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排序方式: 共有341条查询结果,搜索用时 15 毫秒
61.
62.
Park KM Whang D Lee E Heo J Kim K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(2):498-508
This paper reports a synthetic strategy to construct one- and two-dimensional (1D and 2D) polyrotaxanes, in which a number of rings are threaded onto a coordination polymer, by the combination of self-assembly and coordination chemistry. Our approach to construct polyrotaxanes with high structural regularity involves threading a cucurbituril (CB) "bead" with a short "string" to form a stable pseudorotaxane, followed by linking the pseudorotaxanes with metal ions as "linkers" to organize into a 1D or 2D polyrotaxane. A 4- or 3-pyridylmethyl group is attached to each end of 1,4-diaminobutane or 1,5-diaminopentane to produce the short "strings", which then react with the cucurbituril "bead" to form stable pseudorotaxanes. The reaction of the pseudorotaxanes with various transition metal ions including CuII, CoII, NiII, AgI, and CdII produces 1D or 2D polyrotaxanes, in which many molecular "beads" are threaded onto 1D or 2D coordination polymers as confirmed by X-ray crystallography. The overall structure of a polyrotaxane is the result of interplay among various factors that include the coordination preferences of the metal ion, spatial disposition of the donor atoms with respect to the CB beads in the pseudorotaxane, and the size and coordination ability of the counteranion. 相似文献
63.
Free solution capillary electrophoresis of proteins using untreated fused-silica capillaries. 总被引:2,自引:0,他引:2
Numerous efforts have been made to separate proteins by capillary zone electrophoresis (CZE). The most common optimization techniques are changing the pH of the running buffer, coating the capillary surface with a hydrophilic polymer, or using additives in the sample solution. Surface coatings and solution additives can reduce the adsorption of the protein onto the capillary surface, but they diminish the separation efficiency and the resolution of CZE. This paper reports the successful separation of proteins in a untreated fused-silica capillary by raising the pH of the running buffer and washing between runs with 1.0 M sodium hydroxide. Under these conditions, model proteins and proteins in human serum have been determined by CZE. It is shown that the results from CZE are compatible with those of sodium dodecyl sulphate-polyacrylamide gel electrophoresis. 相似文献
64.
In this paper, a high‐order accurate compact finite difference method using the Hopf–Cole transformation is introduced for solving one‐dimensional Burgers' equation numerically. The stability and convergence analyses for the proposed method are given, and this method is shown to be unconditionally stable. To demonstrate efficiency, numerical results obtained by the proposed scheme are compared with the exact solutions and the results obtained by some other methods. The proposed method is second‐ and fourth‐order accurate in time and space, respectively. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
65.
To address if the non‐triphenylamine derivative hole transporting materials such as P3HT (poly‐3‐hexylthiophene) could also exhibit high device efficiency in mesoscopic MAPbI3 perovskite solar cells, we examined the effect of Li‐TFSI (Li‐bis(trifluoromethanesulfonyl) imide) and t‐BP (4‐tert‐butylpyridine) additives added in P3HT on device performance. Unlike the triphenylamine HTMs, the P3HT thiophene HTM without amine moiety was not doped by the additives but its conductivity was significantly improved by the Li‐TFSI/t‐BP mediated additional hole conduction. By inclusion of Li‐TFSI/t‐BP additive, we could fabricate more efficient mesoscopic MAPbI3 perovskite solar cells with smaller hysteresis with respect to scan direction due to Li mediated additional hole conduction. (© 2014 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
66.
Casey P. Johnson Hye-Young Heo Daniel R. Thedens John A. Wemmie Vincent A. Magnotta 《Magnetic resonance imaging》2014
Functional T1ρ mapping has been proposed as a method to assess pH and metabolism dynamics in the brain with high spatial and temporal resolution. The purpose of this work is to describe and evaluate a variant of the spin-locked echo-planar imaging sequence for functional T1ρ mapping at 3 T. The proposed sequence rapidly acquires a time series of T1ρ maps with 4.0 second temporal resolution and 10 slices of volumetric coverage. Simulation, phantom, and in vivo experiments are used to evaluate many aspects of the sequence and its implementation including fidelity of measured T1ρ dynamics, potential confounds to the T1ρ response, imaging parameter tradeoffs, time series analysis approaches, and differences compared to blood oxygen level dependent functional magnetic resonance imaging. It is shown that the high temporal resolution and volumetric coverage of the sequence are obtained with some expense including underestimation of the T1ρ response, sensitivity to T1 dynamics, and reduced signal-to-noise ratio. In vivo studies using a flashing checkerboard functional magnetic resonance imaging paradigm suggest differences between T1ρ and blood oxygen level dependent activation patterns. Possible sources of the functional T1ρ response and potential sequence improvements are discussed. The capability of T1ρ to map whole-brain pH and metabolism dynamics with high temporal and spatial resolution is potentially unique and warrants further investigation and development. 相似文献
67.
68.
Aram Hong Chang Min Choi Han Jun Eun Changseop Jeong Prof. Jiyoung Heo Prof. Nam Joon Kim 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(30):7939-7942
The CD spectroscopy of a chiral compound in solution yields an average CD value derived from all of the conformations of a chiral molecule. By contrast, CD spectroscopy of cold chiral molecules in the gas phase distinguishes specific conformers of a chiral molecule, but the weak CD effect has limited the practical application of this technique. Reported herein is the first resonant two‐photon ionization CD spectra of ephedrines in a supersonic jet using circularly polarized laser pulses, which were generated by synchronizing the oscillation of the photoelastic modulator with the laser firing. The spectra exhibited well‐resolved CD bands which were specific for the conformations and vibrational modes of each enantiomer. The CD signs and magnitudes of the jet‐cooled chiral molecules were very sensitive to their conformations and thus offered crucial information for determining the three‐dimensional structures of chiral species, as conducted in combination with quantum chemical calculations. 相似文献
69.
We propose a light shutter device using dye-doped cholesteric liquid crystals for a high-visibility see-through display. In the focal-conic state, the proposed device can perfectly block the background image through simultaneous use of light scattering and absorption effects in a single-layered structure. By switching the proposed device placed at the backside of a see-through display, we can choose transparent or high-visibility display modes in a see-through display. 相似文献
70.
A neutral Dirac fermion ψ with a nonzero magnetic dipole moment is supplied as a singlet within the context of the standard model and is considered as a dark matter candidate near the electroweak scale (10–1000 GeV). We discuss its dynamics with the ordinary matters through the magnetic dipole moment. The magnetic dipole moment constrained by the relic abundance may be as large as 10−18–10−17e⋅cm. We show that the elastic scattering is due to a spin–spin interaction for the direct detections and the predictions are under experimental exclusion limits of the current direct detectors, XENON10 and CDMS II, and consider the possibility of dark matter detection in the future. 相似文献