全文获取类型
收费全文 | 322篇 |
免费 | 2篇 |
专业分类
化学 | 87篇 |
晶体学 | 6篇 |
力学 | 4篇 |
数学 | 27篇 |
物理学 | 200篇 |
出版年
2023年 | 3篇 |
2021年 | 4篇 |
2020年 | 4篇 |
2017年 | 2篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 3篇 |
2013年 | 9篇 |
2012年 | 9篇 |
2011年 | 12篇 |
2010年 | 3篇 |
2009年 | 6篇 |
2008年 | 13篇 |
2007年 | 33篇 |
2006年 | 20篇 |
2005年 | 37篇 |
2004年 | 27篇 |
2003年 | 6篇 |
2002年 | 8篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1998年 | 7篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 6篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 6篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 5篇 |
1972年 | 3篇 |
1971年 | 2篇 |
1968年 | 2篇 |
1967年 | 2篇 |
1965年 | 2篇 |
1936年 | 3篇 |
1931年 | 1篇 |
1927年 | 1篇 |
1910年 | 2篇 |
1905年 | 2篇 |
1863年 | 2篇 |
排序方式: 共有324条查询结果,搜索用时 15 毫秒
41.
E. Papirer E. Walter A. Vidal E. Held 《Journal of magnetism and magnetic materials》1993,120(1-3):53-57
The surface properties of needle-shaped iron pigments for magnetic recording media have been determined by inverse gas chromatography. It is shown that the outer passivating layer is responsible for the physical adsorption characteristics of the pigments. 相似文献
42.
43.
We present a novel approach to calculating Low-Energy Electron Diffraction (LEED) intensities for ordered molecular adsorbates. First, the intra-molecular multiple scattering is computed to obtain a non-diagonal molecular T-matrix. This is then used to represent the entire molecule as a single scattering object in a conventional LEED calculation, where the Layer Doubling technique is applied to assemble the different layers, including the molecular ones. A detailed comparison with conventional layer-type LEED calculations is provided to ascertain the accuracy of this scheme of calculation. Advantages of this scheme for problems involving ordered arrays of molecules adsorbed on surfaces are discussed. 相似文献
44.
Spectrally resolved luminescence associated with the decay of bound multiexciton complexes in optically excited Ge:Ga is observed. This is the first reported observation of multiexciton complexes in p-type germanium. The observed spectra are consistent with the shell model for bound multiexciton complexes.No-phonon, TA, LA, and TO phonon assisted luminescence are observed. From these spectra, the energies of the LA, TA, and TO phonons in Ge:Ga are determined. 相似文献
45.
Ohne ZusammenfassungStipendiat des Schweizerischen Nationalfonds 相似文献
46.
47.
The “relaxation” procedure introduced by Held and Karp for approximately solving a large linear programming problem related to the traveling-salesman problem is refined and studied experimentally on several classes of specially structured large-scale linear programming problems, and results on the use of the procedure for obtaining exact solutions are given. It is concluded that the method shows promise for large-scale linear programming 相似文献
48.
Xu S Held I Kempf B Mayr H Steglich W Zipse H 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(16):4751-4757
The acetylation of tert-butanol with acetic anhydride catalyzed by 4-(dimethylamino)pyridine (DMAP) has been studied at the Becke3 LYP/6-311 + G(d,p)//Becke3 LYP/6-31G(d) level of theory. Solvent effects have been estimated through single-point calculations with the PCM/UAHF solvation model. The energetically most favorable pathway proceeds through nucleophilic attack of DMAP at the anhydride carbonyl group and subsequent formation of the corresponding acetylpyridinium/acetate ion pair. Reaction of this ion pair with the alcohol substrate yields the final product, tert-butylacetate. The competing base-catalyzed reaction pathway can either proceed in a concerted or in a stepwise manner. In both cases the reaction barrier far exceeds that of the nucleophilic catalysis mechanism. The reaction mechanism has also been studied experimentally in dichloromethane through analysis of the reaction kinetics for the acetylation of cyclohexanol with acetic anhydride, in the presence of DMAP as catalyst and triethylamine as the auxiliary base. The reaction is found to be first-order with respect to acetic anhydride, cyclohexanol, and DMAP, and zero-order with respect to triethyl amine. Both the theoretical as well as the experimental studies strongly support the nucleophilic catalysis pathway. 相似文献
49.
Merbromin, produced in many countries and used world wide as an antiseptic under the trademark "mercurochrome", is shown to be an efficient sensitizer for type II (singlet oxygen) photo-oxygenations by using 2-methyl-2-butene, (+)-limonene, (+)-alpha-pinene, alpha,alpha'-dimethylstilbenes and (--)-L-methionine as oxygen acceptors. Type I photo-oxygenations are negligible. An estimate of the quantum yield of singlet oxygen formation by merbromin in methanol gives a value of about 0.1. 相似文献
50.
Aubert B Bona M Boutigny D Couderc F Karyotakis Y Lees JP Poireau V Tisserand V Zghiche A Grauges E Palano A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Battaglia M Brown DN Button-Shafer J Cahn RN Charles E Gill MS Groysman Y Jacobsen RG Kadyk JA Kerth LT Kolomensky YG Kukartsev G Lynch G Mir LM Orimoto TJ Pripstein M Roe NA Ronan MT Wenzel WA Sanchez Pdel A Barrett M Ford KE Hart AJ Harrison TJ Hawkes CM Watson AT Held T Koch H Lewandowski B Pelizaeus M Peters K 《Physical review letters》2006,97(26):261803
We report measurements of the decays B(+)-->phiphiK(+) and B(0)-->phiphiK(0) using a sample of 231 x 10(6) BB pairs collected with the BABAR detector at the PEP-II asymmetric-energy B factory at the Stanford Linear Accelerator Center. The branching fractions are measured to be B(B(+)-->phiphiK(+))=(7.5+/-1.0(stat)+/-0.7(syst)) x 10(-6) and B(B(0)-->phiphiK(0))=(4.1(-1.4)(+1.7)(stat)+/-0.4(syst)) x 10(-6) for a phiphi invariant mass below 2.85 GeV/c(2). 相似文献