Detection of the hydrogen-bond stretching mode in the low-frequency Raman spectrum of catechol and catechol-D2

Low-frequency Raman spectra of catechol (1,2-dihydroxybenzene) and catechol-d₂ have been measured at 130 K. The stretching mode of the intermolecular hydrogen bond, ν_σ, has been assigned at 187 and 184 cm^?1, respectively. A short discussion of this assignment and its implications with respect to the previously reported guaiacol (2-methoxyphenol) spectra is presented.     

Wilson's functional equation on C

Summary We find the complete set of continuous solutionsf, g of Wilson's functional equation _{n = 0} ^{N – 1} f(x + wⁿy) = Nf(x)g(y), x, y C, given a primitiveN ^th rootw of unity.Disregarding the trivial solutionf = 0 andg any complex function, it is known thatg satisfies a version of d'Alembert's functional equation and so has the formg(z) = g (z) = N^–1 _{n = 0} ^{N – 1} E(wⁿz) for some C². HereE ₍₁, ₂)(x + iy) = exp( ₁x + ₂).For fixedg = g the space of solutionsf of Wilson's functional equation can be decomposed into theN isotypic subspaces for the action of Z _N on the continuous functions on C. We prove that ther ^th component, wherer {0, 1, ,N – 1}, of any solution satisfies the signed functional equation _{n = 0} ^{N – 1} f(x + wⁿy)w^nr = Ng(x)f(y), x, y C. We compute the solution spaces of each of these signed equations: They are 1-dimensional and spanned byz _{n = 0} ^{N – 1} w^nr E(wⁿz), except forg = 1 andr 0 where they are spanned by andz ^{N – r}. Adding the components we get the solution of Wilson's equation. Analogous results are obtained with the action ofZ _N on C replaced by that ofSO(2).The case ofg = 0 in the signed equations is special and solved separately both for Z _N andSO(2).     

Exceptions and counterexamples: Understanding Abel's comment on Cauchy's Theorem

It may seem odd that Abel, a protagonist of Cauchy's new rigor, spoke of “exceptions” when he criticized Cauchy's theorem on the continuity of sums of continuous functions. However, when interpreted contextually, exceptions appear as both valid and viable entities in the early 19th century. First, Abel's use of the term “exception” and the role of the exception in his binomial paper is documented and analyzed. Second, it is suggested how Abel may have acquainted himself with the exception and his use of it in a process denoted critical revision is discussed. Finally, an interpretation of Abel's exception is given that identifies it as a representative example of a more general transition in the understanding of mathematical objects that took place during the period. With this interpretation, exceptions find their place in a fundamental transition during the early 19th century from a formal approach to analysis toward a more conceptual one.     

Rapid convergence of a Galerkin projection of the KdV equation

In this Note, it is shown that a Fourier Galerkin approximation of the Korteweg–de Vries equation with periodic boundary conditions converges exponentially fast if the initial data can be continued analytically to a strip about the real axis. To cite this article: H. Kalisch, C. R. Acad. Sci. Paris, Ser. I 341 (2005).     

A link between Wilson’s and d’Alembert’s functional equations

If \({f, g : G \to \mathbb{C}}\), f ≠ 0, is a solution of Wilson’s functional equation on a group G, then g is a d’Alembert function.     

The Remainder in Ruijsenaars’ Asymptotic Expansion of Barnes Double Gamma Function

We show that the remainder in Ruijsenaars’ asymptotic expansion of the logarithm of Barnes double gamma function gives rise to a completely monotone function. Fourier expansions of the multiple Bernoulli polynomials are also obtained. Research supported by the Carlsberg Foundation.     

Representations, convolution square roots and spherical vectors

We extend results on square integrable representations of a locally compact group to subrepresentations of a representations induced from a character of a closed subgroup. We do so working in the framework of quotient representations of ∗-algebras.     

On the reduction number of some graded algebras

The main result of the paper confirms, for generic coordinates, a conjecture which states that . Here is a homogeneous polynomial ideal in and and are the reduction numbers.