB) with α-chloromaleic anhydride (CMAn) was investigated in THF, 1,4-dioxane, and acetonitrile. The formation of the 1:1 charge transfer complex between HVB and CMAn was confirmed spectroscopically, and the corresponding equilibrium constant (Keq) was determined as follows: Keq = 0.19, 0.11, and 0.058 mol/L in THF, 1,4-dioxane, and CH3CN, respectively. The copolymer composition is affected by the solvent, i.e., the content of HVB in the copolymer obtained in THF or 1,4-dioxane is lower than 50 mol % whereas the copolymer obtained in CH3CN has excess of HVB units. The maximum rate of copolymerization was observed at a 1:1 initial comonomer mole ratio, irrespective of the solvent polarity. Plots of Rp/[HVB] vs. [HVB] gave a straight line with a slope and an intercept for the copolymerization in THF whereas a straight line in CH3CN has no slope. On the basis of these results and 13C-NMR spectra of the copolymers, the mechanism of the predominant formation of alternating copolymers is discussed. 相似文献