排序方式: 共有34条查询结果,搜索用时 15 毫秒
31.
Marc Bria Alan Cooper Shanika Gunatilaka Hewage Gouher Rabani 《Tetrahedron letters》2007,48(2):301-304
This article reports the characterization of pseudorotaxanes fabricated from cyclobis(paraquat-p-phenylene) 1, and 1,4-dialkyloxyphenyl derivative 2 or 1,5-dialkyloxynaphthalene derivative 3 in water. Addition of competing guest 3 to 1.2 or the electrochemical reduction of the cyclophane of 1.3 results in a dethreading of the original pseudorotaxane architecture. 相似文献
32.
Cadogan JI Hewage CM McNab H Macpherson AD Nicolson IS Reed D Sadler IH 《Organic & biomolecular chemistry》2006,4(12):2446-2451
The pyrrolylacrylates 9 and 10 were synthesised and subjected to flash vacuum pyrolysis (FVP) at 650-700 degrees C to generate the radicals 11 and 18, respectively. The phenoxyl 11 underwent hydrogen capture to give a mixture of the phenol 12 and the pyrrolobenzoxazine 13 in low yields, which were also obtained by a Wittig reaction of the 2-formylpyrrole 14. The thiophenoxyl 18 gave a single major product in 41% yield which was identified as the pyrrolo[1,2-a]quinoline 17 by a sequence of NMR experiments. A mechanism for the formation of 17 by a rearrangement-sulfur extrusion sequence is proposed. 相似文献
33.
Cooke G Woisel P Bria M Delattre F Garety JF Hewage SG Rabani G Rosair GM 《Organic letters》2006,8(7):1423-1426
[reaction: see text] A new self-complexing donor-acceptor system has been synthesized that has the propensity to undergo intramolecular decomplexation under thermal and electrochemical perturbation and upon addition of a competitive guest for the cyclophane's cavity. 相似文献
34.
Cooke G Garety JF Hewage SG Rabani G Rotello VM Woisel P 《Chemical communications (Cambridge, England)》2006,(39):4119-4121
Mixed monolayer protected gold nanoparticles have been fabricated incorporating 1,5-dialkyloxynaphthalene moieties that are capable of forming complexes with the tetracationic cyclophane cyclobis(paraquat-p-phenylene); electrochemical reduction of the cyclophane or the addition of tetrathiafulvalene results in disassembly of the complexes. 相似文献