Über Reduktionen mittels Aluminiumpulver in konzentriert-schwefelsaurer Lösung

Ohne Zusammenfassung     

Zur Kenntnis der isomeren Ölsäuren

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Mathematical modelling of selected characterisation procedures for oil fractions

Models of two important characterisation procedures for oil and oil fractions, ASTM D86 (ASTM = American Society for Testing of Materials) and EFV (Equilibrium Flash Vaporization), were presented. The purpose was to provide a basis for the construction of substitute mixtures of real components used in modelling and simulation of chemical engineering processes instead of original complex mixtures. It was shown how to deal with a possible problem of higher index of differential-algebraic model of the ASTM D86. A number of examples proved the adequacy of the presented models. Presented at the 34th International Conference of the Slovak Society of Chemical Engineering, Tatranské Matliare, 21–25 May 2007.     

Crystal Structure,Magnetism, 89Y Solid State NMR,and 121Sb Mössbauer Spectroscopic Investigations of YIrSb

The ternary antimonide YIrSb was synthesized from the binary precursor YIr and elemental antimony by a diffusion controlled solid‐state reaction. Single crystals were obtained by a flux technique with elemental bismuth as an inert solvent. The YIrSb structure (TiNiSi type, space group Pnma) was refined from single‐crystal X‐ray diffractometer data: a = 711.06(9), b = 447.74(5), c = 784.20(8) pm, wR₂ = 0.0455, 535 F² values, 20 variables. ⁸⁹Y solid state MAS NMR and ¹²¹Sb Mössbauer spectra show single resonance lines in agreement with single‐crystal X‐ray data. YIrSb is a Pauli paramagnet.