全文获取类型
收费全文 | 343篇 |
免费 | 4篇 |
国内免费 | 2篇 |
专业分类
化学 | 231篇 |
晶体学 | 1篇 |
力学 | 5篇 |
数学 | 22篇 |
物理学 | 90篇 |
出版年
2021年 | 4篇 |
2020年 | 2篇 |
2019年 | 12篇 |
2018年 | 1篇 |
2017年 | 2篇 |
2016年 | 5篇 |
2015年 | 6篇 |
2014年 | 2篇 |
2013年 | 14篇 |
2012年 | 12篇 |
2011年 | 22篇 |
2010年 | 10篇 |
2009年 | 10篇 |
2008年 | 14篇 |
2007年 | 17篇 |
2006年 | 27篇 |
2005年 | 12篇 |
2004年 | 16篇 |
2003年 | 13篇 |
2002年 | 10篇 |
2001年 | 13篇 |
2000年 | 8篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 6篇 |
1996年 | 9篇 |
1994年 | 2篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 6篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1981年 | 7篇 |
1980年 | 9篇 |
1979年 | 1篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1971年 | 1篇 |
1968年 | 3篇 |
排序方式: 共有349条查询结果,搜索用时 15 毫秒
21.
Optical Review - A graded-index type photonic crystal fiber (GI-PCF) has a graded effective index distribution that can be realized by an α-power air hole diameter distribution in radial... 相似文献
22.
Shintaro Wakamatsu Yuka Takahashi Dr. Hidetsugu Tabata Dr. Tetsuta Oshitari Norihiko Tani Prof. Dr. Isao Azumaya Dr. Yukiteru Katsumoto Dr. Takeyuki Tanaka Dr. Shinzo Hosoi Prof. Dr. Hideaki Natsugari Prof. Dr. Hideyo Takahashi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(22):7056-7063
The stereochemistry around the N‐benzoylated indole moiety of indometacin was studied by restricting the rotation about the N? C7′ and/or C7′? C1′ bond. In the 2′,6′‐disubstituted ones, an atropisomeric property was found and the atropoisomers were separated and isolated as stable forms. Their biological abilities to inhibit cyclooxygenase‐1 (COX‐1) and cyclooxygenase‐2 (COX‐2) were examined. Only the aR‐isomer showed specific inhibition of COX‐1, and COX‐2 was not inhibited by either atropisomer. Conformational analysis in NMR studies and X‐ray crystallography, and CD spectra in combination with calculations were utilized to elucidate the bioactive conformations. 相似文献
23.
Dr. Masayuki Gon Junko Wakabayashi Masashi Nakamura Prof. Dr. Kazuo Tanaka Prof. Dr. Yoshiki Chujo 《化学:亚洲杂志》2021,16(6):696-703
We demonstrate that multi-fluorinated boron-fused azobenzene (BAz) complexes can work as a strong electron acceptor in electron donor-acceptor (D-A) type π-conjugated polymers. Position-dependent substitution effects were revealed, and the energy level of the lowest unoccupied molecular orbital (LUMO) was critically decreased by fluorination. As a result, the obtained polymers showed near-infrared (NIR) emission (λPL=758–847 nm) with high absolute photoluminescence quantum yield (ΦPL=7–23%) originating from low-lying LUMO energy levels of the BAz moieties (−3.94 to −4.25 eV). Owing to inherent solid-state emissive properties of the BAz units, deeper NIR emission (λPL=852980 nm) was detected in film state. Clear solvent effects prove that the NIR emission is from a charge transfer state originating from a strong D-A interaction. The effects of fluorination on the frontier orbitals are well understandable and predictable by theoretical calculation with density functional theory. This study demonstrates the effectiveness of fluorination to the BAz units for producing a strong electron-accepting unit through fine-tuning of energy gaps, which can be the promising strategy for designing NIR absorptive and emissive materials. 相似文献
24.
The band structure of graphene ribbons with zigzag edges have two valleys well separated in momentum space, related to the two Dirac points of the graphene spectrum. The propagating modes in each valley contain a single chiral mode originating from a partially flat band at the band center. This feature gives rise to a perfectly conducting channel in the disordered system, if the impurity scattering does not connect the two valleys, i.e., for long-range impurity potentials. Ribbons with short-range impurity potentials, however, through intervalley scattering display ordinary localization behavior. The two regimes belong to different universality classes: unitary for long-range impurities and orthogonal for short-range impurities. 相似文献
25.
26.
The monotone asymmetric travelling salesman polytope P?nT is defined to be the convex hull of the incidence vectors of all hamiltonian circuits and all subsets of these in a complete diagraph of order n. We prove that certain hypohamiltonian diagraphs G=(V,E), i.e. diagraphs which are not hamiltonian but such that G–υ is hamiltonian for all υ?V, induce facets x(E)?n–1 of P?nT. This result indicates that P?nT has very complicated facets and that it is very unlikely that an explicit complete characterization of P?nT can ever be given. 相似文献
27.
Yoshikatsu Miyashita Yoshimasa Takahashi Yasuhiko Yotsui Hidetsugu Abe Shin-Ichi Sasaki 《Analytica chimica acta》1981,133(4):615-624
A graph-theoretical algorithm based on the minimal spanning tree (MST) is applied to structure—activity problems. The method is helpful in interpreting the results of cluster analysis, and becomes useful by combining with the mapping method that illustrates approximations of a multidimensional data structure. The antibacterial spectra of cephalosporins are analyzed by the MST approach and a linear mapping method. The main diameter obtained by MST gives the representative data set and clarifies the substituent effect on the antibacterial spectra. Relations between the central nervous system activity of benzodiazepine derivatives and their physicochemical parameters are also analyzed by MST and nonlinear mapping methods. These results for cephalosporins and benzodiazepines prove that MST is very useful in understanding the position of compounds in feature space and their activities. 相似文献
28.
Yajima T Wakabayashi N Uchida H Watanabe M 《Chemical communications (Cambridge, England)》2003,(7):828-829
Adsorbed water molecules which promote the methanol oxidation reaction (MOR) at Pt-Ru alloy electrode are clearly detected by in-situ FTIR spectroscopy with the attenuated total reflection configuration, which directly supports the "bi-functional mechanism" for the MOR. 相似文献
29.
Masahiro Kihara Shin‐Ichiro Kohama Shota Umezono Kanji Wakabayashi Shinichi Yamazaki Kunio Kimura 《Journal of polymer science. Part A, Polymer chemistry》2011,49(5):1088-1096
Poly(p‐oxybenzoyl) (POB) crystals were prepared by reaction‐induced crystallization during direct polymerization of p‐hydroxybenzoic acid in the presence of boronic anhydrides. Polymerizations were carried out at 300 °C in dibenzyltoluene at a concentration of 1% with three kinds of anhydrides of boronic acid such as 3,4,5‐trifluorophenylboronic acid (TFB), 4‐methoxyphenylboronic acid (MPB) and 4‐biphenylboronic acid (BPB). The POB crystals were formed as precipitates in the solution and the morphology was considerably influenced by both the structure of the boronic anhydride and its concentration (cB). Needle‐like crystals were firmed in the presence of TFB anhydride (TFBA) at cBs of 5 and 10 mol % by the spiral growth of lamellae. Spherical aggregates of slab‐like crystals were formed at cBs from 50 to 100 mol %. The polymerization with MPB anhydride and BPB anhydride (BPBA) also yielded the needle‐like crystals at cBs of 50 and 5 mol %, respectively. The polymerization with TFBA at lower cB was favorable to prepare the needle‐like crystal. Molecular weight was also influenced by the structure of the boronic anhydride and cB. Mn increased generally with cB and BPBA gave the highest Mn of 14.7 × 103 at cB of 100 mol %. The loose packing of the molecules in the crystal caused by the bulkiness of the end‐groups made the polymerization in the crystals more efficiently. Morphology and molecular weight of the POB crystals could be controlled by the chemical structure and the content of boronic anhydride. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011. 相似文献
30.