Behavior of iodododecane in nuclear fuel reprocessing

By simulation experiments with a 10^–5 mol/l solution of iodododecane labeled with¹³¹I in n-dodecane the influence of various materials and conditions, which are possible in nuclear fuel reprocessing, has been investigated. The formation of decomposition products was detected via HPLC with a radioactivity monitor. By means of²⁵²Cf plasma-desorption mass spectrometry (PDMS) the decomposition products were identified. It was found that a temperature of 100°C favored the formation of iodoalkanes with chain lengths of C₁ to C₁₁. The presence of TBP(tri-n-butyl-phosphate) accelerated the decomposition of iodododecane. In pure TBP only iodobutane was formed as a decomposition product.     

Spin Axioms in Different Geometries of Relativistic Continuum Physics

The 24 components of the relativistic spin tensor consist of 3 + 3 basic spin fields and 9 + 9 constitutive fields. Empirically only three basic spin fields and nine constitutive fields are known. This empirem can be expressed by two spin axioms, one of them denying purely relativistic spin fields, and the other one relating the three additional basic fields and the nine additional constitutive fields to the known (and measurable) ones. This identification by the spin axioms is material-independent and does not mix basic spin fields with constitutive properties. The approaches to the Weyssenhoff fluid and the Dirac-electron fluid found in literature are discussed with regard to these spin axioms. The conjecture is formulated, that another reduction from six to three basic spin fields which does not obey the spin axioms introduces special material properties by not allowed mixing of constitutive and basic fields.     

Evaluation of piezoelectric PVDF polymers for use in space environments. III. Comparison of the effects of vacuum UV and gamma radiation

Films of piezoelectric PVDF and P(VDF‐TrFE) were exposed to vacuum UV (115–300 nm VUV) and γ‐radiation to investigate how these two forms of radiation affect the chemical, morphological, and piezoelectric properties of the polymers. The extent of crosslinking was almost identical in both polymers after γ‐irradiation, but surprisingly, was significantly higher for the TrFE copolymer after VUV‐irradiation. Changes in the melting behavior were also more significant in the TrFE copolymer after VUV‐irradiation due to both surface and bulk crosslinking, compared with only surface crosslinking for the PVDF films. The piezoelectric properties (measured using d₃₃ piezoelectric coefficients and D‐E hysteresis loops) were unchanged in the PVDF homopolymer, while the TrFE copolymer exhibited more narrow D‐E loops after exposure to either γ‐ or VUV‐radiation. The more severe damage to the TrFE copolymer in comparison with the PVDF homopolymer after VUV‐irradiation is explained by different energy deposition characteristics. The short wavelength, highly energetic photons are undoubtedly absorbed in the surface layers of both polymers, and we propose that while the longer wavelength components of the VUV‐radiation are absorbed by the bulk of the TrFE copolymer causing crosslinking, they are transmitted harmlessly in the PVDF homopolymer. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3253–3264, 2006