Isoflavonoid glycosides from the rhizomes of Iris germanica

Four isoflavone glycosides were isolated from the rhizomes of Iris germanica. Compounds 1 and 2 are new, while compounds 3 and 4 are known isoflavone glycosides. These compounds were identified as iriskashmirianin 4'-O-beta-D-glucoside (1), nigricin 4'-O-beta-D-glucoside (2), irilone 4'-O-beta-D-glucoside (3) and iridin (4). Their structures were determined with the help of spectroscopic methods.     

The physicist's role in physical laws

The physicist not only observes phenomena, but he also has an active role in the formulation of some laws. For instance, laws involving irreversibility refer explicitly to what can or cannot be done by physicists. As the abilities of the latter may vary, we obtain sequences of laws, the convergence of which is discussed.     

The isobutylene-isobutane alkylation process in liquid HF revisited

Details on the mechanism of HF catalyzed isobutylene-isobutane alkylation were investigated. On the basis of available experimental data and high-level quantum chemical calculations, a detailed reaction mechanism is proposed taking into account solvation effects of the medium. On the basis of our computational results, we explain why the density of the liquid media and stirring rates are the most important parameters to achieve maximum yield of alkylate, in agreement with experimental findings. The ab initio Car-Parrinello molecular dynamics calculations show that isobutylene is irreversibly protonated in the liquid HF medium at higher densities, leading to the ion pair formation, which is shown to be a minimum on the potential energy surface after optimization using periodic boundary conditions. The HF medium solvates preferentially the fluoride anion, which is found as solvated [FHF](-) or solvated F(-.)(HF)(3). On the other hand, the tert-butyl cation is weakly solvated, where the closest HF molecules appear at a distance of about 2.9 Angstrom with the fluorine termination of an HF chain.     

The threshold for random -SAT is

Let be a random -CNF formula formed by selecting uniformly and independently out of all possible -clauses on variables. It is well known that if , then is unsatisfiable with probability that tends to 1 as . We prove that if , where , then is satisfiable with probability that tends to 1 as .

Our technique, in fact, yields an explicit lower bound for the random -SAT threshold for every . For our bounds improve all previously known such bounds.

     

A linear semi-infinite programming strategy for constructing optimal wavelet transforms in multivariate calibration problems

A novel strategy for the optimization of wavelet transforms with respect to the statistics of the data set in multivariate calibration problems is proposed. The optimization follows a linear semi-infinite programming formulation, which does not display local maxima problems and can be reproducibly solved with modest computational effort. After the optimization, a variable selection algorithm is employed to choose a subset of wavelet coefficients with minimal collinearity. The selection allows the building of a calibration model by direct multiple linear regression on the wavelet coefficients. In an illustrative application involving the simultaneous determination of Mn, Mo, Cr, Ni, and Fe in steel samples by ICP-AES, the proposed strategy yielded more accurate predictions than PCR, PLS, and nonoptimized wavelet regression.     

Morita equivalence and Pedersen ideals

We show that two -algebras are strongly Morita equivalent if and only if their Pedersen ideals are Morita equivalent as rings with involution.

     

Equivalence of positive Hausdorff measure and the open set condition for self-conformal sets

A compact set is self-conformal if it is a finite union of its images by conformal contractions. It is well known that if the conformal contractions satisfy the ``open set condition' (OSC), then has positive -dimensional Hausdorff measure, where is the solution of Bowen's pressure equation. We prove that the OSC, the strong OSC, and positivity of the -dimensional Hausdorff measure are equivalent for conformal contractions; this answers a question of R. D. Mauldin. In the self-similar case, when the contractions are linear, this equivalence was proved by Schief (1994), who used a result of Bandt and Graf (1992), but the proofs in these papers do not extend to the nonlinear setting.

     

Thin points for Brownian motion

Let Θ(x,r) denote the occupation measure of the ball of radius r centered at x for Brownian motion {W_t}_0≤t≤1 in . We prove that for any analytic set E in [0,1], we have

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, where dim_P(E) is the packing dimension of E. We deduce that for any a≥1, the Hausdorff dimension of the set of “thin points” x for which

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, is almost surely 2−2/a; this is the correct scaling to obtain a nondegenerate “multifractal spectrum” for the “thin” part of Brownian occupation measure. The methods of this paper differ considerably from those of our work on Brownian thick points, due to the high degree of correlation in the present case. To prove our results, we establish general criteria for determining which deterministic sets are hit by random fractals of ‘limsup type' in the presence of long-range correlations. The hitting criteria then yield lower bounds on Hausdorff dimension. This refines previous work of Khoshnevisan, Xiao and the second author, that required decay of correlations.