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991.
Consider an operator T:C1(R)→C(R) satisfying the Leibniz rule functional equation
992.
Beldjilali S Yip WL Hermann J Baba-Hamed T Belasri A 《Analytical and bioanalytical chemistry》2011,400(7):2173-2183
We report on investigations of plasmas produced by laser ablation of fresh potatoes using infrared nanosecond laser radiation.
A twin laser system consisting of two Nd:YAG oscillators was used to generate single or double pulses of adjustable interpulse
delay. The potatoes were irradiated under ambient air with moderate pulse energies of about 10 mJ. The expansion dynamics
of the ablation plume was characterized using fast imaging with a gated camera. In addition, time-resolved optical emission
spectroscopy was applied to study the spectral line emission of the various plasma species. The electron density was deduced
from Stark broadening, and the plasma temperature was inferred from the relative emission intensities of spectral lines. The
relative concentrations of metals were estimated from the comparison of the measured emission spectra to the spectral radiance
computed for a plasma in local thermal equilibrium. It is shown that the plasma produced by double pulses has a larger volume
and a lower density. These properties lead to an increase of the signal-to-noise ratio by a factor of 2 and thus to an improved
measurement sensitivity. 相似文献
993.
Salvadó N Butí S Labrador A Cinque G Emerich H Pradell T 《Analytical and bioanalytical chemistry》2011,399(9):3041-3052
Altarpieces and polychrome carved wood from the fifteenth century AD usually exhibit golden and silvery areas by the application
of a very thin foil of metal. The metal foils were normally protected from the atmosphere by a varnish or resin which maybe
either preserved or absent. Moreover, they were glued to the background surface by adhesive substances (egg yolk, drying oil
or animal glue). The high proportion of the glueing substances often renders the development of reaction compounds. With time,
silver alters blacken or simply disappear completely. In this paper, we study the alterations to metal foils from a selection
of fifteenth century artworks showing different glueing agents, organic coatings and several degrees of conservation of the
organic coatings and metal leafs. The submillimetric layered structure and the high variability and low amount of most of
the compounds present in the different layers, as well as their differing nature (organic and inorganic) make the use of micron-sensitive
high-resolution techniques essential for their study. In particular, the high resolution, high brilliance and small footprint
renders synchrotron radiation most adequate for their study. SR-XRD was performed to identify the reaction compounds formed
in the different layers; μFTIR was used at to identify the silver protecting organic coatings, the metal foil glueing layers
and the corresponding reaction compounds. The results obtained suggest that atmospheric corrosion is the dominant mechanism,
and therefore that the degree of corrosion of the metal foils is mainly related to the conservation state of the protecting
coatings. 相似文献
994.
Hermann Thorisson 《Queueing Systems》2011,68(3-4):313-319
This note presents four sets of problems. The first suggests the possibility of a limit theory for null-recurrent renewal processes similar to the theory in the positive recurrent case. The second concerns exact coupling of random walks on the line with step-lengths that are neither discrete nor spread out. The third concerns the coupling characterization of setwise convergence of distributions of stochastic processes to a stationary limit. The fourth concerns characterizations of mass-stationarity, a concept formalizing the intuitive idea that the origin is a typical location in the mass of a random measure. Mass-stationarity is an intrinsic characterization of Palm versions with respect to stationary random measures. 相似文献
995.
Gruber K Hermann BA Seeberger PH 《Angewandte Chemie (International ed. in English)》2011,50(37):A46-A51
Carbohydrates are important mediators of many biological processes that underlie cellular communication and disease mechanisms. Therapeutic agents include carbohydrate-based vaccines and the potent anti-viral protein Cyanovirin-N (CV-N). CV-N acts by specifically binding the carbohydrate structures decorating the cell surface of deadly viruses including human immunodeficiency virus (HI-V) or Ebola. In search for new carbohydrate-binding proteins and the development of sensors that exploit carbohydrate-protein interactions the label-free cantilever array technique can provides a fast, parallel and low-cost approach. 相似文献
996.
Huang MM Schneiders K Schulz PS Wasserscheid P Weingärtner H 《Physical chemistry chemical physics : PCCP》2011,13(9):4126-4131
The underlying principle of the chirality transfer in imidazolium-based camphorsulfonate ionic liquids is rationalized by linking catalytic results from the hydrogenation of [N-(3'-oxobutyl)-N-methylimidazolium] [(+)-camphorsulfonate] to [N-(3'-hydroxybutyl)-N-methylimidazolium] [(+)-camphorsulfonate] in tetrahydrofuran with electrolyte theory by the help of dielectric relaxation spectroscopy. Using this approach we are able to explain why the maximum of the enantiomeric excess of the hydrogenation reaction in tetrahydrofuran is found at a medium concentration of 0.15 mol L(-1), whereas it declines at both, lower and higher concentrations. Dielectric spectra in the concentration range between 0.05 and 1.0 mol L(-1) reveal a solute mode due to dipolar ion pairs and larger dipolar ion clusters. They verify that at very low concentrations the ionic liquid ions are fully solvated with an increasing tendency to form neutral ion pairs with increasing concentration. Already at 0.025 mol L(-1) the degree of dissociation reaches a minimum reflecting a maximum of neutral ion pair formation. With increasing ionic liquid concentration ordered ion clusters are formed by two and more ion pairs. At high concentrations these clusters collapse by dilution in the excess ionic liquid and the defined ion contact necessary for the chirality transfer is lost to a great extent. 相似文献
997.
Yilmaz B Müller U Tijsebaert B De Vos D Xie B Xiao FS Gies H Zhang W Bao X Imai H Tatsumi T 《Chemical communications (Cambridge, England)》2011,47(6):1812-1814
A new zeolite catalyst, Al-RUB-41, was synthesized for the first time. It was tested as a catalyst in methanol amination, and showed a shape-selective performance that results in a highly favorable product distribution. The shape-selective nature was also evidenced by using Pt-Al-RUB-41 as a bifunctional catalyst for decane hydroconversion. With its unique pore architecture and remarkable shape-selective character, Al-RUB-41 presents a significant commercial potential in industrial catalysis. 相似文献
998.
A class of dihydropyranobenzimidazole inhibitors was recently discovered that acts against the hepatitis C virus (HCV) in a new way, binding to the IRES-IIa subdomain of the highly conserved 5' untranslated region of the viral RNA and thus preventing the ribosome from initiating translation. However, the reported synthesis of these compounds is lengthy and low-yielding, the intermediates are troublesome to purify, and the route is poorly structured for the creation of libraries. We report a streamlined route to this class of inhibitors in which yields are far higher and most intermediates are crystalline. In addition, a key variable side chain is introduced late in the synthesis, allowing analogs to be easily synthesized for optimization of antiviral activity. 相似文献
999.
1000.
Bo Zhao Karan Bhuripanyo Keya Zhang Hiroaki Kiyokawa Hermann Schindelin Jun Yin 《Chemistry & biology》2012,19(10):1265-1277
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