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61.
The extraction of cadmium(II) by di-(2-ethylhexyl) phosphoric acid dissolved in tetradecane from aqueous chloride and perchlorate solutions has been studied at 25°C. The distribution of the metal has been determined as a function of metal and DEHPA concentrations. Distribution data have been treated both graphically and numerically using the program LETAGROP-DISTR (Acta Chem. Scand. 1971, 25, 1521) and the composition of the extracted species into the organic phase has been determined. The extraction constants for these species are given in Table 1. 相似文献
62.
Costela A García Moreno I Gómez C García O Sastre R Roig A Molins E 《The journal of physical chemistry. B》2005,109(10):4475-4480
New hybrid solid-state dye laser materials based on highly porous silica aerogels have been synthesized. The open porous network of the aerogel was saturated with laser dyes dissolved in appropriate organic monomers, and polymerization took place inside the silica structure. The resulting polymer-filled nanoporous aerogel (PFNPA) was cast in a cylindrical shape, forming monoliths that were used as gain media in solid-state dye lasers. When the PFNPA incorporated pyrromethene dyes, highly photostable laser emission with good lasing efficiency was obtained. Under the demanding conditions of tightly focused transversal pumping with 532 nm, 5 mJ pulses at 10 Hz repetition rate, the commercial dye Pyrromethene 567 exhibited laser action with only a 10% drop in the laser output after 10(6) pump pulses in the same position of the sample. 相似文献
63.
Sastre Toraño J Rijn-Bikker Pv Merkus P Guchelaar HJ 《Biomedical chromatography : BMC》2000,14(5):306-310
A validated new and precise reversed-phase high-performance liquid chromatographic method for the determination of melatonin in human plasma and cerebrospinal fluid, with 5-fluorotryptamine as internal standard, is described. Liquid-liquid extraction with dichloromethane was performed under alkaline conditions. After evaporation of the organic solvent, the extract was dissolved in eluent and chromatographed on a base-deactivated octadecyl column, using an eluent composed of 650 mL potassium dihydrogenphosphate solution (0.07 mol/L water), adjusted to a pH of 3.0 with a 43% phosphoric acid solution, mixed with 350 mL methanol. Fluorescence detection at an excitation wavelength of 224 nm and an emission wavelength of 348 nm was used for quantitation. Melatonin and 5-fluorotryptamine chromatographed with retention times of 5.3 and 9. 3 min, respectively. Mean recoveries of 96% (n = 10) and 95% (n = 5) were found for melatonin in plasma and cerebrospinal fluid respectively. 5-Fluorotryptamine was found to have a mean recovery of 90% (n = 10) and 82% (n = 5) in plasma and cerebrospinal fluid, respectively. The repeatability coefficients of variation for both melatonin and 5-fluorotryptamine in plasma were 4-5% [five different samples (r = 5) on two consecutive days (n = 2)], with reproducibility coefficients of 1.6-7% (n = 2, r = 5) and 0.9-4% (n = 2, r = 5) for melatonin and internal standard, respectively. In cerebrospinal fluid the repeatability coefficient of variation of the extraction procedure was 5% (n = 1, r = 5) for melatonin and 7% (n = 1, r = 5) for 5-fluorotryptamine. The correlation coefficients of the calibration curves were 0.9998 (n = 2) in plasma at a concentration range of 0.108-25.9 ng/mL and 0.9994 (n = 2) at a concentration range of 0.108-25.9 ng/mL in cerebrospinal fluid. The limit of detection was determined at 8 pg/mL which enables to measure melatonin concentrations at physiological concentrations reached during daytime. 相似文献
64.
Francisco Sastre Elizabeth Moreno-Hilario Maria Guadalupe Sotelo-Serna Alejandro Gil-Villegas 《Molecular physics》2018,116(3):351-360
The microcanonical-ensemble computer simulation method (MCE) is used to evaluate the perturbation terms Ai of the Helmholtz free energy of a square-well (SW) fluid. The MCE method offers a very efficient and accurate procedure for the determination of perturbation terms of discrete-potential systems such as the SW fluid and surpass the standard NVT canonical ensemble Monte Carlo method, allowing the calculation of the first six expansion terms. Results are presented for the case of a SW potential with attractive ranges 1.1 ≤ λ ≤ 1.8. Using semi-empirical representation of the MCE values for Ai, we also discuss the accuracy in the determination of the phase diagram of this system. 相似文献
65.
66.
A. R. E. Brás O. García M. T. Viciosa S. Martins R. Sastre C. J. Dias 《Liquid crystals》2013,40(4):429-441
Electric field driven anchoring breakage in poly(triethylene glycol dimethacrylate)/nematic E7 composites was studied using dielectric spectroscopy and transmittance measurements. The transmittance hysteresis observed on increasing and decreasing an applied electric field, associated with different alignment states of the liquid crystal (LC), was monitored through dielectric loss. Essential changes are felt mainly in the δ‐peak, i.e. the dielectric response of the nematic when the director lies parallel to the applied electric field. An irreversible effect persists after the field had exceeded a critical value, which was manifest in a higher transmittance and a higher dielectric strength of the δ‐peak in the OFF state. The initial scattering/opaque state of the sample can only be recovered by heating to the clearing temperature of the nematic LC. The effect referred, commonly called memory effect, is rationalized in terms of anchoring breakage of the LC at the polymer–LC interfaces. The electro‐optical response was tested for different poly(triethylene glycol dimethacrylate)/nematic E7 composites in different composition ratios prepared by polymerisation‐induced phase separation. The lowest threshold field was observed for the 30:70 composite. 相似文献
67.
The essential oil composition of Cistus ladanifer grown in central Spain was analysed by gas chromatography and gas chromatography/mass spectrometry, revealing it to be rich in oxygenated compounds, with trans-pinocarveol (20.00%), bornyl acetate (7.03%) and terpinen-4-ol (6.37%) as the main monoterpene compounds. Viridiflorol (13.59%) and ledol (4.36%) were the main constituents of the oxygenated sesquiterpene fraction. Large amounts of α-pinene (4.70%) were found in the hydrocarbonated fractions. To study its possible use as a natural herbicide, the oil was tested in?vitro against Amaranthus hybridus, Portulaca oleracea, Chenopodium album, Conyza canadensis and Parietaria judaica, completely inhibiting A. hybridus germination, and nearly blocking C. canadensis and P. judaica germination at all concentrations assayed. In P. oleracea, the oil showed less effect, inhibiting its germination at the higher doses studied. It did not control C. album germination. Regarding seedling length, the oil had strong phytotoxic activity, being effective at all concentrations tested. 相似文献
68.
Sastre Toraño J Delatte TL Schluepmann H Smeekens SC de Jong GJ Somsen GW 《Analytical and bioanalytical chemistry》2012,403(5):1353-1360
A hydrophilic-interaction chromatography (HILIC) method coupled to electrospray ionization mass spectrometry (ESI-MS) was
developed for the determination of trehalose-6-phophate (Tre6P) in Arabidopsis thaliana seedlings. The method was optimized for MS detection and separation of Tre6P from its isomers, such as sucrose-6-phosphate,
by testing eluent pH, type of organic solvent and alkalinizer, and gradient conditions. Tre6P could be resolved from matrix
components within 28 min by using a water–acetonitrile gradient (0.2 ml/min) at pH 12 with piperidine as alkalinizer. The
method was validated for concentrations between 25 and 4,000 nM Tre6P in A. thaliana seedling extracts. Seedlings were extracted with consecutive liquid-liquid and solid-phase extractions, and analyzed with
HILIC-MS. Obtained accuracy (80–120 %) and precision (<24 %) demonstrated the suitability of HILIC-MS for determining Tre6P
level variations in plants. The limit of detection (LOD) was 3.5 nM Tre6P in extracts corresponding to 4.1 pmol.g−1 fresh plant weight (FW). This is a considerable improvement with respect to anion-exchange chromatography (AEC)-MS (40 nM)
and capillary electrophoresis-MS (80 nM). Furthermore, HILIC-MS analysis times were shorter than with AEC-MS (30 and 60 min,
respectively). The applicability of the HILIC-MS method was demonstrated by the analysis of extracts from seedlings grown
on medium containing 100 mM sorbitol or trehalose, resulting in mean Tre6P concentrations of 0.2 and 1.9 nmol.g−1 FW, respectively. Similar concentrations were found with AEC-MS. HILIC-MS was also evaluated at a high flow rate (2.0 ml/min).
This high-speed method resolved the Suc6P and Tre6P peaks within 3 min yielding a detection limit of 1.3 nM Tre6P. 相似文献
69.
This paper deals with the expansion of matrix functions in series of Laguerre matrix polynomials of a complex matrix parameter. A new asymptotic expression for positive and large x and n is obtained for this family of matrix polynomials that improves previous existing expressions. This expression is applied to improving the conditions imposed on the matrix function that are to be expanded in a series of non-hermitian Laguerre matrix polynomials, providing a new series expansion theorem that is more general than previous works. An application to solving linear differential systems without matrix exponentials is included. 相似文献
70.
J. M. Báñez Sanz J. A. López Sastre M. R. Patiño Molina C. Romero-Ávila García 《Journal of carbohydrate chemistry》2013,32(9):1331-1350
Abstract The synthesis of 5-glycosyl isoxazoles with 3-alkyl-, 3-aryl, 3,4-dialkyl, 3-aryl-4-alkyl or 3-alkyl-4-bromo substituents is reported. Deoxyenuloses were obtained from reaction of 2,3-O-isopropylidene-D-glyceraldehyde and several phosphorus ylides, which contain a carbonyl group, by a Wittig reaction. C-glycosyl α,β-unsaturated ketones were obtained, with the polyhydroxylate chain lengthened by two or three carbon atoms. In the second phase the ketones were transformed into the corresponding C-glycosyl α,β-unsaturated ketoximes, leading to the C-glycosyl isoxazoles, which were converted into the title compounds via removal of the isopropylidene group of suitably protected carbohydrates. The solubility of the synthetized C-glycosyl isoxazoles were modified by free hydroxyl groups in such a way that their behaviour against certain viruses and their potential antiviral activity could be studied. 相似文献