Spurenanreicherungen in Ackerb?den mit selektiver Abtrennung von Eisen

Zusammenfassung Die bisher bekannten Verfahren zur Spurenanreicherung in Ackerböden wurden auf die Entfernung des Eisens erweitert. Zwei Anreicherungsverfahren werden angegeben; das eine beruht auf der Entfernung des Eisens aus salzsaurer Lösung durch Ausschütten mit Isobutylmethylketon mit nachfolgender Reduktion von Eisen(lIII) zu Eisen(II) mittels Ascorbinsäure und nochmaligem Ausschütteln der mitextrahierten Elemente mit Isobutylmethylketon. Dabei bleibt das Eisen(II) in der wäßrigen Phase zurück. Aus den vereinigten, die Spurenelemente enthaltenden Phasen beider Ausschüttelungen werden die Spurenelemente mit Pyrrolidindithiocarbaminat und Kupferron gefällt und mit Chloroform extrahiert. Das zweite Verfahren, die Extraktion des Eisen(III)-chlorids aus 7 n Lithiumchloridlösung, bietet Vorteile. Es bleiben mehr Elemente in der wäßrigen Phase zurück, und die Reduktion des Eisen(III)-ions durch Ascorbinsäure verläuft in der sehr schwach sauren Lösung stets quantitativ. Durch eine Ausschüttelung können von Eisen quantitativ die Alkalien, Erdalkalien, Al, Ti, Zr, Th, Pb, As^v, Bi, V^v, Cr^III, Cr^VI, Mo, Mn, Co, Ni, Ag, Cd, Zn (99,2%), Cu (99%) und U^VI (95,5%) abgetrennt werden. Daraus ergeben sich sehr einfach durchzuführende Trennungen von Eisen(III)/Chrom(VI), Eisen(III)/Vanadin(V) und Eisen(III)/Molybdän, die durch Extraktion aus salzsaurer Lösung nicht getrennt werden. Das Anreicherungsverfahren ist für alle Substanzen, die Eisen als Hauptbestandteil enthalten, anwendbar.     

Search for correlation effects in theM 4, 5 N 4, 5 N 4, 5 Auger spectrum of xenon

TheM _{4, 5} N _{4, 5} N _{4, 5} Auger spectrum of xenon has been measured with high resolution. Theoretical line intensities and relative line energies for this spectrum have been calculated applyingjj coupling to the initial states and intermediate coupling and configuration interaction to the final states. Two facts indicate that correlation effects are only small in the present case: The application of configuration interaction gives only small changes in line intensities and the experimental line intensities are found to be in good agreement with theoretical results, calculated without configuration interaction.     

A Lie-theoretic setting for the classical interpolation theories

The three classical interpolation theories — Newton-Lagrange, Thiele and Pick-Nevanlinna — are developed within a common Lie-theoretic framework. They essentially involve a recursive process, each step geometrically providing an analytic map from a Riemann surface to a Grassmann manifold. The operation which passes from the (n−1)st to the nth involves the action of what the physicists call a group of gauge transformations. There is also a first-order difference operator which maps the set of solutions of the nth order interpolation to the (n−1)st: This difference operator is, in each case, covariant with respect to the action of the Lie groups involved. For Newton-Lagrange interpolation, this Lie group is the group of affine transformations of the complex plane; for Thiele interpolation the group SL(2, C) of projective transformations; and for Pick-Nevanlinna interpolation the subgroup SU(1, 1) of SL(2, C) which leaves invariant the disk in the complex plane. National Research Council Senior Research Associate at the Ames Research Center (NASA)}.     

On a class of finite solvable groups

A finite solvable group G is called an X-group if the subnormal subgroups of G permute with all the system normalizers of G. It is our purpose here to determine some of the properties of X-groups. Subgroups and quotient groups of X-groups are X-groups. Let M and N be normal subgroups of a group G of relatively prime order. If G/M and G/N are X-groups, then G is also an X-group. Let the nilpotent residual L of G be abelian. Then G is an X-group if and only if G acts by conjugation on L as a group of power automorphisms.     

Fitting cores and supersolvable groups

Let A be a group. What can be said about the group B to ensure that A and the normal product AB belong to the same prescribed class of groups? Results in this direction are given for the classes of supersolvable groups, absolutely solvable groups and Lagrange groups.     

Management science in the era of smart consumer products: challenges and research perspectives

Smart products not only provide novel functionalities, but also may establish new business models, markets, or distribution channels, strengthen relationships with consumers, and/or add smart remote services. While many technical obstacles of such products have already been overcome, the broad market dissemination of smart products still poses some vital managerial challenges for decision makers. In this paper, we outline the technical potential and future trends of smart consumer products, discuss economic challenges in four scopes, namely, preference-based new product development, market analysis, supply chain design, and industry development, and, in particular, we highlight research perspectives for management science in this promising field.     

On global superconvergence of iterated collocation solutions to linear second-kind Volterra integral equations

It is well known that, in contrast to Fredholm integral equations, iterated collocation solutions (based on collocation at the Gauss points) to Volterra integral equations of the second kind exhibit optimal discrete superconvergence only at the mesh points. Here, we show that some degree of global superconvergence is possible on the entire interval.     

SU2ℍ als Kollineationsgruppe von sechzehndimensionalen lokalkompakten Translationsebenen

As a contribution to a classification of all sixteen-dimensional translation planes whose collineation group has dimension at least 38, this paper deals with the case that contains a subgroup (locally) isomorphic to SU₂Spin₅. Under various further assumptions, it is shown that such a plane satisfying dim 38 is necessarily isomorphic to the classical plane over the octonions.The complete classification will reveal that these further assumptions may in fact be omitted, except for the case that even contains a subgroup isomorphic to Spin₇. The latter planes have been explicitly determined in previous papers.

Meinem verehrten Lehrer Helmut Salzmann zum 65. Geburtstag