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991.
The adsorption isotherms of four activated carbons (Norit RB1, Chemviron BPL, Monolit, and Ambersorb-572) have been examined by nitrogen adsorption at 77.5 K. A method for adsorption potential distribution calculation has been proposed based on the adsorption isotherms. This distribution provides information about possible changes in the Gibbs free energy caused by the energetic and geometrical heterogeneities of an activated carbon as well as by the adsorbate-related entropic effects. The general character of the adsorption potential distribution is clearly visible by its simple relation to the micropore and mesopore distribution. 相似文献
992.
采用自制的近红外双波长脑血氧监测仪实时采集人脑血和氧的数据,应用功率谱和相关函数的方法对采集的脑血氧的数据波形进行分析.结果发现正常人脑血氧波形之间有着严格的相关性,功率谱曲线主频峰清晰,血氧的功率谱曲线吻合好;脑缺氧病人血氧波形间的相关性差,功率谱曲线表现为主频峰不清晰,功率谱曲线吻合性差。临床试验表明:脑血氧波形、功率谱和相关函数对于分析人脑血、氧生理状况及其变化具有较好的效果。 相似文献
993.
Abhishek Roy Michael A. Hickner Xiang Yu Yanxiang Li Thomas E. Glass James E. McGrath 《Journal of Polymer Science.Polymer Physics》2006,44(16):2226-2239
One of the integral parts of the fuel cell is the proton exchange membrane. Our research group has been engaged in the past few years in the synthesis of several sulfonated poly(arylene ether) random copolymers. The copolymers were varied in both the bisphenol structure as well as in the functional groups in the backbone such as sulfone and ketones. To compare the effect of sequence length, multiblock copolymers based on poly(arylene ether sulfone)s were synthesized. This paper aims to describe our investigation of the effect of chemical composition, morphology, and ion exchange capacity (IEC) on the transport properties of proton conducting membranes. The key properties examined were proton conductivity, methanol permeability, and water self diffusion coefficient in the membranes. It was observed that under fully hydrated conditions, proton conductivity for both random and block copolymers was a function of IEC and water uptake. However, under partially hydrated conditions, the block copolymers showed improved proton conductivity over the random copolymers. The proton conductivity for the block copolymer series was found to increase with increasing block lengths under partially hydrated conditions. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2226–2239, 2006 相似文献
994.
XiangKaiFU XueBingMA 《中国化学快报》2002,13(9):839-842
The highly water-soluble phosphine ligands Na2O3PCH2CH2NH(CH2CH2O)nCH2CH2N-(CH2PPh)22(n=1,2,3) were prepared by a new and simple route under mild conditions in good yield; the palladium (Ⅱ) complexes of the ligands 3a-c with 2:1 or 4:1 -PPh2 to Pd^2 molar ratio were also prepared and characterized. 相似文献
995.
Yi‐Lei Chen Chang‐Heng Tan Jun‐Jie Tan Shi‐Jin Qu Heng‐Bin Wang Qiang Zhang Shan‐Hao Jiang Da‐Yuan Zhu 《Helvetica chimica acta》2007,90(12):2421-2426
Pyrocallianthasides A ( 1 ) and B ( 2 ), a new dimer and a new mono‐deglucosyl trimer of homoarbutin (=4‐hydroxy‐3‐methylphenyl β‐glucopyranoside), and callianthaside A ( 3 ), a new ursane‐type triterpene glycoside, together with three known phenolic glycosides and three known ursane‐type triterpenoids, were isolated from the whole plants of Pyrola calliantha. The structures of 1 – 3 were elucidated by chemical and spectroscopic methods. 相似文献
996.
Chi-Sing Man Roberto Paroni Yu Xiang Edward A. Kenik 《Journal of Computational and Applied Mathematics》2006,190(1-2):200-210
Herein we derive an expression for direct determination of the geometric autocorrelation function W of a polycrystalline material from images of its grain boundary network (e.g., those delivered by orientation imaging microscopy). We also obtain an identity that relates the mean linear intercept function to a directional derivative of the geometric autocorrelation function. These formulae were applied to examine whether a widely-used formula for W, particularly in theoretical studies of attenuation of elastic waves in polycrystalline media, would be valid for the grain boundary structure of a commercial aluminum alloy. The conclusion was negative. 相似文献
997.
本文研究了具有低阶项的散度型椭圆方程-(a_(ij)u_(x_i))_(x_j)+b_iu_(x_i)-(d_ju)_(x_j)+cu= (f_j)_(x_j),a.e.x∈Ω的解在Morrey空间上的局部正则性,其中a_(ij)∈VMO∩L~∞(Ω),低阶项系数属于适当的Morrey空间. 相似文献
998.
奇异二维p-Laplacian方程多点边值问题正解的存在性 总被引:1,自引:1,他引:0
本文研究具有p-Laplacian算子的奇异多点边值问题{(Фp(u'))'+q(t)f(t,u)=0,0〈t〈1;u(0)=∑n i=1 αiu(ηi),u(i)∑n i=1 βiu(ηi)正解的存在性,其中f(t,u)可以在u=0奇异,q(t)可以在t=0或t=1奇异. 相似文献
999.
林祥 《数学物理学报(A辑)》2006,26(6):897-905
随机稳定性是各种随机模型中的至关重要的问题,随机稳定性中的关键问题是找出过程遍历,指数遍历和强遍历的准则.该文对一类重要的分支过程给出了过程指数遍历及强遍历的条件.在证明中主要应用了几种不同的比较方法,从该文的结果可以看出,这种方法是有效的,因而在其它情形中也是非常有意义的.而且所得结果的概率意义也是十分清楚的. 相似文献
1000.