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41.
Paul Sheridan Yuichi Yagahara Hidetoshi Shimodaira 《Annals of the Institute of Statistical Mathematics》2008,60(4):747-761
We propose a scale-free network model with a tunable power-law exponent. The Poisson growth model, as we call it, is an offshoot
of the celebrated model of Barabási and Albert where a network is generated iteratively from a small seed network; at each
step a node is added together with a number of incident edges preferentially attached to nodes already in the network. A key
feature of our model is that the number of edges added at each step is a random variable with Poisson distribution, and, unlike
the Barabási–Albert model where this quantity is fixed, it can generate any network. Our model is motivated by an application
in Bayesian inference implemented as Markov chain Monte Carlo to estimate a network; for this purpose, we also give a formula
for the probability of a network under our model. 相似文献
42.
Yan Yin Otoo Yamada Yoshiki Suto Takashi Mishima Kazuhiro Tanaka Hidetoshi Kita Ken‐ichi Okamoto 《Journal of polymer science. Part A, Polymer chemistry》2005,43(8):1545-1553
A series of sulfonated copolyimides (co‐SPIs) bearing pendant sulfonic acid groups were synthesized from 1,4,5,8‐naphthalenetetracarboxylic dianhydride (NTDA), bis(3‐sulfopropoxy) benzidines (BSPBs), and common nonsulfonated diamines via statistical or sequenced polycondensation reactions. Membranes were prepared by casting their m‐cresol solutions. The co‐SPI membrane had a microphase‐separated structure composed of hydrophilic and hydrophobic domains, but the connecting behavior of hydrophilic domains was different from that of the homo‐SPIs. The co‐SPI membranes displayed clear anisotropic membrane swelling in water with negligibly small dimensional changes in the plane direction of the membrane. With water uptake values of 39–94 wt %, they showed dimensional changes in membrane thickness of about 0.11–0.58, which were much lower than those of homo‐SPIs. The proton conductivity σ values of co‐SPI membranes with ion exchange capacity values ranging from 1.95–2.32 meq/g increased sigmoidally with increasing relative humidity. They displayed σ values of 0.05–0.16 S/cm at 50 °C in liquid water. Increasing temperature up to 120 °C resulted in further increase in proton conductivity. The co‐SPI membranes showed relatively good conductivity stability during the aging treatment in water at 100 °C for 300 h. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1545–1553, 2005 相似文献
43.
Yutaka Nishigaichi Ken-ichi Tamura Narifumi Ueda Hidetoshi Iwamoto Akio Takuwa 《Tetrahedron letters》2008,49(13):2124-2127
Using a single allyltin reagent with a chiral nitrogen functionality, binary and remote asymmetric induction was realized toward various aldehydes. Either syn- or anti-1,4-amino-alcohols were selectively obtained with the use of Yb(OTf)3 or SnCl4, respectively. The structures of both diastereomers were identified by means of X-ray analysis. 相似文献
44.
Kenshu Fujiwara Yuta Hirose Hidetoshi Kawai Takanori Suzuki 《Tetrahedron letters》2010,51(32):4263-4546
Armatol F, isolated from the red alga Chondria armata as a polyether triterpene, has a solitary oxepane (A-ring) and a fused tricyclic ether moiety (BCD-ring). The A-ring features a rare cis-relationship between the hydroxy group at the quaternary carbon C6 and the carbon chain at C7. As part of our program toward the total synthesis of armatol F, a new stereoselective method for the construction of the C6 and C7 stereocenters has been developed based on chirality-transferring Ireland-Claisen rearrangement. The A-ring skeleton has also been synthesized from the rearrangement product by a process including ring-closing olefin metathesis. 相似文献
45.
Nariaki Sugiura Hidetoshi Murakami Seong Keon Lee Yasutomo Maeda 《Annals of the Institute of Statistical Mathematics》2006,58(1):93-100
This paper answers the long-standing question of whether the two-sided Wilcoxon rank test for equal sample sizes is unbiased
against a location parameter family of distributions by giving a counterexample. It is also shown that the nonrandomized two-sided
Wilcoxon test for equal sample sizes with the least positive significance level is unbiased. 相似文献
46.
Atsushi TakemuraYasushi Katagiri Kenshu Fujiwara Hidetoshi Kawai Takanori Suzuki 《Tetrahedron letters》2011,52(11):1222-1224
The synthesis of the C22-C37 segment of prorocentin, isolated from the dinoflagellate Prorocentrum lima, was achieved. Because the relative stereochemical relationship between C26 and other stereocenters (C28/C31/C32 established as R*/R*/R*) in the C22-C37 region of natural prorocentin has not yet been determined, both epimers at C26 of the C22-C37 segment were selectively constructed. The synthesis was based on a 5-exo epoxide ring opening reaction to form an oxolane (E-ring), Brown asymmetric methallylation to install the C26-stereocenter, acryloylation of the resulting alcohol, and ring-closing olefin metathesis to establish the Z-olefin at C23/C24. 相似文献
47.
Suzuki D Kato H Ohkawa M Anzai K Tanaka H Limão-Vieira P Campbell L Brunger MJ 《The Journal of chemical physics》2011,134(6):064311
We report measurements of differential and integral cross sections for electron excitation of the Schumann-Runge continuum, longest band, and second band electronic states in molecular oxygen. The energy range of the present study is 15-200 eV, with the angular range of the differential cross section (DCS) measurements from 2 to 130°. A generalized oscillator strength analysis is then employed in order to derive integral cross sections (ICSs) from the corresponding DCSs, and these ICSs are compared with relevant energy and oscillator strength scaled Born cross section (BEf-scaling [Y.-K. Kim, J. Chem. Phys. 126, 064305 (2007)]) results determined as a part of this investigation. Interestingly, while the present Schumann-Runge continuum and second band ICSs were in reasonable agreement with the respective BEf-scaling results, agreement for the longest band was poor below 100 eV with a possible reason for this apparently anomalous behavior being canvassed here. Finally, where possible all present data are compared with the results from earlier measurements and calculations with the level of agreement found being very good in some cases and marginal in others. 相似文献
48.
Nanda V Rosenblatt MM Osyczka A Kono H Getahun Z Dutton PL Saven JG Degrado WF 《Journal of the American Chemical Society》2005,127(16):5804-5805
Metal-binding sites in metalloproteins frequently occur at the interfaces of elements of secondary structure, which has enabled the retrostructural analysis of natural proteins and the de novo design of helical bundles that bind metal ion cofactors. However, the design of metalloproteins containing beta-structure is less well developed, despite the frequent occurrence of beta-conformations in natural metalloproteins. Here, we describe the design and construction of a beta-protein, RM1, that forms a stable, redox-active 4-Cys thiolate Fe(II/III) site analogous to the active site of rubredoxin. The protein folds into a beta-structure in the presence and absence of metal ions and binds Fe(II/III) to form a redox-active site that is stable to repeated cycles of oxidation and reduction, even in an aerobic environment. 相似文献
49.
Yan Yin Shunsuke Hayashi Otoo Yamada Hidetoshi Kita Ken‐Ichi Okamoto 《Macromolecular rapid communications》2005,26(9):696-700
Summary: Branched/crosslinked sulfonated polyimide membranes incorporating superior mechanical properties, high proton conductivity, and excellent fuel cell performance were successfully developed. The resulting polymer electrolytes displayed conductivity values of about 0.2 S · cm−1 at 120 °C and 100% relative humidity. In a single H2/O2 fuel cell system at 90 °C, they exhibited reasonably high fuel cell performances comparable to that of Nafion 112.
50.
Ashraful Alam Hidetoshi Ohta Tatsuya Yamamoto Satoshi Ogawa Ryu Sato 《Heteroatom Chemistry》2007,18(3):239-248
Naphthalene‐1‐sulfonic acid dimethylamides were treated with n‐BuLi and elemental sulfur or selenium to afford dinaphtho[1,2‐b:2′,1′‐d]thiophenes and selenophenes, respectively. This is the first example of making two C S/Se bonds and a C C bond in a single step at room temperature and also demonstrates a useful method for the synthesis of both thiophenes and selenophenes on naphthalene. In the case of the reactions of elemental selenium, diselenides were also obtained along with dinaphtho[1,2‐b:2′,1′‐d]selenophenes. The structure of dinaphtho[1,2‐b:′,1′‐d]thiophene was characterized by X‐ray crystallography as a representative molecule. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:239–248, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20291 相似文献