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951.
Dao-Hua Zou Yu Jin Wang Kang Zhi-Jun Wu Chun-Ping Xiang 《Chinese Journal of Physics (Taipei)》2018,56(2):683-688
We improved the power conversion efficiency (PCE) of the small molecular (S-M) tandem organic solar cells (TOSCs) by employing different low work function alloy nanoparticle intermediate layers. The enhancement of the PCE was mainly attributed to the gap states formed at the interface between the buffer layer and alloy nanoparticle intermediate layer. The gap states result in the disappearance of the electron injection barrier. Compared with the planar heterojunction (PHJ) TOSCs with single Ag nanoparticle intermediate layer, the PCE of the PHJ TOSC with the Mg-Ag alloy nanoparticle intermediate layer exhibits an enhancement of 7.5%. Moreover, the Mg-Ag alloy nanoparticle intermediate layer was also employed in the bulk-heterojunction (BHJ) TOSCs. Compared with the PHJ TOSCs, the PCE of the BHJ TOSCs with Mg-Ag alloy nanoparticle intermediate layer is doubled and achieves a value of 5.54%. 相似文献
952.
953.
通过一系列化学反应合成得到了Eu(ally-DBM)3-2TPPO和PNIPAM形成的大分子水溶性发光配合物. 本文通过TGA、GPC、HNMR表征复合物的结构,并研究了配合物在水溶液中的荧光热响应性. 研究发现,PNIPAM在低临界溶解温度以上塌缩引起配位键断裂,导致Eu3+的荧光减弱和配体荧光增强. 当温度降低时,发现Eu3+的荧光增强,配体荧光相应减弱. 推断当温度降低时配体再次与铕离子重新配位,并通过红外光谱进一步证实了. 这种配合物的荧光热响应性具有可逆性,可用作分子探针应用在生物成像方面和研究PNIPAM塌缩. 相似文献
954.
针对VxWorks启动映像依赖于ROM地址,不能适应航天型号中三模存储要求的缺点,利用VxWorks自带的压缩算法,按照航天型号软件任务要求设计了一种基于VxWorks内存型映像的新型压缩映像,实现了软件映像与ROM区地址无关。并且实现了新型压缩映像的三模冗余引导启动,启动时每一个bit数据都从三份映像获取,并进行三取二判断,将最后结果拷贝到内存作为目的映像的bit数据,目的映像启动后能够回写正确数据自动纠正空间环境下可能发生的单粒子翻转错误,为软件的可靠启动建立了基础。 相似文献
955.
在水平激波管中,采用平面激光诱发荧光(planar laser-induced fluorescence, PLIF)方法对椭圆形重气柱界面的Richtmyer-Meshkov不稳定性进行实验。气柱由SF6混入一定比例的丙酮蒸气构成,环境气体为空气。通过改变椭圆形气柱的长短轴比值,得到了激波马赫数为1.25时,3种初始界面的演化形态。通过相对体积分数标定,得到了界面失稳演化过程中的相对体积分数分布,观察到了激波作用后界面气体聚集、转移、消散等现象。实验结果发现,对于流向轴长与展向轴长之比较大的气柱界面,初始界面产生的涡量更大且分布更广,其界面不稳定性发展得越迅速和剧烈。失稳发展迅速的界面甚至出现涡对碰撞并产生尾部射流结构的现象。初始界面直接决定了失稳发展初期形成的涡对强度和间距,并对后期演化有重要影响。 相似文献
956.
Yiyu Yang Ran Xiao Xiaosong Cao Zhanxiang Chen Xialei Lv Youming Zhang Shaolong Gong Yang Zou Chuluo Yang 《Molecules (Basel, Switzerland)》2021,26(17)
In this work, we demonstrate dibenzothiophene sulfoximine derivatives as building blocks for constructing emitters featuring both thermally activated delayed fluorescent (TADF) and aggregation-induced emission (AIE) properties, with multiple advantages including high chemical and thermal stability, facile functionalization, as well as tunable electron-accepting ability. A series of phenoxazine-dibenzothiophene sulfoximine structured TADF emitters were successfully synthesized and their photophysical and electroluminescent properties were evaluated. The electroluminescence devices based on these emitters displayed diverse emissions from yellow to orange and reached external quantum efficiencies (EQEs) of 5.8% with 16.7% efficiency roll-off at a high brightness of 1000 cd·m−2. 相似文献
957.
Two new nortriterpenoids, paeonenoides D and E ( 1 and 2 , resp.), together with seven known compounds, were isolated from the roots of Paeonia lactiflora. Their structures were elucidated on the basis of spectroscopic evidence. Compounds 1 – 7 were screened for inhibitory effects against NO production in LPS‐induced RAW246.7 macrophages and for cytotoxic activities against HL‐60, Hep‐G2, and SK‐OV‐3 cell lines. Compounds 1 – 3 and 5 – 7 exhibited inhibitory activities with IC50 values in the range of 9.6–32.2 μM . Triterpenoids with an epoxide ring and a free COOH function, 1 – 3 , showed effectively increased activities compared with other pentacyclic triterpenoids. Compounds 1 – 6 showed significant cytotoxic activities against the Hep‐G2 cell line and modest cytotoxic activities against HL‐60 and SK‐OV‐3 cell lines. 相似文献
958.
Microwave plasma torch mass spectrometry for the direct detection of copper and molybdenum ions in aqueous liquids 下载免费PDF全文
Xiaohong Xiong Tao Jiang Runzhi Zhou Shangxian Wang Wei Zou Zhiqiang Zhu 《Journal of mass spectrometry : JMS》2016,51(5):369-377
Microwave plasma torch (MPT) is a simple and low power‐consumption ambient ion source. And the MPT Mass spectra of many metal elements usually exhibit some novel features different from their inductively coupled plasma (ICP) mass spectra, which may be helpful for metal element analysis. Here, we presented the results about the MPT mass spectra of copper and molybdenum elements by a linear ion trap mass spectrometer (LTQ). The generated copper or molybdenum contained ions in plasma were characterized further in collision‐induced dissociated (CID) experiments. These researches built a novel, direct and sensitive method for the direct analysis of trace levels of copper and molybdenum in aqueous liquids. Quantitative results showed that the limit of detection (LOD) by using MS2 procedure was estimated to be 0.265 µg/l (ppb) for copper and 0.497 µg/l for molybdenum. The linear dynamics ranges cover at least 2 orders of magnitude and the analysis of a single aqueous sample can be completed in 5–6 min with a reasonable semi‐quantitative sense. Two practical aqueous samples, milk and urine, were also analyzed qualitatively with reasonable recovery rates and RSD. These experimental data demonstrated that the MPT MS is able to turn into a promising and hopeful tool in field analysis of copper and molybdenum ions in water and some aqueous media, and can be applied in many fields, such as environmental controlling, hydrogeology, and water quality inspection. Moreover, MPT MS could also be used as the supplement of ICP‐MS for the rapid and in‐situ analysis of metal ions. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
959.
LIU ShuQuan BCHERL Thomas ZOU YuBin WANG Sheng LU YuanRong GUO ZhiYu 《中国科学:物理学 力学 天文学(英文版)》2014,57(2):244-250
Fast neutron tomography has been established as an inspection and detection tool at the NECTAR facility at the FRM-II reactor.Scattered neutrons from the object become a major disturbance and bring in artifacts and deviations in reconstruction results,especially for hydrogenous material object.In this article,an iterative scattering correction method for fast neutron tomography was proposed.In each loop of iteration the scattering component of the projections will be simulated by Monte-Carlo program MCNPX based on the previous reconstruction result and then it will be subtracted from original projections.The differences between scattering components at different perspectives were quantitatively evaluated and an average scattering component image was used for all projections finally.Smooth and uniform slices with more clear edges were obtained and the new reconstructed attenuation coefficients are quite close to the real one compared to the results without scattering correction,in which case the relative error of the reconstructed attenuation coefficients is about 10%–30%. 相似文献
960.
According to the requirements for the beam collimation system of the rapid cycling synchrotron(RCS)of China Spallation Neutron Source(CSNS),the main structure of a scraper of primary collimator is made by W/Cu brazing,in which the thickness of tungsten slice is 0.17 mm.In order to get the best mechanical properties,the brazing temperature is suggested to be controlled under the recrystallization temperature of tungsten,while the recrystallization temperature is affected directly by the thickness of tungsten.Because of little research and application on the brazing of thin tungsten slice of 0.17 mm and copper,tensile tests are done to get the mechanical properties of tungsten slices which experience different brazing temperatures.In keeping the inner relationships between the mechanical properties and temperature,another experiment is done by using SEM to scan the microstructures including the size and distribution of crystals.Finally we determine the recrystallization temperature of tungsten slice of 0.17 mm,and get the best parameters of W/Cu brazing for scrapers of primary collimator in CSNS/RCS. 相似文献