Charge transport at mid-gap in trans-(CH)x: An electrochemical study

Electrochemical studies demonstrate that ～300 ppm of charge (equal to the number of neutral solitons in undoped $\text{trans}$-(CH)_x) is removed at mid-gap. These charges are transported through the polyacetylene electrode via hopping among states at the center of the energy gap, in agreement with Kivelson's theory. From analysis of the data, we have been able to determine the soliton creation energy, E_s ? 0.5eV, which is in good agreement with the theoretical value, E_s = (2/π)Δ.     

Experimental analysis of flashback in lean premixed swirling flames: upstream flame propagation

Simultaneous 10-kHz OH-PLIF and 20-kHz two-component PIV were made in conjunction with wide-field 20-kHz flame luminescence imaging of an unconfined, swirling, lean premixed, bluff-body stabilized flame during flashback. Flashback was induced by increasing the stoichiometry or swirl number or reducing the Reynolds number. A detailed stability regime was prepared and compared to predictions. Analysis of the time-correlated flame history inside the exit nozzle during flashback and non-flashback flame events led to a new hypothesis for the flashback mechanism.     

New Perspectives on Turbulent Combustion: Multi-Parameter High-Speed Planar Laser Diagnostics

Over the past three decades laser combustion diagnostics have guided an improved understanding of turbulent combustion processes. Until recently, this was based on statistically independent sampling using sampling rates much slower than typical integral time-scales of turbulent flames. Recent developments in laser and camera technology enabled an increase in sampling rates by more than three orders of magnitudes. Using these new instruments for particle image velocimetry (PIV) and planar laser-induced fluorescence (PLIF) at high sampling rates (high-speed diagnostics) allowed the resolution of integral time-scales of turbulent flames. This statistically dependent sampling is increasingly used to temporally track transients in turbulent combustion, such as flame extinction, ignition, flashback and cycle-to-cycle variations in IC engines. The simultaneous application of flow and scalar field measurements makes insights into these transients possible that were not when using statistically independent sampling with low data acquisition rates. Conditioning on distinct flame features with high-speed diagnostics enables the inclusion of time as an additional dimension. This paper reviews the emerging field of multi-parameter, high-speed, planar laser diagnostics in combustion applications. The benefit of high data acquisition rates in turbulent combustion applications is discussed in detail as well as requirements and constraints imposed by the time-scales of the investigated phenomenon are addressed. Recent developments in laser and detector hardware are highlighted, as these are the limiting factors of the sampling rate. Finally, multi-parameter high-speed measurements in combustion are summarized, with a few examples discussed in more detail.     

Theory of microwave losses of one-dimensional conductors in the skin effect regime: Application of TTF-TCNQ

Solutions for the microwave cavity losses due to a long isotropic or anisotropic conducting crystal oriented parallel to the maximum cavity E field are reported. The results are used to study the temperature dependent microwave conductivity of TTF-TCNQ along the principal conducting b-axis.     

High sensitivity search for nu;e's from the sun and other sources at KamLAND

Data corresponding to a KamLAND detector exposure of 0.28 kton yr has been used to search for nu;(e)'s in the energy range 8.3相似文献   

Transport,Magnetic and Structural Studies of Polyacetylene

Experimental progress is reviewed with emphasis on magnetic and transport studies. The magnetic results are fully consistent with the soliton doping mechanism; the decrease in Curie-law contribution has been demonstrated; the Pauli term remains small (Y < 0.07) and is apparently zero in the limit of completely uniform doping. The electrical conductivity (P and T dependence) and thermopower (n-type and p-type) are in excellent agreement with Kivelson's theory of intersoliton electron hopping.     

Anisotropic thermoelectric power of TTF-TCNQ

We have measured the thermoelectric power along the a-axis as well as the highly conducting b-axis in TTF-TCNQ crystals. Measurements were taken both parallel and perpendicular to the long axis on two sets of crystals. One set grew along the a-axis and the other along the b-axis. The thermopowers are of opposite sign except near 60°K where both cross zero at slightly different temperatures. The a-axis thermopower is consistent with non-metallic diffusive transport in the a direction.     

Anomalous electrical properties of linear chain mercury compounds

The electrical resistivity of Hg_2.86AsF₆ has been studied as a function of temperature. At room temperature, the resistivity along the chain direction is 10^?4 Ω-cm with an anisotropy of about 10². This incommensurate linear chain system remains metallic at low temperatures with resistance ratio ?_ab(300 K)/ ?_ab(1.4 K) ? 3000 and still increasing with no apparent sign of residual resistivity. A large anisotropic magnetic field dependence of the resistivity is observed below 30 K. Near 4 K, the c-axis resistance drops abruptly more than three orders of magnitude, apparently to zero, while ?_ab is continuous. The c-axis transition is suppressed in a small magnetic field.     

Detection of telomerase activity in high concentration of cell lysates using primer-modified gold nanoparticles

Although the telomeric repeat amplification protocol (TRAP) has served as a powerful assay for detecting telomerase activity, its use has been significantly limited when performed directly in complex, interferant-laced samples. In this work, we report a modification of the TRAP assay that allows the detection of high-fidelity amplification of telomerase products directly from concentrated cell lysates. Briefly, we covalently attached 12 nm gold nanoparticles (AuNPs) to the telomere strand (TS) primer, which is used as a substrate for telomerase elongation. These TS-modified AuNPs significantly reduce polymerase chain reaction (PCR) artifacts (such as primer dimers) and improve the yield of amplified telomerase products relative to the traditional TRAP assay when amplification is performed in concentrated cell lysates. Specifically, because the TS-modified AuNPs eliminate most of the primer-dimer artifacts normally visible at the same position as the shortest amplified telomerase PCR product apparent on agarose gels, the AuNP-modified TRAP assay exhibits excellent sensitivity. Consequently, we observed a 10-fold increase in sensitivity for cancer cells diluted 1000-fold with somatic cells. It thus appears that the use of AuNP-modified primers significantly improves the sensitivity and specificity of the traditional TRAP assay and may be an effective method by which PCR can be performed directly in concentrated cell lysates.