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161.
Hirokazu Takahara Shunji Nomura Hiromichi Kawai Yutaka Yamaguchi Kazumi Okazaki Akio Fukushima 《Journal of Polymer Science.Polymer Physics》1968,6(1):197-221
The dimensional stability of regenerated cellulose film on swelling with water is discussed in relation to the biaxial orientation of the two kinds of structural units, cellulose II crystallites and noncrystalline chain segments, and their anisotropic swelling (anisotropic absorption of water). Considerable dimensional stability in the plane of the film but enormous instability of thickness on swelling in water of some commercial cellophanes is qualitatively interpreted in terms of the planar orientation of crystal (101) planes along the film surface and the orientation of the noncrystalline chain segments parallel to the film surface. The dimensional changes on swelling from the completely dry state to 10% moisture regain were further interpreted quantitatively in terms of the degrees of biaxial orientation of the two kinds of structural units and their degrees of anisotropic swelling by modifying the Hermans monophase model for crystalline and noncrystalline biphase structures. The following degrees of anisotropic swelling of the structural units were thus obtained: qc, [101] = 0.40%, qc, [101 ] = ?0.33%, and qa = 2.42%. 相似文献
162.
Hirokazu Nishimura 《Mathematical Logic Quarterly》1994,40(1):69-75
In conventional generalization of the main results of classical measure theory to Stone algebra valued measures, the values that measures and functions can take are Booleanized, while the classical notion of a σ-field is retained. The main purpose of this paper is to show by abundace of illustrations that if we agree to Booleanize the notion of a σ-field as well, then all the glorious legacy of classical measure theory is preserved completely. Mathematics Subject Classification: 03C90, 28B15. 相似文献
163.
Lignans from bark of the Olea plants. I 总被引:1,自引:0,他引:1
164.
165.
166.
N-Cyano monoaza crown ethers were prepared by the reaction of cyanamide with oligoethylene glycol dichlorides or ditosylates in the NaH/DMSO reaction system and led to the derivatives. 相似文献
167.
168.
Silylmethyl, tertiary-alkyl, alkenyl, and aryl Grignard reagents underwent intermolecular addition to olefins, such as styrenes, conjugated dienes, and enynes under an air atmosphere to give homologated alcohols. For example, (trimethylsilyl)methylmagnesium chloride and alpha-methylstyrene in ether at room temperature under dry air directly furnished 2-phenyl-4-(trimethylsilyl)-2-butanol in good yield. As the Grignard addition to olefins under argon with rigorous exclusion of O2 did not proceed at all, the above reaction should involve a radical mechanism: an alkyl radical generated by the aerial oxidation of the Grignard reagent adds to olefin, which is followed by oxygenation. Representative examples of this transformation, where products were obtained in good to excellent diastereo- or regioselectivity, are also disclosed. 相似文献
169.
Toshikazu Shimada Yoshifumi Katayama Kiyokazu Nakagawa Hirokazu Matsubara Masatoshi Migitaka Eiichi Maruyama 《Journal of Non》1983
The structural properties of microcrystalline silicon (μc-Si) are studied by Raman scattering. It is found that the intensity of each Raman band closely correlates with the absorption coefficient in the interband region and that the Raman band at ca. 150 cm?1 is a sensitive probe to randomness of Si-Si bonding structure in μc-Si. 相似文献
170.
N,N‐Di(arenesulfonyl)‐N′,N′‐dimethyl‐hydrazines, readily prepared from arenesulfonyl chlorides and N,N‐dimethylhydrazine, were heated at 120°C in chlorobenzene to give S‐aryl arenethiosulfonates, ArSSO2Ar, in good yields. 相似文献