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131.
Hongli Li Brad Bendiak William F. Siems David R. Gang Herbert H. Hill Jr. 《International Journal for Ion Mobility Spectrometry》2013,16(2):105-115
A high-throughput ion mobility mass spectrometer (IMMS) was used to rapidly separate and analyze peptides and glycopeptides derived from glycoproteins. Two glycoproteins, human α-1-acid glycoprotein and antithrombin III were digested with trypsin and subjected to electro-spray traveling wave IMMS analysis. No deglycosylation steps were performed; samples were complex mixtures of peptides and glycopeptides. Peptides and glycosylated peptides with different charge states (up to 4 charges) were observed and fell on distinguishable trend lines in 2-D IMMS spectra in both positive and negative modes. The trend line separation patterns matched between both modes. Peptide sequence was identified based on the corresponding extracted mass spectra and collision induced dissociation (CID) experiments were performed for selected compounds to prove class identification. The signal-to-noise ratio of the glycopeptides was increased dramatically with ion mobility trend line separation compared to non-trend line separation, primarily due to selection of precursor ion subsets within specific mobility windows. In addition, isomeric mobility peaks were detected for specific glycopeptides. IMMS demonstrated unique capabilities and advantages for investigating and separating glycoprotein digests in this study and suggests a novel strategy for rapid glycoproteomics studies in the future. 相似文献
132.
1‐Thiacyclooct‐4‐yne (=5,6‐didehydro‐3,4,7,8‐tetrahydro‐2H‐thiocin; 9 ) can be prepared from thiocan‐5‐one ( 6 ) in three steps by applying the so‐called selenadiazole method. The heterocyclic alkyne can be oxidized to the corresponding sulfoxide 16 and sulfone 17 . Due to their geometrical strain, all three cyclic alkynes show high reactivities in Diels? Alder and 1,3‐dipolar cycloadditions. Moreover, tetrathiafulvalenes can be prepared from 9 and 16 by the reaction with CS2. 相似文献
133.
Yuhui Kou Derong Cao Hongqi Tao Lingyun Wang Jianquan Liang Zhizhao Chen Herbert Meier 《Journal of inclusion phenomena and macrocyclic chemistry》2013,77(1-4):279-289
A detailed study of the reaction conditions revealed that a quantitative cyclocondensation of 1,4-dialkoxy-2,5-bis(alkoxymethyl)-benzenes to pillar[n]arenes can be achieved by catalysis of p-toluenesulfonic acid in CH2Cl2. Major product of this new reaction is in each case a cyclopentamer (n = 5), but small amounts of the pillar[n]arenes with n = 6, 7 and 10 can be obtained as well. Different alkoxy groups in 1- and 4-position lead to regioisomers. All cyclooligomers exist in pillar structures as pair of enantiomers, which show a racemisation at room temperature, which is fast in terms of the NMR time scale. The racemisation process occurs by rotation of the 1,4-phenylene segments in the macrocyclic rings. Pillar[n]arenes exhibit novel host–guest behavior. 相似文献
134.
Yu Chen Prof. Derong Cao Lingyun Wang Minqing He Prof. Lixia Zhou Dieter Schollmeyer Prof. Herbert Meier 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(22):7064-7070
The self‐inclusion behavior of monoester copillar[5]arenes depends on the position of the ester group, which causes different guest selectivities. Monoester copillar[5]arenes bearing an acetate chain can form stable self‐inclusion complexes in low‐ and high‐concentration solution and exhibit high guest selectivity. However, a monoester copillar[5]arene bearing a butyrate chain can not form a self‐inclusion complex and exhibits low guest selectivity. Thus, a new class of stable self‐inclusion complexes of copillar[5]arenes was explored to improve the selectivity of molecular recognition. 相似文献
135.
Dr. David E. Herbert Nadia C. Lara Prof. Theodor Agapie 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(48):16453-16460
The meta‐terphenyl diphosphine, m‐P2, 1 , was utilized to support Ni centers in the oxidation states 0, I, and II. A series of complexes bearing different substituents or ligands at Ni was prepared to investigate the dependence of metal–arene interactions on oxidation state and substitution at the metal center. Complex (m‐P2)Ni ( 2 ) shows strong Ni0–arene interactions involving the central arene ring of the terphenyl ligand both in solution and the solid state. These interactions are significantly less pronounced in Ni0 complexes bearing L‐type ligands ( 2‐L : L=CH3CN, CO, Ph2CN2), NiIX complexes ( 3‐X : X=Cl, BF4, N3, N3B(C6F5)3), and [(m‐P2)NiIICl2] ( 4 ). Complex 2 reacts with substrates, such as diphenyldiazoalkane, sulfur ylides (Ph2S?CH2), organoazides (RN3: R=para‐C6H4OMe, para‐C6H4CF3, 1‐adamantyl), and N2O with the locus of observed reactivity dependent on the nature of the substrate. These reactions led to isolation of an η1‐diphenyldiazoalkane adduct ( 2‐Ph2CN2 ), methylidene insertion into a Ni? P bond followed by rearrangement of a nickel‐bound phosphorus ylide ( 5 ) to a benzylphosphine ( 6) , Staudinger oxidation of the phosphine arms, and metal‐mediated nitrene insertion into an arene C? H bond of 1 , all derived from the same compound ( 2 ). Hydrogen‐atom abstraction from a NiI–amide ( 9 ) and the resulting nitrene transfer supports the viability of Ni–imide intermediates in the reaction of 1 with 1‐azido‐arenes. 相似文献
136.
137.
This paper proposes a learning robot force/position control for high speed force trajectory following. Following high speed force trajectories in different repetitve robotic applications is a challenging field in robot force control. If the end–effector should provide a contact force while following a position trajectory in the non–force controlled direction a parallel force / position control is suitable. However, when it comes to high speed tasks this force control method reaches its limit. The problem can be solved by using an iterative learning control method in combination with the parallel force/position control. In this paper the learning force control method is introduced and experimental results are presented. (© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
138.
Mikhail Iakovlev Xiang You Adriaan van Heiningen Herbert Sixta 《Cellulose (London, England)》2014,21(3):1419-1429
SO2–ethanol–water (SEW) fractionation process is a highly attractive platform for future lignocellulosic Biorefineries. Its governing advantages include high flexibility in the selection of the raw material, simple and efficient recovery of fractionation chemicals, absence of carbohydrate degradation (both cellulose and hemicelluloses), and high reaction rates. The process is suitable for production of various carbohydrate- and lignin-based products including papermaking pulp, glucose, bioalcohols and lignosulfonates. The present paper addresses the possibility of producing dissolving pulp from spruce using SEW fractionation followed by ECF bleaching with and without hot caustic extraction. Comprehensive characterisation of chemical and macromolecular properties of the SEW dissolving pulps was complemented by determining the quality of viscose. The comparison with conventional viscose-grade acid sulfite pulps revealed close proximity in all properties. Therefore, considering the advantages of SEW process, it is suggested as a possible replacement for acid sulfite process in dissolving pulp manufacturing. 相似文献
139.
140.
Gerda Rogl Viktor Soprunyuk Wilfried Schranz Michael J. Zehetbauer Jiri Bursik Herbert Müller Ernst Bauer Peter F. Rogl 《无机化学与普通化学杂志》2020,646(14):1267-1272
Thermoelectric materials with a high figure of merit, ZT, are the essential basis to build thermoelectric generators, which can directly convert heat into electricity. Severe plastic deformation (SPD) via high-pressure torsion (HPT) was successfully applied to enhance ZT of ball-milled and hot-pressed skutterudites as well as to produce bulk nanostructured skutterudites directly from powders. SPD introduces many defects into the sample and in parallel the crystallite size is significantly reduced. During measurement-induced heating these defects anneal partially out, and the grains grow. In this work for the first time systematically the changes of the temperature-dependent electrical resistivity and of thermal expansion were compared. It could be shown that for p- and n-type skutterudites, being hot-pressed and HPT-processed as well as directly HPT-processed from compacted powder, these changes occur more or less simultaneously within the same temperature ranges. This evaluation gives a much deeper insight into the thermoelectric behavior of HPT samples under the influence of changing temperature. 相似文献