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71.
Frederick F. Tisdal R. D. Bell E. A. Doisy W. Denis L. v. Meysenburg A. P. Briggs W. Grote R. Kuhn C. S. Smith A. L. Brown J. N. Kugelmass und Carmen Rothwell 《Fresenius' Journal of Analytical Chemistry》1927,70(1-2):91-95
Ohne Zusammenfassung 相似文献
72.
J.-L. Vay C.G.R. Geddes E. Cormier-Michel D.P. Grote 《Journal of computational physics》2011,230(15):5908-5929
Modeling of laser-plasma wakefield accelerators in an optimal frame of reference [1] has been shown to produce orders of magnitude speed-up of calculations from first principles. Obtaining these speedups required mitigation of a high-frequency instability that otherwise limits effectiveness. In this paper, methods are presented which mitigated the observed instability, including an electromagnetic solver with tunable coefficients, its extension to accommodate Perfectly Matched Layers and Friedman’s damping algorithms, as well as an efficient large bandwidth digital filter. It is observed that choosing the frame of the wake as the frame of reference allows for higher levels of filtering or damping than is possible in other frames for the same accuracy. Detailed testing also revealed the existence of a singular time step at which the instability level is minimized, independently of numerical dispersion. A combination of the techniques presented in this paper prove to be very efficient at controlling the instability, allowing for efficient direct modeling of 10 GeV class laser plasma accelerator stages. The methods developed in this paper may have broader application, to other Lorentz-boosted simulations and Particle-In-Cell simulations in general. 相似文献
73.
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75.
Summary. The equations describing the mean flow and small-scale interaction of a barotropic flow via topographic stress with layered
topography are studied here through the interplay of theory and numerical experiments. Both a viewpoint toward atmosphere—ocean
science and one toward chaotic nonlinear dynamics are emphasized. As regards atmosphere—ocean science, we produce prototype
topographic blocking patterns without damping or driving, with topographic stress as the only transfer mechanism; these patterns
and their chaos bear some qualitative resemblance to those observed in recent laboratory experiments on topographic blocking.
As regards nonlinear dynamics, it is established that the equations for mean flow and small-scale interaction with layered
anisotropic topography form a novel Hamiltonian system with rich regimes of intrinsic conservative chaos, which include both
global and weak homoclinic stochasticity, as well as other regimes with complete integrability involving complex heteroclinic
structure.
Received August 7, 1997; second revision received December 18, 1997 相似文献
76.
M. G. Beker G. Cella R. DeSalvo M. Doets H. Grote J. Harms E. Hennes V. Mandic D. S. Rabeling J. F. J. van den Brand C. M. van Leeuwen 《General Relativity and Gravitation》2011,43(2):623-656
The next generation gravitational wave interferometric detectors will likely be underground detectors to extend the GW detection frequency band to frequencies below the Newtonian noise limit. Newtonian noise originates from the continuous motion of the Earth??s crust driven by human activity, tidal stresses and seismic motion, and from mass density fluctuations in the atmosphere. It is calculated that on Earth??s surface, on a typical day, it will exceed the expected GW signals at frequencies below 10 Hz. The noise will decrease underground by an unknown amount. It is important to investigate and to quantify this expected reduction and its effect on the sensitivity of future detectors, to plan for further improvement strategies. We report about some of these aspects. Analytical models can be used in the simplest scenarios to get a better qualitative and semi-quantitative understanding. As more complete modeling can be done numerically, we will discuss also some results obtained with a finite-element-based modeling tool. The method is verified by comparing its results with the results of analytic calculations for surface detectors. A key point about noise models is their initial parameters and conditions, which require detailed information about seismic motion in a real scenario. We will describe an effort to characterize the seismic activity at the Homestake mine which is currently in progress. This activity is specifically aimed to provide informations and to explore the site as a possible candidate for an underground observatory. Although the only compelling reason to put the interferometer underground is to reduce the Newtonian noise, we expect that the more stable underground environment will have a more general positive impact on the sensitivity. We will end this report with some considerations about seismic and suspension noise. 相似文献
77.
Computational studies are used to show that the crystalline structure of Si causes the waveguide Kerr effective nonlinearity, γ, to vary by 10% for in-plane variation of the orientation of a silicon nanowire waveguide (SiNWG) fabricated on a standard silicon-on-insulator wafer. Our analysis shows that this angular dependence of γ can be employed to form a nonlinear Kerr grating in dimensionally uniform SiNWGs based on either ring resonators or cascaded waveguide bends. The magnitude of the nonlinear index variation in these gratings is found to be sufficient for phase matching in four-wave mixing and other optical parametric processes. 相似文献
78.
Christopher Finke Dirk Grote Rüdiger W. Seidel Sergei V. Chapyshev Wolfram Sander 《Journal of Physical Organic Chemistry》2012,25(6):486-492
The photochemistry of 2,4,6‐triazido‐3,5‐difluoropyridine 21 was investigated by matrix infrared and electron paramagnetic resonance spectroscopies. Ultraviolet irradiation (>260 nm) of 21 results in the formation of 3,5‐difluoropyridyl‐2,4,6‐trinitrene 26 in yields high enough for characterization by infrared spectroscopy. The experimental infrared spectrum is in good agreement with density functional theory calculations. Under similar conditions, a very strong electron paramagnetic resonance spectrum of septet trinitrene 26 was obtained. Shorter irradiation times resulted in more complex product mixtures containing, in addition, mononitrenes and dinitrenes. Surprisingly, azirines and keteneimines, the typical photoproducts of arylnitrenes, were not observed. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
79.
Dirk Grote Dr. Christopher Finke Simone Kossmann Frank Neese Prof. Dr. Wolfram Sander Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(15):4496-4506
The photochemistry of 2‐iodo‐3,4,5,6‐tetrafluorophenyl azide ( 7 d ) has been investigated in argon and neon matrices at 4 K, and the products characterized by IR and EPR spectroscopy. The primary photochemical step is loss of a nitrogen molecule and formation of phenyl nitrene 1 d . Further irradiation with UV or visible light results in mixtures of 1 d with azirine 5 d ′, ketenimine 6 d ′, nitreno radical 2 d , and azirinyl radical 9 . The relative amounts of these products strongly depend on the matrix and on the irradiation conditions. Nitreno radical 2 d with a quartet ground state was characterized by EPR spectroscopy. Electronic structure calculations in combination with the experimental results allow for a detailed understanding of the properties of this unusual new type of organic high‐spin molecules. 相似文献
80.
Infrared two-photon-pumped and cavity-enhanced frequency upconversion lasing has been achieved in a novel DNA-surfactant-chromophore complex (DSCC) gel system, which is a new step toward producing a biological laser. Once the focused intensity of the 150 fs and approximately 775 nm pump laser beam is higher than a certain threshold level, highly directional stimulated emission at approximately 582 nm wavelength can be observed from a 1 cm long DSCC complex gel cell. With cavity feedback provided by the two optical windows, the pump threshold can be further reduced, the highly directional output lasing can be greatly enhanced, and the output spectral linewidth can be reduced to less than 1/5 of the spontaneous fluorescence spectral bandwidth. 相似文献