Neutral palladium(II) complexes with P,N Schiff-base ligands: Synthesis, characterization and catalytic oligomerisation of ethylene

New N-functionalised 2-phosphinobenzaldimino (P^N) ligands bearing 3-picolyl, furfuryl, thiophene-2-methyl, thiophene-2-ethyl, and benzyl groups have been prepared in good yield. The 2-phosphinobenzaldimino ligands were reacted with PdCl₂(COD) to give the corresponding metal complexes of the type Pd(L)Cl₂ (L = 2-phosphinobenzaldimino (P^N) ligand). All compounds were fully characterized using spectroscopic and analytical techniques, including ¹H, ¹³C, and ³¹P NMR and IR spectroscopies, mass spectrometry and elemental analysis. Selected neutral palladium complexes were evaluated as catalyst precursors in ethylene oligomerisation reactions, after activation with a co-catalyst (MMAO, EtAlCl₂, or Et₂AlCl).     

A four-component Fock-space coupled cluster investigation of the HM(CO)5, (M = Mn,Re) photoelectron spectra

In this work, we readdress the photoelectron spectra of the HM(CO)₅, (M=Mn, Re) carbonyl complexes by applying four-component Fock-space coupled cluster (FSCC) methods for their calculation in order to extend earlier studies based on less demanding approaches. The final-state characterisation was based on group theoretical considerations of the contributing orbitals and allowed for an unambiguous assignment. Energy level diagrams show the effect of spin–orbit (SO) coupling starting from scalar relativistic results and for the heavy representative HRe(CO)₅ nonadditivity effects of SO and electron correlation can be observed requiring a consistent treatment of both contributions.     

Hochgradige Einschlussthermometer

Ohne Zusammenfassung     

Surface microstructure/miniature mass spectrometer:.processing and applications

3 . Its fabrication is based on techniques used in microsystem processing and in particular anisotropic etching, thin film deposition, electroplating, and anodic bonding. The mass spectrometer consists of a plasma electron source for measurand ionisation as well as an ion optic and a mass separator specifically designed for the system’s small dimensions. Received: 27 February 1998/Accepted: 11 March 1998     

Optimization of oxidation of glycoproteins: an assay for predicting coupling to hydrazide chromatographic supports.

A rapid, simple assay for aldehydes generated by oxidation of saccharide units in glycoproteins, using dyes containing hydrazide functionalities, is described. The assay is used, in conjunction with tests of biological activity, to predict oxidation conditions that will result in a maximum of active protein coupled to a hydrazide chromatographic support. Glycoproteins are labeled with Lucifer Yellow CH or Texas Red Hydrazide, and the extent of labeling is determined. Using the assay, it is shown that the efficiency of coupling to Affi-Prep Hydrazide is proportional to oxidation.     

A measurement of the K+ → e+v)(K+ → μ+v) branching ratio

The branching ratio $\text{R =}\text{Γ(}\text{K}{}^{\mathrm{+}}\text{→}\text{e}{}^{\mathrm{+}}\text{v)}\text{Γ(}\text{K}{}^{\mathrm{+}}\text{→ μ}{}^{\mathrm{+}}\text{v)}$ has been measured on the basis of 534 observed K⁺ → e⁺v decays. The K⁺ decay at rest; the momenta of the e⁺ and μ⁺ are measured in a magnetic spectrometer using multiwire driftchambers, and the electrons are identified in a gas Cerenkov counter. The result is R = (2.37 ± 0.17_× 10^?5. The value predicted for pure axial-vector interaction and μ-e-universality is R = 2.57 × 10^?5.