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91.
In situ formation of allyl ketones via Hiyama-Nozaki reactions followed by a chromium-mediated Oppenauer oxidation 总被引:1,自引:0,他引:1
Schrekker HS de Bolster MW Orru RV Wessjohann LA 《The Journal of organic chemistry》2002,67(7):1975-1981
In Hiyama-Nozaki reactions of allylchromium with aldehydes the expected products are homoallylalcohols. However, oxidation products derived from these, predominantly allyl ketones, can be common side products. This can be explained by an Oppenauer-(Meerwein-Ponndorf-Verley)-type mechanism (OMPV-reaction). The amount of oxidation is strongly dependent on the substitution pattern of the reaction partners and the reaction conditions. An appropriate choice of these can lead to preferential formation of ketones instead of the alcohols. In addition to its synthetic usefulness, the oxidation-reduction equilibrium is of the utmost importance for the design of enantioselective Hiyama-Nozaki reactions because it is also a potential racemization pathway. 相似文献
92.
[structure: see text] A new type of donor-spacer-acceptor podand system has been synthesized and proved as an efficient dual channel fluorosensor for Li+, Mg2+, and Ca2+. The known ability for the N-oxide function to bind Lewis acids is the key step in the appearance of a new emitting charge-transfer (CT) excited state. The occurrence of this CT state for alkaline earth (Mg2+ and Ca2+) and not for alkaline metals (Li+) provided a new type of dual channel fluorosensors. 相似文献
93.
In previous papers [1, 2], we presented hyperbolic governing equations and jump conditions for barotropic fluid mixtures. Now we extend our results to the most general case of twocomponent media. We obtain governing equations for each component. This is not a system of conservation laws. Nevertheless, using Hamilton's principle we are able to obtain a complete set of Rankine–Hugoniot conditions. For the twofluid case, the jump relations do not involve the conservation of the total momentum and the total energy.Sommario. In precedenti lavori [1, 2] sono state dedotte equazioni di governo iperboliche e condizioni di salto per miscele fluide barotropiche. I risultati sono estesi al caso più generale di mezzi a due componenti, ottenendo le equazioni di governo per ciascun componente. Questo sistema non è derivabile dalle leggi di conservazione. Nondimeno, usando il principio di Hamilton è possibile ottenere un insieme completo di condizioni di Rankine–Hugoniot. Nel caso dei due fluidi, le condizioni di salto non coinvolgono la conservazione del momento e dell'energia totali. 相似文献
94.
A study of the microbiological reduction of different α-halogenoketones (4-chloro-3-octanone, 4-chloro-5-nonanone, 5-bromo-4-nonanone and 5-chloro-4-nonanone) with several strains of microorganism showed great difficulty in reducing ketone functions located in the middle of carbon chains. However, by choosing the appropriate microorganism, several enantiomerically pure diastereoisomers of the corresponding halohydrins have been obtained and were transformed into chiral epoxides. 相似文献
95.
Henri Faure 《Journal of Number Theory》1983,16(3):376-394
We get the asymptotic behaviour of the remainder function with respect to the Van Der Corput generalized sequences construted in a previous paper (in Bulletin de la S.M.F, no 109, 1981). As a consequence, we obtain the intervals [0, a] for which the remainder is bounded. Moreover, we give an explicit formula for the remainder with respect to the Van Der Corput sequence in the r-adic system. 相似文献
96.
97.
Catecholamine levels in body fluids are reliable biochemical markers of several types of tumors, cardiovascular diseases and hereditary and metabolic disorders. Reversed-phase liquid chromatography with electrochemical detection (RPLC-EC) is now the method of choice for catecholamine analysis. 相似文献
98.
99.
The synthesis of three lipophilic n-dodecyl tetraazacycloalkanes is described. Extraction of Cu(II), Cd(II) and Pb(II) is related. 相似文献
100.
Ionic and radical mechanistic steps are postulated in order to explain the formation of the rearrangement-, the isomerization- and the fragmentation-products isolated during the thermal treatment of pyrazolo-diazepines. 相似文献