Three-loop relation of quark\overline {MS} and pole masses

We calculate, exactly, the next-to-leading correction to the relation between the \(\overline {MS} \) quark mass, \(\bar m\) , and the scheme-independent pole mass,M, and obtain $$\begin{gathered} \frac{M}{{\bar m(M)}} \approx 1 + \frac{4}{3}\frac{{\bar \alpha _s (M)}}{\pi } + \left[ {16.11 - 1.04\sum\limits_{i = 1}^{N_F - 1} {(1 - M_i /M)} } \right] \hfill \\ \cdot \left( {\frac{{\bar \alpha _s (M)}}{\pi }} \right)^2 + 0(\bar \alpha _s^3 (M)), \hfill \\ \end{gathered} $$ as an accurate approximation forN _F?1 light quarks of massesM _i <M. Combining this new result with known three-loop results for \(\overline {MS} \) coupling constant and mass renormalization, we relate the pole mass to the \(\overline {MS} \) mass, \(\bar m\) (μ), renormalized at arbitrary μ. The dominant next-to-leading correction comes from the finite part of on-shell two-loop mass renormalization, evaluated using integration by parts and checked by gauge invariance and infrared finiteness. Numerical results are given for charm and bottom \(\overline {MS} \) masses at μ=1 GeV. The next-to-leading corrections are comparable to the leading corrections.     

G-invariante Morse-funktionen

If f is a Morse function on a smooth manifold M there exists a homotopy equivalence from M to a CW complex X such that the critical points of f with index are in a one-one correspondence to the -cells of X. In the equivariant case, a similar result holds for a special type of invariant Morse functions. In this paper we prove the existence of such special invariant Morse functions on compact smooth G-manifolds. As a consequence, any compact smooth G-manifold is homotopy equivalent to a G-CW complex. Other applications deal with the Euler number of the fixed point set and Morse inequalities in equivariant homology theory.     

The synthesis of N-substituted ureas II: Nucleophilic substitution of ureas at the carbonyl group

Summary N-Arylsubstituted ureas undergo exchange of the N-residue upon reaction with amines. Using kinetic measurements, investigation of product distribution, regioselectivity, catalysis, and substrate influences, it was shown that this reaction proceeds via a second order nucleophilic substitution at the urea carbonyl center. By means of semiempirical calculations using the MNDO method the alternative mechanism of fragmentation was investigated.

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Zur Synthese N-substituierter Harnstoffe II: Nucleophile Substitution von Harnstoffen an der Carbonylgruppe

Zusammenfassung N-Arylsubstituierte Harnstoffe erleiden bei der Reaktion mit Aminen einen Austausch des N-Restes. Durch kinetische Messungen, Untersuchung der Produktverteilung, Regioselektivität, Katalyse und des Einflusses des Edukts konnte abgeleitet werden, daß es sich hiebei um eine nucleophile Substitution zweiter Ordnung am Carbonylzentrum des Harnstoffs handelt. Durch semiempirische Rechnungen mit Hilfe der MNDO Methode wurde der alternative Reaktionsmechanismus einer Fragmentierung untersucht.