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51.
Griesbeck AG Heinrich T Oelgemöller M Lex J Molis A 《Journal of the American Chemical Society》2002,124(37):10972-10973
An elaborated protocol is described which allows the efficient transformation of di-, tri-, and tetrapeptides into cyclopeptides with a minimum of protection and activation chemistry using the photoinduced electron transfer initiated decarboxylation of N-phthaloyl peptides resulting in C-C coupling between the initially formed carbon radicals. 相似文献
52.
Two methods based on gel permeation chromatography (GPC) [size exclusion chromatography] for the analysis of traces (ng/kg)
of nitrogen and phosphorus containing pesticides (like triazines or phosphothionates) from marine sediment samples are compared:
A macro GPC with Biobeads SX-3 and a chromatography on a high-performance (HP-GPC) column with UV-detection. Results for eight
triazine herbicides, two triazine metabolites, the phenylurea derivative linuron, two acetanilides and two organophosphorus
compounds are given. Concentrations obtained with the HP-GPC are compared with those obtained with a macro GPC approach in
an earlier study.
Received: 4 October 1996/Revised: 20 December 1996/Accepted: 24 December 1996 相似文献
53.
Heinrich Wefelscheid 《Journal of Geometry》1977,9(1-2):127-133
A characterisation of those (B*G)-Geometries (in the sense of Benz) is given, which can be constructed with the help of nearfields F, char F 2, in which the multiplicative group F*(·) has a subgroup A with index [F*:A]=2.
Werner Burau zum 70. Geburtstag gewidmet 相似文献
Werner Burau zum 70. Geburtstag gewidmet 相似文献
54.
55.
56.
Mohamed El-Sayed Hardy Müller Gerd Rheinwald Heinrich Lang Stefan Spange 《Monatshefte für Chemie / Chemical Monthly》2003,50(11):361-370
N-(2′-Hydroxy-4′-N,N-dimethylaminobenzylidene)-4-nitroaniline [HDBN] has been used as a model for investigating intra- and intermolecular D–A (donor–acceptor) interactions in various environments
by means of UV/Vis spectroscopy. UV/Vis spectra of HDBN have been measured in various solvents, ethanolic solutions of different pH, adsorbed on silica, and in the solid state. A bathochromic shift of νmax is observed with increasing the dipolarity/polarizability and HBD (hydrogen bond donor) capacity of the solvent, which is
described by means of a multiple LSE (linear solvation energy) relationship in terms of the empirical Kamlet-Taft solvent polarity parameters. The adsorption of HDBN on Aerosil? 300-silica particles in non-HBA (hydrogen bond acceptor) solvents is explained in the same sense. Mobile protons and sol–gel
entrapping cause a hypsochromic shift due to protonation of the lone electron pair of the 4′-N,N-dimethylamino group. Hydroxide ions attack the 2′-hydroxy group which causes a bathochromic shift. A strong intramolecular
hydrogen bond between the 2′-hydroxyl hydrogen and the imine nitrogen atom is present in the solid-state structure causing
an unprecedented bathochromic shift. 相似文献
57.
C. M. Wai M. E. Dysart M. Blander R. R. Heinrich M. C. Oselka 《Journal of Radioanalytical and Nuclear Chemistry》1988,124(1):21-32
A lanthanum fluoride precipitation method for the separation of18F produced from the18O(p,n)18F reaction in alkali halide salts is described. This radiochemical separation method minimizes interferences from other positron emitters produced by proton bombardment and makes the accurate determination of ppm-level18O in complex alkali halide systems feasible. The interference from the19F(p,d)18F reaction is eliminated by keeping the proton energy less than 8.2 MeV. Applications of this technique to studies of dissolved oxide species in molten alkali halide salts are discussed. 相似文献
58.
Cyclic Silicic Acid Derivatives By reaction of SiCl4 with oxygen at elevated temperatures a number of chlorsiloxanes consisting of more or less fused rings can be prepared of which those components of low molecular weight can be separated by combining distillation and crystallization. Methyl and ethyl esters of silicic acids are obtained by reaction with methyl or ethyl nitrite, resp. The compounds are characterized by silicon n.m.r. and mass spectroscopy. 相似文献
59.
Kinetic investigations of thermo-controlled two-step reactions between an uretdione cross-linker and OH-groups are undertaken. Non-isothermal DSC measurements are chosen for the determination of the kinetic parameters (E, A, n) using of THERMOKINETICS software. The system can be described very accurately with a four-step kinetic model of consecutive reactions. On the basis of the kinetic model and parameters the realization of the first reaction step, which is the formation of the allophanate network is simulated. Finally, the result of the calculated progress of the reaction is evaluated by FT-IR and isothermal DSC measurements. 相似文献
60.
This work is part of an effort to develop chelating agents for stable binding and easy conjugation of Re-188 to biologically interesting structures. Starting from the well-known in vivo stability of [(188)ReO(DMSA)(2)](-), we want to exploit this coordination system for the design of (188)ReO(V) chelates, which are stable toward reoxidation to perrhenate and toward ligand exchange under all conditions of radiopharmaceutical development. Therefore, a new type of tetradentate ligand has been synthesized by bridging two molecules of N,N'-diisobutyl-2,3-dimercaptosuccinamide with N-(3-aminopropyl)propane-1,3-diamine. The resulting stereoisomeric tetrathiolato S(4) ligand of composition ((i)()Bu)(2)N(O)C-C(SH)-C(SH)-C(O)NH-(CH(2))(3)-NH-(CH(2))(3)-NHC(O)-C(SH)-C(SH)-C(O)N((i)Bu)(2) forms anionic five-coordinate oxorhenium(V) complexes by a ligand-exchange reaction of NBu(4)[ReOCl(4)] in methanol. In the absence of a base, the compounds were isolated as "betaine", [ReO(S(4))], with the protonated nitrogen of the bridge serving as an internal "counterion". Two representatives have been fully characterized in both the solid and solution states and found to adopt the expected square-pyramidal coordination geometry. The equatorial plane is formed by four thiolate sulfur atoms, whereas the oxygen occupies the apical position. The orientation of the metal oxo group is exo in relation to the carbamido groups in both isomers. Both complexes are stereoisomeric regarding the junction of the triamine chain. 相似文献