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41.
Roesky HW Murugavel R Walawalkar MG 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(2):324-331
Metal hydroxides represent a very interesting and highly useful class of compounds that have been known to chemists for a very long time. While alkali and alkaline earth metal hydroxides (s‐block) are commonplace chemicals in terms of their abundance and their use in a chemical laboratory as bases, the interest in Brønsted acidic molecular terminal hydroxides of p‐block elements, such as aluminum and silicon, has been of recent origin, with respect to the variety of applications these compounds can offer both in materials science and catalysis. Moreover, these systems are environmentally friendly, relative to the metal halides, owing to their ‐OH functionality (resembling that of water). Design and conceptualization of the corresponding terminal thiols, selenols, and tellurols (M? SH, M? SeH, and M? TeH) offer even more challenging problems to synthetic inorganic chemists. This concept summarizes some of the recent strategies developed to stabilize these otherwise very unstable species. The successful preparation of a number of silicon trihydroxides a few years back resulted in the generation of several model compounds for metal–silicates. The recent synthesis of unusual aluminum compounds such as RAl(OH)2, RAl(SH)2, and RAl(SeH)2 with terminal EH (E=O, Se, or Se) groups is likely to change the ways in which some of the well‐known catalytic conversions are being carried out. The need for very flexible and innovative synthetic strategies to achieve these unusual compounds is emphasized in this concept. 相似文献
42.
The ring-oven technique is a special type of spot analysis. In this review, papers published since 1976 are discussed. The aspects dealt with include developments in the technique and its use, the identification and determination of inorganic ions, organic substances, enzymatic analysis, applications to air and water samples, and combinations with other techniques. 相似文献
43.
Indole lactones 8 and 14 were synthesized as a means of functionalizing the 1-isopropyl substituent of the indole nucleus. Lactone 8 , upon reduction with diisobutylaluminum hydride, produces lactol 9 which behaves like a masked hydroxy aldehyde and undergoes a Horner-Emmons reaction with triethyl phosphonoacteate to give α,β-unsaturated ester 3 which possesses a hydroxyl group on the 1-isopropyl moiety. 相似文献
44.
Gert Brandl Fritz Kastner Rainer Fritsch Herbert Zinner Albrecht Mannschreck 《Monatshefte für Chemie / Chemical Monthly》1992,123(11):1059-1069
Summary A procedure is described which serves to measure circular dichrograms () on line during stops of flow in liquid chromatography. Since the concentration of substrate in the spectrometer cell during the stop is not known, the differential absorption coefficients are calculated from the experimental differential absorbances A by means of UV absorption (i. e. photomultiplier voltage) data. Verifications of the procedure are obtained by its application to three substrates (Table 1), the () spectra of which were known. The present on-line technique is compared with a corresponding off-line method.The N,N-dimethylthiobenzamides1 and2 as well as the 9,10-phenanthrenequinone7 consist of interconvertible enantiomers because their planar states are destabilized by steric overcrowding of groups. The unknown dichrograms () of1, 2 and7 are obtained (Figs. 2 and 4) and discussed with reference to the helicities of these molecules.In memory of the late Professor Dr. Dr. h. c. Günther Snatzke. 相似文献
45.
S. Korhammer Rolf Herzig Peter Schramel Jorma Kumpulainen Bernd Markert Herbert Muntau Philippe Quevauviller 《Accreditation and quality assurance》2000,5(6):238-242
Cabbage is frequently used in environmental monitoring and food control, and, hence, cabbage reference materials (RMs) are
required for ensuring quality assurance. A cabbage RM was prepared in view of certification of specific elements from the
"black list" of high toxicological interest and nutritive importance. All tasks of the RM production (production of the plant
material, cutting and freeze-drying, determination of the residual water content, preparation of the RM, homogeneity testing,
stability testing, certification measurements) are described in detail.
Received: 12 November 1999 / Accepted: 29 January 2000 相似文献
46.
Vibrational spectroscopy is uniquely capable of determining the structure and dynamics arising from the rotational degrees of freedom in molecular solids. Vibrational spectroscopy is sensitive to phenomena occurring on a time scale between the slow scale of magnetic, resonance methods and fast scale of diffraction methods; a time scale appropriate for both internal and overall rotation. Rotational motion of molecules in crystals provide examples of very simple reactions. Our understanding of the spectra of reacting molecules can thus be tested on these systems, and we conclude that Redfield equations can describe such spectra.A rich variety of motional effects are described: (1) The libration of the water of hydration in sodium perchlorate which illustrates a simple reacting system. (2) The libration of the adamantane molecule in both its ordered and disordered crystal phases which illustrates intermolecular interactions in organic crystals and the consequences of disorder. (3) The libration of the ammonium ion in crystals of ammonium salts which illustrated both change of orientational position by tunneling and the subtle orientating effects of isotopic substitution. (4) The internal rotation in n-alkane crystals which illustrates the ability to determine conformers and the relationship between the occurrence of disordered conformers and the occurrence of phase transitions. 相似文献
47.
Allenyl cations, generated from allenyl or alkynyl halides and Ag+, attack styrene at the side chain or at the aromatic nucleus. The allenyl/alkynyl product ratio is dependent on the structure of the precursor halide except for highly substituted systems. 相似文献
48.
Stevan W. Djuri Richard B. Herbert Frederick G. Holliman 《Journal of heterocyclic chemistry》1985,22(5):1425-1428
A novel procedure for the chemoselective reduction of 2-acyl-1H-indole-3-carboxaldehydes has been developed. Low temperature lithium triethylborohydride reduction affords the indol-2-yl carbinol whilst sodium cyanoborohydride reduction in acetic acid affords the 3-hydroxymethyl analogs. Both processes are high yield, and provide access to intermediates of potential utility for indole alkaloid synthesis. 相似文献
49.
In catalytic end-point detection, the first drop of titrant in excess is not used for a stoichiometric reaction with the indicator (as in conventional titrations) but acts as, or liberates, a catalyst for the indicator reaction. A very small excess of titrant thus suffices to catalyze large amounts of the indicator reaction mixture. Such catalytic end-points are therefore very sensitive. Terminology is discussed briefly. The various types of titration (direct, with a “brake”, reversed, indirect and substitution) and of end-point detection (visual, olfactory, photometric, thermometric and electrometric) are described. Applications of these techniques are summarized. 相似文献
50.
A novel modification of a hydrogen-atmosphere flamo ionization detector (HAFID) is presented which attenuates response to hydrocarbon compounds, significantly enhancing selectivity towards organometallic compounds by more than an order of magnitude. Chromatograms of an organometallic compound test mixture and regular leaded gasoline are presented to depict the specificity of the response. 相似文献