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71.
In an investigation of phonation onset, a linear stability analysis was performed on a two-dimensional, aeroelastic, continuum model of phonation. The model consisted of a vocal fold-shaped constriction situated in a rigid pipe coupled to a potential flow which separated at the superior edge of the vocal fold. The vocal fold constriction was modeled as a plane-strain linear elastic layer. The dominant eigenvalues and eigenmodes of the fluid-structure-interaction system were investigated as a function of glottal airflow. To investigate specific aerodynamic mechanisms of phonation onset, individual components of the glottal airflow (e.g., flow-induced stiffness, inertia, and damping) were systematically added to the driving force. The investigations suggested that flow-induced stiffness was the primary mechanism of phonation onset, involving the synchronization of two structural eigenmodes. Only under conditions of negligible structural damping and a restricted set of vocal fold geometries did flow-induced damping become the primary mechanism of phonation onset. However, for moderate to high structural damping and a more generalized set of vocal fold geometries, flow-induced stiffness remained the primary mechanism of phonation onset. 相似文献
72.
Spiral surface growth is well understood in the limit where motion of the spiral ridge is controlled by the local supersaturation of adatoms in its surrounding. In liquid epitaxial growth, however, spirals can form governed by both, transport of heat as well as solute. We propose for the first time a two-scale model of epitaxial growth which takes into account all of these transport processes. This new model assumes a separation of length scales for the transport of heat compared to that of the solutal field. It allows for the first time numerical simulations of extended surface regions by at the same time taking into account microstructure evolution and microstructure interaction. We apply this model successfully to extend the scaling relation for the step spacing given by the BCF theory [Phil. Trans. R. Soc. London, Ser. A 243, 299 (1951)] to microstructure evolution governed by heat and solute diffusion. Further applications to understand the mechanisms and consequences of spiral interaction at epitaxial surfaces, in particular the resulting morphology transitions, are discussed. 相似文献
73.
Observation time-dependent self-diffusion coefficients can be used to obtain microstructural information of porous media. This paper presents two different kinds of Monte Carlo simulations of the self diffusion process of fluids like water in porous systems, a lattice-free method and a lattice-based method. The results for simple porous media model geometries agree well with each other and with published analytical as well as semi-analytical equations. The use of these equations, which are important for the interpretation of Pulsed Field Gradient-Nuclear Magnetic Resonance (PFG-NMR) time-dependent diffusion data with respect to properties of porous media, is discussed. 相似文献
74.
Two decades ago, it has been observed experimentally that hydrogels immersed in a bath solution swells or shrinks under external stimulations (Ric?ka et al., Macromolecules 17:2916?C2921, 1984). Recently, this fact has received renewed interest, since understanding the precise mechanisms underlying that kind of behavior has the potential to tailor most sensitive drug delivery systems based on hydrogels (Segalman and Witkowski, Mater Sci Eng C 2:243?C249, 1995). Here we contribute to a precise understanding of the mechanisms responsible for the hydrogels?? swelling kinetics as well as dynamics by proposing for the first time a model approach that can resolve the inherent short-range correlation effects along the hydrogel?Csolution interface jointly with the long-range ionic transport fields. To that end, we investigate the swelling dynamics of hydrogels, which is a moving boundary problem, by a phase field model, which couples the Nernst?CPlanck equation for the concentration of mobile ions, Poisson equation for the electric potential, mechanical equation for the displacement, and an equation for the phase field variable. Simulation for two-dimensional case reveals that under the chemical stimulation, the hydrogel will swell or shrink if the concentration of mobile ions inside bath solution decreases or increases. This is in agreement with the experimental results qualitatively and validates our new model approach. 相似文献
75.
Hennig A Hoffmann A Borcherding H Thiele T Schedler U Resch-Genger U 《Chemical communications (Cambridge, England)》2011,47(27):7842-7844
We introduce a method to determine the number of accessible functional groups on a polymer microsphere surface based on the interaction between the macrocyclic host cucurbit[7]uril (CB7) and a guest reacted to the microsphere surface. After centrifugation, CB7 in the supernatant is quantified by addition of a fluorescent dye. The difference between added and detected CB7 affords the number of accessible surface functional groups. 相似文献
76.
Heike Fliegl Olli Lehtonen Ying-Chan Lin Michael Patzschke Dage Sundholm 《Theoretical chemistry accounts》2011,129(3-5):701-713
The molecular structures of cyclic group 6 transition-metal (M = Cr, Mo, W, Sg) oxides (M 3O 9 0/1?/2? ) species have been optimized at density functional theory (DFT) levels. The photoelectron spectra (PES) of M 3O 9 ? (M = Cr, Mo, W) were calculated at the time-dependent DFT and approximate coupled-cluster singles doubles (CC2) levels and compared with experimental results. The CC2 calculations did not yield any reliable PES, whereas the molecular structures can be identified by comparing PES obtained at the DFT level with experiment. Magnetically induced current densities were calculated at the DFT level using the gauge-including magnetically induced current (gimic) approach. The current strengths and current pathways of the neutral M3O9 and the dianionic M3O 9 2? (M = Cr, Mo) oxides were investigated and analyzed with respect to a previous prediction of d-orbital aromaticity for Mo3O9 anions. Current-density calculations provide ring-current strengths that are used to assess the degree of aromaticity. Comparison of current-density calculations and calculations of nucleus-independent chemical shifts (NICS) shows that NICS calculations are not a reliable tool for determining the degree of aromaticity of the metal oxides. 相似文献
77.
Liebner F Pour G de la Rosa Arranz JM Hilscher A Rosenau T Knicker H 《Angewandte Chemie (International ed. in English)》2011,50(37):A34-A39
Nitrogen (N) is a major nutrient element controlling the cycling of organic matter in the biosphere. Its availability in soils is closely related to biological productivity. In order to reduce the negative environmental impact, associated with the application of mineral N-fertilizers, the use of ammonoxidised technical lignins is suggested. They can act as potential slow N-release fertilisers which concomitantly may increase C sequestration of soils by its potential to bind CO?. The idea of our study was to combine an improved chemical characterisation of ammonoxidised ligneous matter as well as their CO?-binding potential, with laboratory pot experiments, performed to enable an evaluation of their behaviour and stability during the biochemical reworking occurring in active soils. 相似文献
78.
Fliegl H Taubert S Lehtonen O Sundholm D 《Physical chemistry chemical physics : PCCP》2011,13(46):20500-20518
An overview of applications of the recently developed gauge including magnetically induced current method (GIMIC) is presented. The GIMIC method is used to obtain magnetically induced current densities in molecules. It provides detailed information about electron delocalization, aromatic character, and current pathways in molecules. The method has been employed in aromaticity studies on hydrocarbons, complex multi-ring organic nanorings, M?bius twisted molecules, inorganic and all-metal molecular rings and open-shell species. Recent studies on hydrogen-bonded molecules indicate that GIMIC can also be used to estimate hydrogen-bond strengths without fragmentation of the system. Preliminary results are presented on the applicability of GIMIC for investigating current transport in molecules attached to clusters simulating molecular conductivity measurements. Advantages and limitations of the GIMIC method are reviewed and discussed. 相似文献
79.
Hardelauf H Sisnaiske J Taghipour-Anvari AA Jacob P Drabiniok E Marggraf U Frimat JP Hengstler JG Neyer A van Thriel C West J 《Lab on a chip》2011,11(16):2763-2771
Spatially defined neuronal networks have great potential to be used in a wide spectrum of neurobiology assays. We present an original technique for the precise and reproducible formation of neuronal networks. A PDMS membrane comprising through-holes aligned with interconnecting microchannels was used during oxygen plasma etching to dry mask a protein rejecting poly(ethylene glycol) (PEG) adlayer. Patterns were faithfully replicated to produce an oxidized interconnected array pattern which supported protein adsorption. Differentiated human SH-SY5Y neuron-like cells adhered to the array nodes with the micron-scale interconnecting tracks guiding neurite outgrowth to produce neuronal connections and establish a network. A 2.0 μm track width was optimal for high-level network formation and node compliance. These spatially standardized neuronal networks were used to analyse the dynamics of acrylamide-induced neurite degeneration and the protective effects of co-treatment with calpeptin or brain derived neurotrophic factor (BDNF). 相似文献
80.