Matrix effects in the determination of butyltin compounds in environmental samples by GC AA after hydride generation

Experiments for the determination of mono-, di and tri-butyltin (MBT, DBT and TBT) by hydride generation/gas chromatography/atomic absorption spectrometry in various matrices (sediment, suspended matter, mussel, algae and water) have revealed that poor butyltin recoveries are obtained in sediments displaying high sulphur and hydrocarbon contents; very poor recoveries were also observed for TBT in sediments with high chlorophyll pigment contents as well as in algal samples. It was however not clear whether the hydride generatin was inhibited by these infering compounds, as was previously assumed in the case of hydrocarbons, or whether interferences affected the atomization rate. Further studies were performed to solve this problem in order to validate this method in the case of analyses of, for example, oil-contaminated sediment and algae. This paper presents the results obtained. It is concluded here that the poor recoveries were due to an inhibition of hydride generation rather than to interference at the atomization stage.     

Electronic and electromagnetic devices for millimeter-wave beam control arrays

Device alternatives for millimeter-wave beam control arrays are examined. For the control function, a wide range of semiconductor device as well as bulk material alternatives are considered. In addition, alternatives to the traditional metal strip are considered for the passive electromagnetic array element. This work should provide a broader perspective regarding the choices available for the optimized design of new beam control arrays.     

Spherical harmonic representation of the gravitational coupling between a truncated sector of a hollow cylinder and an arbitrary gravitational source: Relevance to the STEP experiment

The gravitational interaction between grooves machined in a hollow cylindrical mass of uniform density, and an external point mass, is derived in terms of the Associated Legendre functions, and the parametric form of the coupling coefficients is presented. The cross-sections of the grooves, which are regularly spaced in azimuth, are in the form of truncated sectors of the cylinder's end-faces. This theory is applied to the test-masses for the Satellite Test of the Equivalence Principle (STEP) experiment, for which four grooves have been assumed, and an expression for the axialforce is derived which is more than 10⁴ times faster to compute than a Monte-Carlo integration of similar accuracy. Following this analysis it is suggested that the STEP test-masses should carry at least 6 grooves. This theory has wider application to gravitational problems involving general sectored cylindrical bodies.     

金属羰基化合物（CpFe（CO）2）2与金属氧化物表面作用的傅里叶变…

用漫反射红外光谱和光声红外光谱研究了金属羰基化合物（ＣｐＦｅ（ＣＯ）２）２Ｃｐ＝η＾５－Ｃ５Ｈ５与酸性，中性和碱性Ａｌ２Ｏ３及ＴｉＯ２的相互作用，结果表明，在Ａｌ２Ｏ３表面生成的洗生物种类及浓度与Ａｌ２Ｏ３的酸碱度明显相关，在酸性Ａｌ２Ｏ３表面，主要存在衍生物（ＣｐＦｅ（ＣＯ）２Ｆｅ－Ｈ－Ｆｅ（ＣＯ２Ｃｐ）＾＋及少量的ＣｐＦｅ（ＣＯ）２（－Ｏ－）；在中性Ａｌ２Ｏ３表面存在的ＣｐＦｅ（ＣＯ）２（－Ｏ     

Quantum Thermal Effect of Dirac Particles in a Nonuniformly Rectilinearly Accelerating Black Hole with Electric Charge, Magnetic Charge, and Cosmological Constant

The Hawking radiation of Dirac particles in an arbitrarily rectilinearly accelerating Kinnersley black hole with electromagnetic charge and cosmological constant is investigated by using the generalized tortoise coordinate transformation. Both the location and the temperature of the event horizon depend on the time and the polar angle. The Hawking thermal radiation spectrum of Dirac particles is also derived.     

Effects of electron-interface-phonon interactions on interactions between electrons in double-heterostructures

Effects of electron-interface-phonon interaction on the interaction between electrons in double heterostructures are considered. It is found that the interaction potential between electrons caused by each of four interface-phonon modes is different. For electrons moving at the two interfaces of double heterostructure, the interaction energies of the electrons produced by the interaction with antisymmetric modes are positive which indicate that the forces between electrons are repulsive. The interaction energies caused by interaction with symmetric modes are negative and the forces are attractive. The resultant of the forces are attractive and become larger when the width of potential barrier decreases for InAs/GaSb/InAs double heterostructure.     

Influence of preparation methods on structure and properties of PA6/PA66 blends: A comparison of melt‐mixing and in situ blending

The blends composed of polyamide 6 (PA6) and polyamide 66 (PA66) were obtained using two different preparation methods, one of which was the melt‐mixing through a twin‐screw extruder and the subsequent injection molding; and the other, the in situ blending through anionic polymerization of ε‐caprolactam in the presence of PA66. For the former, there existed a remarkable improvement in toughness but a drastic drop in strength and modulus; however, for the latter, a reverse but less significant trend of mechanical properties change appeared. Various characterizations were conducted, including the analyses of crystalline morphology, crystallographic form, and crystallization and melting behaviors using polarized optical microscopy (POM), wide‐angle X‐ray diffraction (WAXD), and differential scanning calorimetry (DSC), respectively; observation of morphology of fractured surface with scanning electron microscope (SEM); measurement of glass transition through dynamic mechanical analysis (DMA); and the intermolecular interaction as well as the interchange reaction between the two components by Fourier transform infrared spectrometry (FT‐IR) and ¹³C solution NMR. The presence and absence of interchange reaction was verified for the in situ and melt‐mixed blends, respectively. It is believed that the transreaction resulted in a drop in glass transition temperature (T_g) for the in situ blends, contrary to an increase of T_g with increasing PA66 content for the melt‐mixed ones. And the two kinds of fabrication methods led to significant differences in the crystallographic form, spherulite size and crystalline content and perfection as well. Accordingly, it is attempted to explain the reasons for the opposite trends of changes in the mechanical properties for these two blends. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1176–1186, 2007     

General Information

In this paper, we propose and analyze an SQP-type method for solving linearly constrained convex minimization problems where the objective functions are too complex to be evaluated exactly. Some basic results for global convergence and local superlinear convergence are obtained according to the properties of the approximation sequence. We illustrate the applicability of our approach by proposing a new method for solving two-stage stochastic programs with fixed recourse.