全文获取类型
收费全文 | 974篇 |
免费 | 57篇 |
国内免费 | 7篇 |
专业分类
化学 | 714篇 |
晶体学 | 4篇 |
力学 | 11篇 |
数学 | 175篇 |
物理学 | 134篇 |
出版年
2023年 | 5篇 |
2022年 | 13篇 |
2021年 | 17篇 |
2020年 | 34篇 |
2019年 | 35篇 |
2018年 | 19篇 |
2017年 | 17篇 |
2016年 | 39篇 |
2015年 | 38篇 |
2014年 | 42篇 |
2013年 | 65篇 |
2012年 | 53篇 |
2011年 | 63篇 |
2010年 | 53篇 |
2009年 | 24篇 |
2008年 | 87篇 |
2007年 | 49篇 |
2006年 | 54篇 |
2005年 | 43篇 |
2004年 | 26篇 |
2003年 | 25篇 |
2002年 | 28篇 |
2001年 | 13篇 |
2000年 | 18篇 |
1999年 | 19篇 |
1998年 | 7篇 |
1997年 | 12篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 14篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1987年 | 5篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1975年 | 6篇 |
1974年 | 7篇 |
1973年 | 3篇 |
1972年 | 5篇 |
1965年 | 2篇 |
排序方式: 共有1038条查询结果,搜索用时 15 毫秒
41.
42.
Temple H. Fay P. Hendrik Kloppers 《International Journal of Mathematical Education in Science & Technology》2013,44(1):73-89
This paper analyses the answers of a group of first-year university Mathematics students to a questionnaire, with the aim of determining the difficulties they have when carrying out non-routine tasks related to improper integrals. The questionnaire consisted of nine questions including not only calculus tasks and determining the convergence of given improper integrals, but also intuitive questions and some paradoxical results too (for example, a figure with an infinite longitude which closes the same area as the unit circumference, or an infinite figure with a finite volume). In particular, the students were asked to interpret most of the results they had obtained. Answers given by the students to each of the questions were categorized, which allowed some initial conclusions to be reached regarding this research. From analyses carried out, one can conclude that there are students who have difficulties in articulating the different systems of representation, and have problems in connecting and relating this knowledge as a generalization of previous concepts, such as definite integrals, series and sequences. 相似文献
43.
Linear conditions for a C 0 spline to be convex are developed and used to create some convexity preserving interpolation and approximation methods. 相似文献
44.
45.
46.
Hendrik P. Benschop C. A. G. Konings L. P.A. De Jong H. Kienhuis J. Van Genderen 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-3):345-349
Abstract The four stereoisomers of pinacolyl methylphospho-nofluoridate (soman) were isolated with more than 99% optical purity. The bimolecular rate constants for inhibition of electric eel acetylcholinesterase and the LD50-values (sc, mice) of the stereoisomers were determined. 相似文献
47.
Dr. Markus Lampimäki Dr. Veronika Zelenay Dr. Adéla Křepelová Dr. Zhi Liu Rui Chang Dr. Hendrik Bluhm Dr. Markus Ammann 《Chemphyschem》2013,14(11):2419-2425
Ozone adsorption and decomposition on metal oxides is of wide interest in technology and in atmospheric chemistry. Here, ozone‐adsorption‐induced band bending is observed on Ti‐ and Fe‐oxide model surfaces under dry and humid conditions. Photoelectron spectroscopic studies indicate the effect of charge transfer to O3, which limits the surface coverage of the precursor to decomposition reactions. This is also consistent with the negative pressure dependence observed in previous studies. These results contribute to our fundamental understanding of ozone adsorption and decomposition mechanisms on metal oxides of environmental and technological relevance. 相似文献
48.
Raman Tandon Teresa Unzner Dr. Tobias A. Nigst Dr. Nicolas De Rycke Dr. Peter Mayer Dr. Bernd Wendt Dr. Olivier R. P. David Prof. Dr. Hendrik Zipse 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(20):6435-6442
New heterocyclic derivatives of 9‐azajulolidine have been synthesized and characterized with respect to their nucleophilicity and Lewis basicity. The Lewis basicity of these bases as quantified through their theoretically calculated methyl‐cation affinities correlate well with the experimentally measured reaction rates for addition to benzhydryl cations. All newly synthesized pyridines show exceptional catalytic activities in benchmark acylation reactions, which correlate only poorly with Lewis basicity or nucleophilicity parameters. A combination of Lewis basicity with charge and geometric parameters in the framework of a three‐component quantitative structure–activity relationship (QSAR) model is, however, highly predictive. 相似文献
49.
50.
Dr. Natércia F. Brás Salavat S. Ashirbaev Prof. Hendrik Zipse 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(11):e202104240
The oxidized form of baicalein ( BA ) leads to covalent binding with human amyloid proteins. Such adducts hamper the aggregation and deposition of fibrils. A novel reaction of BA with pentylamine ( PA ) as a model for the lysine side chain is described. This is the first study addressing the atomistic details of a Schiff base reaction with the trihydroxylated moiety of BA . Nuclear magnetic resonance and mass spectrometry approaches clearly indicate the formation of dehydrobaicalein in solution as well as its condensation with PA under aerobic conditions, yielding regioselectively C6-substituted products. The combined results suggest initial ion pair formation between BA and PA , followed by a redox chain reaction: the initiation by oxygen/air; an o-quinone-based chain involving oxidation and reduction steps; and extra off-chain formation of a doubly oxidized product. These mechanistic details support the anti-amyloid activity of BA and endorse its trihydroxyphenyl moiety as a pharmacophore for drug-design studies. 相似文献