Beiträge zur Methodik der chemischen Analyse der Uranpechblenden

Ohne Zusammenfassung     

Mass and spin of Poincaré Gauge Theory

We discuss two expressions for the conserved quantities (energy momentum and angular momentum) of the Poincaré Gauge Theory. We show, that the variations of the Hamiltonians, of which the expressions are the respective boundary terms, are well defined, if we choose an appropriate phase space for asymptotic flat gravitating systems. Furthermore, we compare the expressions with others, known from the literature.     

Crystallographic report: [N,N‐Methylethylaminopropylalane]2

Dimeric and centrosymmetric [MeEtN(CH₂)₃AlH₂]₂ comprises aluminum centers, coordinated in a distorted trigonal bipyramidal fashion by three hydrogen atoms, one nitrogen atom and one carbon atom. The aluminum atoms are bridged by hydrogen atoms, creating a planar, four‐membered Al₂H₂ ring. Copyright © 2005 John Wiley & Sons, Ltd.     

Effect of quantum entanglement on Aharonov-Bohm oscillations, spin-polarized transport and current magnification effect

We present a simple model of transmission across a metallic mesoscopic ring. In one of its arm an electron interacts with a single magnetic impurity via an exchange coupling. We show that entanglement between electron and spin impurity states leads to reduction of Aharonov-Bohm oscillations in the transmission coefficient. The spin-conductance is asymmetric in the flux reversal as opposed to the two-probe electrical conductance which is symmetric. In the same model, in contradiction to the naive expectation of a current magnification effect, we observe enhancement as well as suppression of this effect depending on the system parameters. The limitations of this model to the general notion of dephasing or decoherence in quantum systems are pointed out.     

Crystal and molecular structure of cinnamylidene-butenolides fromPiper sanctum

An x-ray analysis of two natural compounds isolated fromPiper sanctum confirmed thetrans configuration for 5-(8-methoxy)cinnamyliden-4-methoxy-but-3-enolide [piperolide (I)] and for 5-[trans-(z)-,-epoxy--methoxycinnamyliden]-4-methoxy-2(5H)-furanon [epoxypiperolide (II)]. The space groups arePbca [a = 44.174(3),b = 8.056(3),c = 7.515(4) Å] for (I) andP2₁/c [a = 11.351(4),b = 8.292(5),c = 14.292(2) Å, = 96.28(2) °] for (II). The structures were solved by direct methods and refined by least-squares techniques toR = 4.8% (I) andR = 7.5% (II). The stereochemistry of the semicyclic double bond is in favor of theZ-isomers.     

Band crossing and the prealignment B(E2) anomaly in 126Ba

A theoretical interpretation of the reduction in E2 strengths in ¹²⁶Ba prior to backbending is presented. A shell model basis is built from normal parity orbilals organized into multiplets of a pseudo SU(3) symmetry coupled to $\text{h}{}_{\mathrm{<mtext>11</mtext><mtext>2</mtext>}}$ configurations restricted to states of seniority zero and two. Within the framework of the model the scattering of a pair of protons from normal parity to the $\text{h}{}_{\mathrm{<mtext>11</mtext><mtext>2</mtext>}}$ orbital produces band crossing and a corresponding reduction in E2 transition strengths prior to pair alignment which is the principal mechanism of the backbending.     

Intrinsic surface binding energy shifts in Yb metal

We report on the four-peak structure observed in the region of 4f photoemission in Yb metal, using synchrotron radiation in the energy range 70–200 eV. We conclude, contrary to previous reports, that the doublet associated with surface emissions results from an intrinsic surface shift on clean regions of the surface. We also demonstrate that the observed structure is consistent with earlier XPS measurements, and we set an upper limit on the width of the bulk peaks.