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Bekir Dizman Mohamed O. Elasri Lon J. Mathias 《Journal of polymer science. Part A, Polymer chemistry》2006,44(20):5965-5973
New water‐soluble methacrylate polymers with pendant quaternary ammonium (QA) groups were synthesized and used as antibacterial materials. The polymers with pendant QA groups were obtained by the reaction of the alkyl halide groups of a previously synthesized functional methacrylate homopolymer with various tertiary alkyl amines containing 12‐, 14‐, or 16‐carbon alkyl chains. The structures of the functional polymer and the polymers with QA groups were confirmed with Fourier transform infrared and 1H and 13C NMR. The degree of conversion of alkyl halides to QA sites in each polymer was determined by 1H NMR to be over 90% in all cases. The number‐average molecular weight and polydispersity of the functional polymer were determined by size exclusion chromatography to be 32,500 g/mol and 2.25, respectively. All polymers were thermally stable up to 180 °C according to thermogravimetric analysis. The antibacterial activities of the polymers with pendant QA groups against Staphylococcus aureus and Escherichia coli were determined with broth‐dilution and spread‐plate methods. All the polymers showed excellent antibacterial activities in the range of 32–256 μg/mL. The antibacterial activity against S. aureus increased with an increase in the alkyl chain length for the ammonium groups, whereas the antibacterial activity against E. coli decreased with increasing alkyl chain length. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5965–5973, 2006 相似文献
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Abstract— It was shown that chlorophyll a and its epimer chlorophyll a' are chlorinated and hydroxyl-ated during thin layer chromatography with silica gel plates. Hydroxylated chlorophyll a could not be chlorinated. Chlorinated and non chlorinated chlorophylls could be separated and determined by high performance liquid chromatography, because chlorophylls do not alter during this procedure. These findings support the assumption that Chi RC I is a preparation artifact. The extent of chlorination depends on chloride availability on the thin layer and on time. Chlorination and hydroyxlation do not take place under nitrogen atmosphere. The mechanism of chlorination during the thin layer chromatography procedure is discussed. 相似文献
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M. Jonathan Fray Paul Allen Paul R. Bradley Clare E. Challenger Michael Closier Tim J. Evans Mark L. Lewis John P. Mathias Carly L. Nichols Yvonne M. Po-Ba Hayley Snow Mark H. Stefaniak Hannah V. Vuong 《Tetrahedron》2006,62(29):6869-6875
The synthesis of ten substituted aminomethylene tetrahydro-isoquinolines is described, proceeding in eight steps from 5-hydroxyisoquinoline via reductive amination of N-Boc tetrahydro-isoquinoline 5-carboxaldehyde. Likewise, reductive amination was used to prepare four substituted dihydro-isoindoles from the corresponding aldehyde. The dihydro-isoindole ring system was conveniently accessed via a 2+2+2 cycloaddition reaction. 相似文献
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