全文获取类型
收费全文 | 1485篇 |
免费 | 22篇 |
国内免费 | 9篇 |
专业分类
化学 | 1108篇 |
晶体学 | 31篇 |
力学 | 28篇 |
数学 | 114篇 |
物理学 | 235篇 |
出版年
2022年 | 6篇 |
2019年 | 13篇 |
2017年 | 8篇 |
2016年 | 22篇 |
2015年 | 20篇 |
2014年 | 33篇 |
2013年 | 88篇 |
2012年 | 72篇 |
2011年 | 75篇 |
2010年 | 44篇 |
2009年 | 57篇 |
2008年 | 88篇 |
2007年 | 83篇 |
2006年 | 96篇 |
2005年 | 93篇 |
2004年 | 80篇 |
2003年 | 64篇 |
2002年 | 74篇 |
2001年 | 19篇 |
2000年 | 31篇 |
1999年 | 20篇 |
1998年 | 18篇 |
1997年 | 13篇 |
1996年 | 21篇 |
1995年 | 12篇 |
1994年 | 23篇 |
1993年 | 12篇 |
1992年 | 10篇 |
1991年 | 9篇 |
1990年 | 8篇 |
1988年 | 6篇 |
1987年 | 11篇 |
1986年 | 8篇 |
1985年 | 28篇 |
1984年 | 22篇 |
1983年 | 14篇 |
1982年 | 31篇 |
1981年 | 30篇 |
1980年 | 18篇 |
1979年 | 18篇 |
1978年 | 11篇 |
1977年 | 11篇 |
1976年 | 16篇 |
1975年 | 10篇 |
1974年 | 7篇 |
1973年 | 17篇 |
1972年 | 5篇 |
1970年 | 4篇 |
1968年 | 6篇 |
1967年 | 4篇 |
排序方式: 共有1516条查询结果,搜索用时 15 毫秒
61.
V. Meenakumari Hideo Utsumi Fuminori Hyodo A. Jawahar A. Milton Franklin Benial 《Magnetic resonance in chemistry : MRC》2017,55(11):1022-1028
Agarose is a tissue‐equivalent material and its imaging characteristics similar to those of real tissues. Hence, the dynamic nuclear polarization studies of 3‐carboxy‐2,2,5,5‐tetramethyl‐pyrrolidine‐1‐oxyl (carboxy‐PROXYL) in agarose gel were carried out. The dynamic nuclear polarization parameters such as spin lattice relaxation time, longitudinal relaxivity, leakage factor, saturation parameter and coupling parameter were estimated for 2 mM carboxy‐PROXYL in phosphate‐buffered saline solution and water/agarose mixture (99 : 1). From these results, the spin probe concentration was optimized as 2 mM, and the reduction in enhancement was observed for carboxy‐PROXYL in water/agarose mixture (99 : 1) compared with phosphate‐buffered saline solution. Phantom imaging was also performed with 2 mM concentration of carboxy‐PROXYL in various concentrations of agarose gel at various radio frequency power levels. The results from the dynamic nuclear polarization measurements agree well with the phantom imaging results. These results pave the way for designing model system for human tissues suited to the biological applications of electron spin resonance/Overhauser‐enhanced magnetic resonance imaging. 相似文献
62.
Various N-alkylsaccharins were easily prepared in moderate to good yields by the reaction of N-alkyl(o-methyl)arenesulfonamides with (diacetoxyiodo)benzene in the presence of iodine under irradiation with a tungsten lamp (W-hν). On the other hand, irradiation of N-alkyl(o- methyl)arenesulfonamide derivatives bearing various subslituents on the aromatic ring with a high- pressure mercury lamp (Hg-hν), in the presence of (diacetoxyiodo)benzene and iodine gave the corresponding N-alkyl-1,2-benzisothiazoline-3-one-1-oxide derivatives in moderate yields, together with N-alkyl-1,2-benzisothiazoline-3-one-1,1-dioxide (saccharin) derivatives. 相似文献
63.
Kakiuchi K Okada H Kanehisa N Kai Y Kurosawa H 《The Journal of organic chemistry》1996,61(9):2972-2979
Acid-catalyzed rearrangement of 5-cyclopentylidenecyclooctanone derivatives 9a-c was examined to obtain polyspiropolyquinanes 11a-c, considered to have a unique helical structure, through cascade rearrangement pathways consisting of continuous transannular cyclization followed by successive 1,2-alkyl shifts. The substrates were prepared easily by use of the Wittig or McMurry reaction. Reaction of the 5-cyclopentylidenecyclooctanone (9a) with acid gave the expected dispirotriquinane ketone 11a in high yield. The precise mechanism was elucidated by a deuterium-labeling experiment. In the case of the ketone 9b, having another spiroannulated cyclopentane ring attached on 9a, the trispirotetraquiane 11b was not obtained but the bis-propellane-type tetrahydrofuran 25 was produced exclusively. The 5-(5'-cyclopentylidenecyclooctylidene)cyclooctanone (9c) afforded the polycyclic compounds 27-31, depending on the acid used, instead of the desired tetraspiropentaquinane 11c. The structures of the products were determined by NMR spectral data including 2D (13)C INADEQUATE spectra and X-ray crystallographic analyses. The unexpected rearrangement pathways are also discussed. 相似文献
64.
65.
Fumio Kiyono Hideo Tajima Keiichi Ogasawara Akihiro Yamasaki 《Fluid Phase Equilibria》2005,230(1-2):90-98
A method for determining quadruple points of a two-component system containing a simple hydrate phase is proposed. This method utilizes the quasi-static change of the system along three-phase equilibrium lines and was proved to be able to determine the quadruple points as accurately as the conventional method. By using this method, even though some preparation is necessary, a quadruple point can be determined in just a single experimental run. The behavior of the system near the quadruple points was also examined experimentally, for both the quasi-static and the irreversible change cases. At the quadruple points, the temperature and pressure of the system were kept constant for a while, as at the triple point of water. In both cases, the representative point of the state of the system passed through the quadruple point on a p–T diagram. 相似文献
66.
PHOTOCHROMISM AND LUMINESCENCE OF DOPANT CHROMOPHORES THROUGH TWO-PHOTON IONIZATION IN POLYMER FILMS
Two-photon ionization and recombination processes of an aromatic chromophore doped in polymer films werestudied and the features of these processes were discussed in relation to photofunctional polymers, An aromatic moleculehaving low ionization potential, e.g., N,N,N',N'-tetramethyl-p-phenylene diamine doped in poly(methyl methacrylate)(PMMA) film was easily photoionized by intense laser ligh excitation, giving a colored radical cation (photochromism) anda trapped electron in PMMA matrix. As a reversed process, the radical cation recombined with the trapped electron, showingdiscoloration and emitting luminescence, either isothermal luminescence (ITL), or thermoluminescence (TL). In this report,ITL and TL through the charge recombination process were studied and the luminescence was suggested as a mean of the read-out of photorecording. 相似文献
67.
68.
A new preparative method of β- and γ-alkoxy (acetoxy) ketones, which are important precursors of vinyl ketones and 1,4-diketones, respectively, is presented. With PdCl2/CuCl/O2 or PdCl2/p-benzoquinone catalyst system, internal olefins bearing allylic alkoxy or acetoxy group underwent regioselective oxidation to form the corresponding β-alkoxy or β-acetoxy ketones. Similarly, γ-acetoxy ketones were obtained from homoallyl acetates having internal olefins with high regioselectivity. 相似文献
69.
On treatment of the 2-allyl-3-aminocyclohexenones with mercury(II) acetate, either sequence, dehydrogenation—oxymercuration or dehydrogenation—aminomercuration, occurred depending on the nature of the amino group in the substrate to yield the dihydrobenzofurans or indoles, respectively. 相似文献
70.
The structures of two new bitter triterpenes, ganoderic acid A and B. isolated from a mushroom Ganoderma lucidum (FR.) Karst. (Polyporaceae) were determined as 1 and 2 on the basis of spectral data. Ganoderic acid A is a novel highly oxidized triterpene bearing a boat-shaped A-ring of lanostane. 相似文献