Synthesis of macrocyclic 1,1′-biarenol derivatives by the tandem Claisen rearrangement and their binding properties

Crown ether-type macrocycles consisting of an enantiopure biarenol derivative and an oligoethylene glycol were synthesized by the Lewis acid-mediated tandem Claisen rearrangement. This is the first example of the successful application of the tandem Claisen rearrangement to the synthesis of enantiopure macrocyclic biarenol derivatives. The enantiopure macrocyclic biarenols were found to form 1:1 complexes with amino acid salts and to discriminate their chirality.     

Nickel(II) oxide surface-modified titanium(IV) dioxide as a visible-light-active photocatalyst

The electronic modification of TiO(2) with highly dispersed NiO particles smaller than ca. 2 nm by the chemisorption-calcination-cycle technique has given rise to a high level of visible-light-activity exceeding that of iron oxide-surface modified TiO(2) simultaneously with the UV-light-activity being significantly increased.     

Optically transparent superhydrophobic TEOS-derived silica films by surface silylation method

Optically transparent silica films were prepared at room temperature (~27°C) by keeping the molar ratio of TEOS:MeOH:H₂O (0.001 M NH₄F) constant at 1:19.29:6.20, respectively. A surface chemical modification of the films was done with alkylchlorosilanes at different concentrations from 0 to 1 vol. % and aging times varied from half to 2 h. The DMCS and TMCS surface modified silica films showed the static water contact angle of 146° and 162°, respectively. When the DMCS and TMCS modified films were cured at temperatures higher than 240 and 275°C, respectively, the films became superhydrophilic. Further, the humidity study was carried out at a relative humidity of 90% at 30°C temperature over 60 days. We characterized the water repellent silica films by Fourier transform infrared spectroscopy, scanning electron microscopy, atomic force microscopy, % of optical transmission, humidity tests and contact angle measurements.     

Efficient synthesis of aminomethylated azaindoles and corresponding pyrrole-fused derivatives by copper-catalyzed domino multicomponent coupling and cyclization

Efficient methods for the synthesis of aminomethylated azaindole derivatives via domino copper-catalyzed multicomponent coupling and cyclization have been developed. Using various secondary amines and aldehydes, N-substituted 3-ethynyl-4-aminopyridine was converted to substituted azaindoles in moderate to excellent yields. By use of a 3,4-diaminopyridine derivative bearing two alkynyl groups, the corresponding pyrrole-fused azaindoles were synthesized by controlled stepwise cyclization.     

Parallelization of multireference perturbation calculations with GAMESS

The quasi‐degenerate multireference second‐order perturbation theory (MRMP2) routines in the GAMESS suite of program codes have been parallelized using a distributed data interface (DDI). Two typical kinds of molecules were chosen for examination of parallelization speedup using one to eight PCs gathered as a cluster and connected by Fast Ethernet. The first example, in which total energies of several low‐lying electronic states have been obtained for niobium monohydride, give parallelization speedup of 7.15 when eight PCs were used as a cluster. The second example is the ground‐state total energy for a medium sized molecule, 4a,4b,8a,9a‐tetrahydro‐pyridino[1′,2′‐4,3]imidazo‐lidino[1,5‐a]pyridine. When distributed memory is employed, the parallelization speedup improves to 6.84 for the MRMP2 calculations when an eight‐PC cluster is used. These results demonstrate that our efforts to achieve the parallelization of MRMP2 routines have been successful. © 2001 John Wiley & Sons, Inc. J Comput Chem 22: 1243–1251, 2001     

Synthesis of polymers by template polymerization. I. Template polymerization of poly(methacrylic acid) with β‐cyclodextrin

A novel template monomer with multiple methacryloyl groups was synthesized with β‐cyclodextrin by the acetylation of primary hydroxyl groups and the esterification of secondary hydroxyl groups with methacrylic acid anhydride. The average number of methacryloyl groups in the monomer was 11. The radical polymerization of the monomer was carried out with the following initiators: α,α′‐azobisisobutylonitrile, H₂O₂? Fe²⁺ redox initiator, p‐xylyl‐N,N‐dimethyldithiocarbamate (XDC), and α‐bromo‐p‐xylyl‐N,N‐dimethyldithiocarbamate (BXDC). When the concentration of the monomer was less than 4.12 × 10^?3 M, polymerization was limited inside the molecule, and gelation of the system was hindered. For controlled radical photopolymerization with XDC and BXDC, the methacryloyl groups of the monomer were homogeneously polymerized, and poly(methacrylic acid) with a narrow molecular weight distribution was obtained by the hydrolysis of the polymerized products. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 3539–3546, 2001     

Theoretical study on dependence of hyperpolarizability of one‐dimensional ring system on the delocalization transition

We calculate the optical properties such as the polarization, the (hyper)polarizabilities, the critical vector potential, etc., in terms of the non‐Hermitian Anderson model of a 6‐site ring model. The dependence of the optical properties on the delocalization transition is investigated. It is found that all the total optical properties nonlinearly increase with the increase of the delocalization. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem, 2001