Synthesis and Reactivity of 2‐Pyrrolidino‐, 2‐N‐Methylpiperazino‐, 2‐Piperidino‐, and 2‐Morpholino‐1,3,4‐thiadiazines

A variety of 2‐pyrrolidino‐, 2‐N‐methylpiperazino‐, 2‐piperidino‐, and 2‐morpholino‐1,3,4‐thiadiazines were prepared by cyclocondensation of phenacyl halides with thiosemicarbazides. Heating of the products resulted in desulfurization and formation of pyrazoles. The rate of this process strongly depends on the substitution pattern of the 1,3,4‐thiadiazines.     

Changes in the characteristics of acid‐treated clay after the inclusion of proteins

The aim of this work is to study the difference in the characteristics of commercial clay after the inclusion of two proteins. Bovine serum albumin and egg white lysozyme were immobilized on the structure of commercial montmorillonite, which was previously treated with a hydrochloric acid solution. Studies were carried out at two different concentrations, fixing the pH to ensure the charge of biomolecules and clay surface. Acid‐treated clay containing proteins was characterized by X‐ray diffraction, Fourier transformed infrared spectroscopy, thermogravimetric analysis, and nitrogen adsorption at 77 K. The powders showed similar thermal behavior after the inclusion of proteins but with variations in the amount of mass loss in each sample. Moreover, changes in the surface characteristics of the final solid were observed, depending on both the concentration and the nature of the incorporated protein. The differences observed in the acid‐treated clay characteristics after the inclusion of each type of protein are discussed. The characterization of materials after the inclusion of protein molecules can be useful to understand the adsorption mechanism of biomolecules on solid surfaces. Copyright © 2014 John Wiley & Sons, Ltd.     

SN2P2: A Neutral Five‐Membered Sulfur–Pnictogen(III) Ring

The novel aromatic ring compound 2,4‐diphospha‐3,5‐diaza‐thiole (cyclo‐SNPNP) was synthesized via flash pyrolysis of SP(N₃)₃ and characterized by IR spectroscopy and ¹⁵N isotope labeling. Quantum chemical computations indicate its formation by head‐to‐tail dimerization of SNP and subsequent elimination of a sulfur atom from the highly unstable boatlike six‐membered‐ring compound cyclo‐SNPSNP.     

Global conservative solutions of the generalized hyperelastic-rod wave equation

We prove existence of global and conservative solutions of the Cauchy problem for the nonlinear partial differential equation where f is strictly convex or concave and g is locally uniformly Lipschitz. This includes the Camassa-Holm equation (f(u)=u²/2 and g(u)=κu+u²) as well as the hyperelastic-rod wave equation (f(u)=γu²/2 and g(u)=(3−γ)u²/2) as special cases. It is shown that the problem is well-posed for initial data in H¹(R) if one includes a Radon measure that corresponds to the energy of the system with the initial data. The solution is energy preserving. Stability is proved both with respect to initial data and the functions f and g. The proof uses an equivalent reformulation of the equation in terms of Lagrangian coordinates.     

One-dimensional band-edge absorption in a doped quantum wire

Low-temperature photoluminescence-excitation spectra are studied in an n-type modulation-doped T-shaped single quantum wire with a gate to tune electron densities. With a nondegenerate one-dimensional (1D) electron gas, the band-edge absorption exhibits a sharp peak structure induced by the 1D density of states. When the dense 1D electron gas is degenerate at a low temperature, we observe a Fermi-edge absorption onset without many-body modifications.     

Biexciton gain and the Mott transition in GaAs quantum wires

Optical gain and the Mott transition in GaAs quantum wires were studied via simultaneous measurements of absorption and photoluminescence (PL). We observed well-separated PL peaks assigned to excitons (X) and biexcitons (XX) even at densities where optical gain existed. A sharp optical gain first appeared when the XX peak overtook the X peak, indicating the gain origin of biexciton-exciton population inversion. The XX peak eventually changed to a broad peak of plasma, and a broad gain due to plasma was observed as the Mott transition was completed.     

Fermi edge polaritons in a microcavity containing a high density two-dimensional electron gas

Sharp, near band gap lines are observed in the reflection and photoluminescence spectra of GaAs/AlGaAs structures consisting of a modulation doped quantum well (MDQW) that contains a high density two-dimensional electron gas (2DEG) and is embedded in a microcavity (MC). The energy dependence of these lines on the MC-confined photon energy shows level anticrossings and Rabi splittings very similar to those observed in systems of undoped QW's embedded in a MC. The spectra are analyzed by calculating the optical susceptibility of the MDQW in the near band gap spectral range and using it within the transfer matrix method. The calculated reflection spectra indicate that the sharp spectral lines are due to k{ parallel}=0 cavity polaritons that are composed of e-h pair excitations just above the 2DEG Fermi edge and are strongly coupled to the MC-confined photons.     

An all-optical trap for a gram-scale mirror

We report on a stable optical trap suitable for a macroscopic mirror, wherein the dynamics of the mirror are fully dominated by radiation pressure. The technique employs two frequency-offset laser fields to simultaneously create a stiff optical restoring force and a viscous optical damping force. We show how these forces may be used to optically trap a free mass without introducing thermal noise, and we demonstrate the technique experimentally with a 1 g mirror. The observed optical spring has an inferred Young's modulus of 1.2 TPa, 20% stiffer than diamond. The trap is intrinsically cold and reaches an effective temperature of 0.8 K, limited by technical noise in our apparatus.     

Hard-x-ray lensless imaging of extended objects

We demonstrate a hard-x-ray microscope that does not use a lens and is not limited to a small field of view or an object of finite size. The method does not suffer any of the physical constraints, convergence problems, or defocus ambiguities that often arise in conventional phase-retrieval diffractive imaging techniques. Calculation times are about a thousand times shorter than in current iterative algorithms. We need no a priori knowledge about the object, which can be a transmission function with both modulus and phase components. The technique has revolutionary implications for x-ray imaging of all classes of specimen.