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111.
An interstitial hydroxyl radical (HO*) has been generated in bulk amorphous SiO2 (a-SiO2) loaded with interstitial H2O molecules and exposed to F2 laser light (hnu = 7.9 eV, lambda = 157 nm) at 77 K. F2 laser light dissociates an O-H bond of interstitial H2O into a pair of hydrogen atom (H0) and HO*. The resultant H0 disappears below 150 K, whereas HO* is detectable after thermal annealing at 200 K. The electron paramagnetic resonance (EPR) signal of the interstitial HO* recorded at 77 K is similar to that formed in amorphous ice, indicating that HO* is confined in an orthorhombic field by hydrogen bonding, probably with adjacent H2O molecules, silanol (SiOH) groups, and bridging oxygen atoms in the a-SiO2 network. 相似文献
112.
Elucidation of codoping effects on the solubility enhancement of Er3+ in SiO2 glass: striking difference between Al and P codoping 总被引:1,自引:0,他引:1
Saitoh A Matsuishi S Se-Weon C Nishii J Oto M Hirano M Hosono H 《The journal of physical chemistry. B》2006,110(15):7617-7620
The codoping effect mechanism of Al and P on the solubility enhancement of Er(3+) ion in SiO(2) glass was clarified by electron spin-echo envelope modulation spectroscopy. It turned out that doped P ions preferentially coordinate to the Er(3+) ion to form a "solvation shell structure", and the environment is similar to that in phosphate glass, while doped Al ions do not form such a selective solvation structure, taking octahedral coordination. This striking difference indicates that the primary roles of the P-doping and the Al-doping are attributed to "enthalpy of mixing" and to "entropy of mixing", respectively. 相似文献
113.
114.
Amorphous xGeO(2)-(1-x)SiO(2) thin films exhibit large negative index changes (4-8%) in the high GeO(2) region (x>~0.25) on irradiation with ArF laser pulses. The sign of the index change is opposite the low GeO(2) region X<0.25, and the magnitude of the index change is larger by an order of magnitude than that reported so far. Cross-sectional transmission electron microscope observation has revealed that nanometer-scale phase separation is induced in these highly photosensitive glasses by irradiation with ArF excimer laser light pulses or electron beams. This is a first finding of microphase separation in SiO(2)-GeO(2) glasses by irradiation and provides an essential constraint on the modeling of photonic effects induced by irradiation in these glasses. 相似文献
115.
Shinobu Hosono Bong H. Lian Keiji Oguiso Shing-Tung Yau 《Communications in Mathematical Physics》2003,241(2-3):245-286
We find a concise relation between the moduli , of a rational Narain lattice (,) and the corresponding momentum lattices of left and right chiral algebras via the Gauss product. As a byproduct, we find an identity which counts the cardinality of a certain double coset space defined for isometries between the discriminant forms of rank two lattices. 相似文献
116.
Hirashita T Kamei T Satake M Horie T Shimizu H Araki S 《Organic & biomolecular chemistry》2003,1(21):3799-3803
Diastereoselective couplings of salicylaldehyde, anisaldehyde and 2-pyridylaldehyde with crotyl- and cinnamylindium reagents were studied. The syl/anti selectivity was found to depend largely on the ligands on the indium atom of the allylic indium reagents. A syn-selective cinnamylation of salicylaldehyde was realized by the combination of cinnamyl acetate and indium(I) iodide, whereas an anti-selective coupling with salicylaldehyde was achieved by the indium trichloride/aluminium-mediated cinnamylation. 相似文献
117.
Shiigi H Yamamoto Y Yakabe H Tokonami S Nagaoka T 《Chemical communications (Cambridge, England)》2003,(9):1038-1039
Gold nanoparticles, modified with alkyl thiol, formed a film on polystyrene substrate, and it was found that the deposited film drastically changes its conductivity and hydrophobicity, depending on the alkyl chain length of the thiol used. 相似文献
118.
Castro-Rodriguez I Nakai H Gantzel P Zakharov LN Rheingold AL Meyer K 《Journal of the American Chemical Society》2003,125(51):15734-15735
A series of five uranium-alkane complexes of the general formula [(ArO)3tacn)U(alkane)].(cy-alkane) has been synthesized and crystallographically characterized. In all cases, X-ray diffraction studies revealed a pseudo-six-coordinate trivalent uranium core structure, [(ArO)3tacn)U], with a coordinated alkane ligand at the axial position. The average U-C bond distance to the bound alkane was determined to be 3.798 A, which is considerably shorter than the sum of the van der Waals radii of the U atom and a CH2 or CH3 unit (3.9 A). In all complexes, the alkane is coordinated in an eta2-H,C fashion. 相似文献
119.
Hiroyuki Ohno Shinji Takeoka Hidetaka Iwai Eishun Tsuchida 《Journal of polymer science. Part A, Polymer chemistry》1987,25(10):2737-2746
1-Palmitoyl-2(2,4-octadecadienoyl)-sn-glycero-3-phosphocholine (POPC), a polymerizable lipid that contains one diene group in only a 2-acyl chain, was polymerized as liposome in an aqueous medium. Polymerization was initiated by water-insoluble azobisisobutyronitrile (AIBN), or water-soluble azobis(2-amidinopropane) dihydrochloride (AAPD). AIBN was mixed with monomeric lipids, and the mixture was dispersed in an aqueous medium by sonication to prepare AIBN-containing monomeric lipid liposomes. On the other hand, AAPD was simply added to the liposome suspension. The POPC liposomes were easily polymerized by the addition of AAPD, a water-soluble radical initiator, but few were polymerized by AIBN. The results suggested that the diene group in the 2-acyl chain was in an aqueous phase and, therefore, easily polymerized by a water-soluble radical initiator. The polymerized POPC liposomes were revealed to be more stable than those of monomeric ones because the scattered-light intensity from the polymerized POPC liposome suspension changed a little by the addition of Triton X-100. For only the polymerized ones, the liposome structure was confirmed by TEM after addition of an excess amount of Triton X-100. 相似文献
120.
Photo-induced reduction of gold and platinum metal salt solutions was carried out using viologen graft copolymerized on low-density polyethylene (LDPE) films and viologen-containing poly(vinylidene fluoride) (PVDF-PVBV) microporous membranes. The effects of the UV irradiation time and concentration of the metal salt solutions on the metal ion reduction process and the resultant metal deposition on the polymeric substrates were investigated. The metal-polymer composites were characterized using X-ray photoelectron spectroscopy (XPS), scanning and transmission electron microscopy (SEM and TEM), atomic force microscopy (AFM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and UV-visible absorption spectroscopy. The amount of metal uptake, the state of the metal, and the size of the metal particles were found to be strongly dependent on the UV irradiation time and the type and concentration of the metal salt solution. The microporous structure and the high viologen content of the PVDF-PVBV membrane constitute an effective matrix for metal ion reduction and preparation of metal nanoparticles. 相似文献