全文获取类型
收费全文 | 3431篇 |
免费 | 171篇 |
国内免费 | 29篇 |
专业分类
化学 | 2499篇 |
晶体学 | 23篇 |
力学 | 58篇 |
数学 | 575篇 |
物理学 | 476篇 |
出版年
2023年 | 23篇 |
2022年 | 44篇 |
2021年 | 103篇 |
2020年 | 77篇 |
2019年 | 101篇 |
2018年 | 48篇 |
2017年 | 49篇 |
2016年 | 147篇 |
2015年 | 113篇 |
2014年 | 134篇 |
2013年 | 183篇 |
2012年 | 258篇 |
2011年 | 276篇 |
2010年 | 173篇 |
2009年 | 141篇 |
2008年 | 249篇 |
2007年 | 228篇 |
2006年 | 217篇 |
2005年 | 215篇 |
2004年 | 150篇 |
2003年 | 122篇 |
2002年 | 100篇 |
2001年 | 39篇 |
2000年 | 36篇 |
1999年 | 34篇 |
1998年 | 19篇 |
1997年 | 28篇 |
1996年 | 41篇 |
1995年 | 27篇 |
1994年 | 23篇 |
1993年 | 21篇 |
1992年 | 17篇 |
1991年 | 20篇 |
1990年 | 18篇 |
1989年 | 14篇 |
1988年 | 18篇 |
1987年 | 21篇 |
1986年 | 8篇 |
1985年 | 19篇 |
1984年 | 13篇 |
1983年 | 10篇 |
1982年 | 8篇 |
1981年 | 7篇 |
1980年 | 6篇 |
1979年 | 4篇 |
1978年 | 6篇 |
1977年 | 9篇 |
1975年 | 5篇 |
1974年 | 3篇 |
1926年 | 1篇 |
排序方式: 共有3631条查询结果,搜索用时 15 毫秒
71.
José M. Figueroa-O'Farrill Javier Mas Eduardo Ramos 《Communications in Mathematical Physics》1993,158(1):17-43
The KP hierarchy is hamiltonian relative to a one-parameter family of Poisson structures obtained from a generalized Adler map in the space of formal pseudodifferential symbols with noninteger powers. The resulting W-algebra is a one-parameter deformation of WKP admitting a central extension for generic values of the parameter, reducing naturally to W
n
for special values of the parameter, and contracting to the centrally extended W1+, W and further truncations. In the classical limit, all algebras in the one-parameter family are equivalent and isomorphic tow
KP. The reduction induced by setting the spin-one field to zero yields a one-parameter deformation of
which contracts to a new nonlinear algebra of the W-type.Address after October 1993: Queen Mary and Westfield College, UK 相似文献
72.
73.
The tautomeric properties of isoguanine (also named 2-oxoadenine or 2-hydroxyadenine) have been studied in the gas phase, in different pure solvents, and in the DNA environment using state of the art theoretical methods. Our results show that isoguanine constitutes an unique example of how tautomerism can be modulated by the environment. Compared to the tautomeric preference in the gas phase, both polar solvents and the DNA microenvironment dramatically change the intrinsic tautomeric properties of isoguanine. Tautomers which are important in physiological conditions are less than 1/10(5) of the total population of isoguanine in the gas phase. The impact of the present findings in the understanding of spontaneous mutations and in the design of new nucleobases with multiple recognition properties is discussed. 相似文献
74.
Two vibrational spectrometry-based methodologies were developed for Metamitron determination in pesticide formulations. Fourier transform-middle infrared (FT-MIR) procedure was based on the extraction of Metamitron by CHCl3 and latter determination by peak area measurement between 1556 and 1533 cm−1, corrected with a two points baseline established from 1572 to 1514 cm−1. Fourier transform-near infrared (FT-NIR) determination was made after the extraction of Metamitron in acetonitrile and measuring the peak area between 6434 and 6394 cm−1 corrected using a two points baseline defined between 6555 and 6228 cm−1. Repeatability, as relative standard deviation, of 5 independent measurements at mg g−1 concentration level, of 0.16% and 0.07% for MIR and NIR and a limit of detection of 0.03 and 0.004 mg g−1 were obtained for MIR and NIR, respectively.NIR determination provides a sample frequency of 120 h−1, higher than that found by MIR and liquid chromatographic methods (60 and 15 h−1, respectively). On the other hand, the NIR method reduces the solvent consumption and waste generation, to only 1 ml acetonitrile per sample as compared with 3.4 ml chloroform required for the MIR determination and 60 ml acetonitrile used in the chromatographic reference procedure. So, vibrational procedures can be considered serious alternatives to long and time consuming chromatographic methods usually recommended for quality control of commercially available pesticide formulations. 相似文献
75.
Urones JG Sexmero MJ Hernandez FA Basabe AB Diez D Marcos IS 《Natural product letters》2001,15(6):387-391
Two new diterpenic acids with an ent-halimane skeleton have been isolated from the aerial parts of Halimium viscosum (Villarino de los Aires chemotype) and separated as methyl esters. These diterpenes were 13-oxo-14, 15-dinor-1(10),11E-ent-halimadien-18-oic acid and 15-hydroxy-1(10),13Z-ent-halimadien-18-oic acid. 相似文献
76.
[reaction: see text] Condensation of N-substituted glycines with chiral 3-allyl-2-formyl perhydro-1,3-benzoxazines forms an azomethine ylide that cyclizes to give octahydropyrrolo[3,4-b]pyrrole derivatives. The [3 + 2] dipolar cycloadditions are stereoespecific leading to a single diastereoisomer. The chemical yields are dependent on the reaction temperature and the presence or absence of a base. 相似文献
77.
In this paper we study theoretically the molecular structure of [Be(C5Me5)2], with special interest in similarities and differences found in the computed geometric parameters, depending on the treatment of the electron correlation used. Given the low energy differences found between the different configurations studied (less than 4 kcal mol−1), and the high fluxionality found in experimental studies for this compound, we analyzed the dynamics of the system by means of first principles molecular dynamics calculations. A complex dynamics is found and analyzed in terms of two molecular rearrangement processes: 1,2-sigmatropic intraring rearrangement and a ring inversion mechanism that interchanges the roles (with regard to their coordination to the central Be atom) of the two rings.Dedicated to Dr. Jeal Paul Malrieu on occasion of his 65th birthday. 相似文献
78.
Esteve-Turrillas FA Armenta S Moros J Garrigues S Pastor A de la Guardia M 《Journal of chromatography. A》2005,1065(2):321-325
A non-destructive, fast and environmentally friendly procedure has been developed for cocaine determination in euro bank notes. Cocaine was extracted with 15 ml methanol by vortex agitation during 5 min. The extract was evaporated and reconstituted in 0.5 ml methanol. GC-MS-MS analysis was performed using as precursor ion m/z 182.2, with an excitation energy voltage of 1.60 eV, being the product ions measured m/z 150.2 and 82.0. A limit of detection of 0.15 ng per note and a repeatability of 6%, established from the relative standard deviation, of a 1 ng ml(-1) level, were achieved. Recoveries of 101+/-2 and 98+/-3% were obtained for samples spiked with 100 and 10 microg respectively. Results show that all the euro bank notes measured (16 samples) were contaminated with cocaine in the range between 1.25 and 889 microg. Two different contamination levels, high level (150-889 microg) and low one (1.25-77 microg) were found and it could be related with the direct or indirect contact with the drug. 相似文献
79.
4,5,7,13,15,16-Hexamethyl- (3) and 4,5,7,8,12,13,15,16-octamethyl[2.2]paracyclophane (4) have been oxidized to their radical cations in solution under relatively mild conditions. Substantial hyperfine splittings in the ESR. spectra of 3⊕. and 4⊕. arise from the methyl protons, whereas those from methylene protons are very small. This result indicates that the ethano bridges, unlike the methyl substituents, are rather ineffective in delocalizing the positive charge in 3⊕. and 4⊕. It is in line with the interpretation proposed previously to rationalize the gas-phase ionization potentials of multiply bridged [2N]cyclophanes and methyl derivatives of [2.2]paracyclophane. The π-spin distributions in 3⊕. and 4⊕. are discussed in terms of a simple model in which the singly occupied orbitals are represented as the antibonding combinations of two benzene HOMO's. 相似文献
80.
Ab initio ground state potential energy surfaces are obtained from interaction energies calculated with the coupled cluster singles and doubles model including connected triples corrections [CCSD(T)] and the aug-cc-pVXZ (X=5,Q,T,D) basis sets augmented with two different sets of midbond functions (denoted 33221 and 33211). The aug-cc-pV5Z-33221 surface is characterized by a T-shaped 49.5 cm(-1) minimum at Re=3.38 Angstroms and a linear saddle point at 3.95 Angstroms with De=36.6 cm(-1). These results agree well with the values provided by the accurate semiempirical potentials available. The rovibronic spectroscopic properties are determined and compared to the available experimental data and previous theoretical results. We study the basis set convergence of the intermolecular potentials and the rotational frequencies. The aug-cc-pVTZ basis sets provide reasonable binding parameters, but seem not to be converged enough for the evaluation of the microwave spectra. The aug-cc-pVQZ basis sets considerably improve the triple zeta results. The differences between the results obtained with the aug-cc-pVTZ-33221 basis set surface and those with the aug-cc-pVQZ-33221 are smaller than those of the corresponding bases with the set of 33211 midbond functions. The aug-cc-pVQZ surfaces are close to the aug-cc-pV5Z, that are expected to be close to convergence. With our best surfaces the errors in the frequencies with respect to the accurate experimental results go down to 0.6%. 相似文献