Versatile formation of [2]catenane and [2]pseudorotaxane structures; threading and noncovalent stoppering by a self-assembled macrocycle

A self-assembled dimeric macrocycle between 4,4'-bis(4-pyridylmethoxy)biphenyl (L) and (en)Pd(NO(3))(2) was constructed, and its interactions with cyclodextrins of different cavity size resulted in the formation of [2]catenane and [2]pseudorotaxane systems, respectively. The structures were identified by 1D and 2D NMR spectroscopy and cold spray ionization mass (CSI-MS) spectrometry.     

Reaction-phase-selective inter- and intramolecular photochemical reaction of 2-pyridone derivatives

Phase-selective photochemical reaction of 2-pyridone derivatives was examined. Irradiation of 1 in benzene mainly gave rearrangement products 2. However, intermolecular [4 + 4] photocycloaddition proceeded quantitatively in the solid state, affording photodimers 3. An effective pi-pi stacking and dipole-dipole interaction between two pyridone moieties might play important roles in an effective arrangement of 1 for photodimerization in their crystal structures. [reaction: see text]     

Three-dimensional observation of an helical hot structure during a sawtooth crash in the WT-3 tokamak

Sawtooth crashes in an Ohmically heated plasma in the WT-3 tokamak have been observed by using soft x-ray computer tomography at three different poloidal cross sections around the torus. Initially, collapsing proceeds slowly with keeping the helical structure of an m = 1/n = 1 hot core around the torus. It accelerates as the helical hot structure is strongly deformed and fades away in the manner that the hot core at the high field side becomes obscure and disappears, while that at the low field side is deformed into a thin crescent aligned along the inversion circle, which survives even at the completion of the crash.     

Quantum interference effects in the magnetopiezoresistance of InAs/AlGaSb quasi-one-dimensional electron systems

We measured the low temperature magnetopiezoresistance of a quasi-one-dimensional electron system by fabricating an InAs/AlGaSb micromechanical cantilever. The magnetopiezoresistance curve showed aperiodic but reproducible oscillation, which was similar to the differential magnetoresistance curve obtained for the same device. A detailed comparison with model calculations strongly suggests that the quantum interference effects that cause the conductance fluctuations in the magnetoresistance are responsible for the peculiar behavior of the magnetopiezoresistance.     

Electron-spin and electron-orbital dependence of the tunnel coupling in laterally coupled double vertical dots

We employ a new laterally coupled, vertical double dot with a tunable tunnel-coupling gate in a parallel configuration to study the electron spin and orbital dependence of quantum mechanical tunnel coupling on the size of the honeycomb vertices in the small electron numbers regime. We find a transition from the weak coupling regime, where fluctuations in tunnel coupling due to varying electron configuration dominate the anticrossings, to a regime where the two dots coalesce. We apply a magnetic field to ascertain the orbital angular momenta of the Fermi surface eigenstates, which correlate with anticrossing size, and we identify spin pairs with congruent behavior.     

Dynamical ordering of symmetric non-Birkhoff periodic points in reversible monotone twist mappings

We study the coexistence of symmetric non-Birkhoff periodic orbits of C(1) reversible monotone twist mappings on the cylinder. We prove the equivalence of the existence of non-Birkhoff periodic orbits and that of transverse homoclinic intersections of stable and unstable manifolds of the fixed point. We derive the positional relation of symmetric Birkhoff and non-Birkhoff periodic orbits and obtain the dynamical ordering of symmetric non-Birkhoff periodic orbits. An extension of the Sharkovskii ordering to two-dimensional mappings has been carried out. In the proof of various properties of the mappings, reversibility plays an essential role. (c) 2002 American Institute of Physics.     

All-silicon quantum computer

A solid-state implementation of a quantum computer composed entirely of silicon is proposed. Qubits are 29Si nuclear spins arranged as chains in a 28Si (spin-0) matrix with Larmor frequencies separated by a large magnetic field gradient. No impurity dopants or electrical contacts are needed. Initialization is accomplished by optical pumping, algorithmic cooling, and pseudo-pure state techniques. Magnetic resonance force microscopy is used for ensemble measurement.